Search NASASearch

Engineering topics

Defrees, D.

Publications and source records attributed to Defrees, D..

Exobiology in Earth orbit: The results of science workshops held at NASA, Ames Research Center

The Workshops on Exobiology in Earth Orbit were held to explore concepts for orbital experiments of exobiological interest and make recommendations on which classes of experiments should be carried out. Various observational and experimental opportunities in Earth orbit are described including those associated with the Space Shuttle laboratories, spacecraft deployed from the Space Shuttle and expendable launch vehicles, the Space Station, and lunar bases. Specific science issues and technology needs are summarized. Finally, a list of recommended experiments in the areas of observational exobiology, cosmic dust collection, and in situ experiments is presented.

Defrees, D.

Interstellar isomers

Both observational and theoretical studies of molecular clouds are hindered by many difficulties. One way to partially circumvent the difficulties of characterizing the chemistry within these objects is to study the relative abundances of isomers which are synthesized from a common set of precursors. Unfortunately, only one such system has been confirmed, the HCN/HNC pair of isomers. While the basic outlines of its chemistry have been known for some years, there are still many aspects of the chemistry which are unclear. Another potential pair of isomers is HCO+/HOC+; HCO+ is an abundant instellar molecule and a tentative identification of HOC+ has been made in Sgr B2. This identification is being challenged, however, based on theoretical and laboratory evidence that HOC+ reacts with H2. Another potential pair of interstellar isomers is methyl cyanide (CH3CN, acetonitrile) and methyl isocyanide (CH3NC). The cyanide is well known, however the isocyanide has yet to be observed despite theoretical predictions that appreciable quantities should be present.

Defrees, D.