Engineering topics

Delos, S.

Publications and source records attributed to Delos, S..

3 records

NASA NTRS1988

Frequency-dependent dielectric analysis - Monitoring the chemistry and rheology of thermosets during cure

Frequency-dependent dielectric measurements in a curing resin sample were performed using an impedance analyzer and a permittivity sensor, to separate and measure the ionic (sigma) and dipolar (tau) mobilities, used as molecular probes of the cure reaction in the resin. The resin samples were tetraglycidyl 4,4-prime-diaminodiphenylmethane epoxy resins which included catalyzed (Hercules 3501-6) and uncatalyzed l3502 resin samples. The values of sigma and tau were used to quantitatively determine the viscosity, the degree of cure, and the T(g) of the resin. It is shown that the values of the Arrhenius and WLF constants during the cure process reflect the buildup of the crosslink network.

Kranbuehl, D.↗

NASA NTRS1986

Dynamic dielectric analysis - A means for process control

The development of dynamic dielectric analysis techniques (as a 'smart' sensor for quantitative NDE) and of intelligent closed-loop cure systems is reported. The cure process of both BF3:R-catalyzed and uncatalyzed tetraglycidyl-4,4'-diaminodiphenyl methane (TGDDM)/diamine epoxy resins was studied. Measurements were made over a frequency range of six decades. The resin was monitored continuously throughout the cure process as it changed from a viscous liquid to a highly crosslinked solid. From the frequency dependence of the dielectric loss, the specific conductivity has been determined and shown to directly monitor the viscosity before the gel point is reached. Dielectric master plots of the cure process, analogous to time-temperature superposition plots for rheological data, have been developed.

Kranbuehl, D.↗

NASA NTRS1985

Correlation of dynamic dielectric measurements with viscosity in polymeric resin systems

Dynamic dielectric analysis has been used to study curing polymer systems and thermoplastics. Measurements have been made over a frequency range of six decades. This wide range of frequencies increases the amount of information which can be obtained. The data are analyzed in terms of the frequency dependence of the specific conductivity sigma and the relaxation time tau, parameters which are characteristic of the cure state of the material and independent of size of the sample. Dynamic dielectric measurements have been correlated with viscosity for the polysulfone thermoplastic UDEL-P1700 and with viscosity and ultrasonic measurements on the DGEBA-type epoxy Epon 828 cured with Agent U. The experimental results suggest that when ionic processes dominate the dielectric response, the intensive property sigma is a good monitor of the resin's viscosity. The results show that the dielectric relaxation time tau can be used to monitor the state of the system and the extent and rate of the reaction.

Kranbuehl, D.↗