Search NASA⌕ Search

Engineering topics

Delsemme, A. H.

Publications and source records attributed to Delsemme, A. H..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Cometary origin of carbon and water on the terrestrial planets

An early high-temperature phase of the protosolar accretion disk is implied by at least three different telltales in chondrites and confirmed by peculiarities in the dust grains of Comet Halley. The existence of this high-temperature phase implies a large accretion rate hence a massive early disk. This clarifies the origin of the Kuiper Belt and of the Oort cloud, those two cometary populations of different symmetry that subsist today. Later, when the dust sedimented and was removed from the thermal equilibrium with the gas phase, a somewhat lower temperature of the disk explains the future planets' densities as well as the location beyond 2.6 AU of the carbonaceous chondrite chemistry. This lower temperature remains however large enough to require an exogenous origin for all carbon and all water now present in the earth. The later orbital diffusion of planetesimals, which is required by protoplanetary growth, is needed to explain the origin of the terrestrial biosphere (atmosphere, oceans, carbonates and organic compounds) by a veneer mostly made of comets.

Delsemme, A. H.↗
NASA NTRS1992

Cometary origin of carbon, nitrogen, and water on the earth

In this paper, two assumptions on the origin of the earth are substantiated: (1) that the earth accreted from fine hot degassed dust particles containing no volatiles; and (2) that, after the accretion was finished, all the volatiles of the biosphere, including the atmosphere and the oceans, were brought to the earth by cometary bombardment. A temperature of more than 1000 K is deduced at the time when the dust that was going to form the earth was separated from the gas phase. This implies grains of anhydrous silicates and of reduced iron, without either water, carbon, or any labile elements, which remained in gas phase; thus, the minor bodies could not produce atmosphere or oceans. The second assumption is based on the evidence that cometary nuclei are formed in the outer space, by accumulation of frosty particles containing large amounts of ice and volatile molecules. It is shown that the icy bodies which hit the earth are more than enough to explain the whole biosphere.

Delsemme, A. H.↗
NASA NTRS1991

Nature and history of the organic compounds in comets - An astrophysical view

The chemical similarities between comets, carbonaceous chondrites, and interstellar molecules and grains are reviewed first. The evolution of frosty interstellar grains is then followed during the collapse of a molecular cloud fragment and the subsequent formation of the Solar System. The paradigm clarifies the probable origin of the two populations of comets of different symmetry (the Oort Cloud and the Kuiper Belt) and implies an exogenous origin for all carbon and water on earth. This origin is explained by the orbital diffusion of planetesimals that is required by the growth of protoplanets.

Delsemme, A. H.↗
NASA NTRS1988

The chemistry of comets

Comets appear to represent a population of rather homogeneous objects. In particular, the original size distribution peaks at a mean diameter of the order of 10 km. Cometary dust grains appear to be made of clusters of extremely fine particles (0.1-1.0 micron) sintered by heat at a variable degree during their perihelion passages. The brightness laws of comets appear to be derived only by the sublimation of water ice or at least of gas hydrates of the clathrate type. Pristine nuclei are likely to be radially undifferentiated; only their crustal surface must be outgassed and sintered by the heat of perihelion passages. Comet Halley is confirmed to be in the same general class as the bright comets of the 1970s. With an organic fraction of 33 percent in the cometary dust, the carbon of Comet Halley is close to cosmic abundances.

Delsemme, A. H.↗
NASA NTRS1987

Diversity and similarity of comets

The evolution of comets from an early stage where they were all similar, to the later diversity is reviewed. The elemental abundances of all pristine comets are likely to be primitive, that is in solar abundance ratios for all elements including C, N, O, S, but with the exception of H (and assumedly He and Ne) that are severely depleted. The solid phase was originally in very fine grains, typically 0.1 micron or less, eventually sintered into larger grain clusters. The volatile phase contains H, C, N, O, and S molecules frozen in the pores of the grain clusters; cosmic ray plus solar irradiation changes the volatile to refractory ratio of the crust. Differences in dust tails, in plasma tails, in photometry between young and old comets, and in the variable carbon depletion of the gas phase seem to be induced by the decay processes.

Delsemme, A. H.↗
NASA NTRS1986

Neutral cometary atmospheres. V - C2 and CN in comets

The radial Haser scale lengths for the production and destruction of C2 and CN are calculated on the basis of brightness profiles for comets Bennett 1970 II and Kohoutek 1973 XII, applying the Monte Carlo particle-trajectory model of Combi and Delsemme (1980). Findings reported include C2/CN ratio independent of heliocentric distance, C2 ejection velocity from its parent molecule about 0.5 km/s, and 1-AU photochemical lifetime 31,000 s for the C2 parent molecule and 120,000 s for C2.

Combi, M. R.↗
NASA NTRS1986

Has Nemesis' orbit been detected?

The orbital angular momenta of 126 very young comets are calculated from the orbital data of Marsden and Roemer (1982) and analyzed statistically. A large anisotropy is detected in a plane almost perpendicular to the ecliptic and shown to have a characteristic dissipation lifetime of 10-30 Myr. Dynamic evolution computations indicate that the impulse which produced the anisotropy is that of a very slow massive (10-90 Jupiter mass) body, which is bound to the solar system, passed its 15,000-35,000-AU perihelion about 2-15 Myr ago, and has period 5-50 Myr. It is suggested that this body could well be identical to Nemesis, the object proposed to explain mass faunal extinctions.

Delsemme, A. H.↗
NASA NTRS1986

Elemental, isotopic and molecular abundances in comets

The chemical composition of comet nuclei and the factors affecting it are discussed, summarizing the results of recent theoretical, experimental, and observational investigations. Consideration is given to the evidence supporting the view that the nucleus is radially differentiation (except for a thin outer layer), surface differentiation by heat processing and outgassing, and mantle buildup on an undifferentiated core. The nature of the refractory and volatile components is examined, and the elemental and isotopic compositions are given in tables and characterized. The uncertain (except for H2O) molecular composition of the volatile fraction is considered, and it is suggested that some oxides or aldehydes (such as CO, CO2, and H2CO), but no large amounts of fully hydrogenated compounds (such as CH4 and NH3) are included.

Delsemme, A. H.↗
NASA NTRS1986

Cometary evidence for a solar companion?

It is demonstrated that a large anisotropy exists in a set of 126 cometary orbits that is manifested in a plane almost perpendicular to the ecliptic. This anisotropy would dissipate by orbital diffusion in 10 to 20 Myr, and thus must be due to a recent impulsive event in the Oort cloud. It is shown that this anisotropy cannot be due to gravitational perturbations from fast-moving stars or molecular clouds. A massive body slow enough to be bound to the solar system is the probable cause. The strip of sky centered on its presumed orbit reveals large anomalies in the ratio of retrograde to prograde comets which suggest the position of the perihelion of an eccentric orbit. It is proposed that the massive body is the solar companion Nemesis; other possibilities are discussed.

Delsemme, A. H.↗
NASA NTRS1985

The nature of the cometary nucleus

The basic properties of the cometary nucleus are reviewed. Consideration is given to the absence of depth differentiation, the icy conglomerate nature, the possible existence of a halo of icy grains around the nuclear region, the nucleus size and albedo, the mass, the rotation rate, and the chemical composition (elemental and molecular).

Delsemme, A. H.↗
NASA NTRS1985

The sublimation temperature of the cometary nucleus Observational evidence for H2O snows

It is shown that information on the chemical composition of cometary snows can be inferred from the distance r(0) between sublimating states in the cometary nucleus. Consideration is given to three techniques for measuring r(0): estimation of the dependence on distance of non-gravitational forces (NGF); estimation of the dependence on distance of molecular emissions; and (3), analysis of the cometary light curve. The dependence on distance of the NGFs suggests that the observed sublimations of short-period coments are determined by water snow. Light curves of newly discovered comets appear to confirm this result. The large production rates of H and OH in cometary atmospheres suggest that they are due to dissociation of H2O in the vapor states. Estimates of r(0) for eleven different comets are given in a table.

Delsemme, A. H.↗
NASA NTRS1985

What we do not know about cometary ices - A review of the incomplete evidence

Only two features seem rather well established about the cometary nucleus: it is an icy conglomerate that contains a large amount of volatile ices, and its major constituent seems to be water ice. The evidence on all the minor constituents is incomplete and fragmentary and there are still major difficulties in establishing a complete list of the parent molecules from the numerous radicals, ions, and atoms observed in the coma. In particular, the case of the forbidden lines of oxygen is discussed here in detail; new arguments are shown to contradict the need for CO2 as a major source of O(1D).

Delsemme, A. H.↗
NASA NTRS1984

The cometary connection with prebiotic chemistry

The latent heat of water ice has been established to control the sublimation of most cometary nuclei. The next most abundant molecules are CO and/or CO2, typically reaching 10-30 percent of the water content. The other species are in the range of 1-10 percent or less and include the newly discovered NH3. HCN and CH3CN are two other important prebiotic molecules present at a comparable (1 percent) level. Attention is drawn to similarities between these compositions and those inferred for the primordial earth.

Delsemme, A. H.↗
NASA NTRS1982

Chemical composition of cometary nuclei

Observational evidence pertaining to the origin and composition of cometary material is reviewed. Arguments favoring the undifferentiated character of the icy conglomerate are summarized. Theoretical descriptions of the sublimation of a cometary nucleus and the velocity field of the expanding gas are presented and compared with observations. The nature of cometary dust and the atomic abundances of H, C, N, O, and S in the volatile fraction are examined, and data on the dust and volatile fractions are combined to derive elemental abundances. It is shown that O, N, and S in cometary nuclei appear to have essentially cosmic abundances but that both H and C are drastically depleted with respect to the cosmic abundances. The apparent depletion of C by a factor of more than three is discussed. It is suggested that the missing carbon might be hidden in the dust fraction in the form of heavy organic molecules or might have remained in either the primeval solar nebula or interstellar space.

Delsemme, A. H.↗
NASA NTRS1981

Observing chemical abundances in comets

The atomic resonance lines of the major elements were observed in the atmospheres of a few comets, by using vacuum ultraviolet spectrographs on board rockets or orbiting observatories. Dust-to-gas ratios were also deduced for two comets through a Finson-Probstein's analysis of their dust-tail isophotes. The geometric albedo of the dust for the phase angle alpha of the observations is not accurately known but, the dust-to-gas ratio is not overly sensitive to the actual value of this albedo. Infrared observations of the dust head of some comets show that the bulk of cometary dust must be silicates, although a minor component (5-10 percent) of carbon compounds is rather likely, because of poor dielectric properties of the grains. This interpretation is confirmed by the fact that interplanetary dust probably of cometary origin, that was collected in the stratosphere by NASA-U2 Spacecraft, is chondritic in nature. Metal abundances in the head of a sungrazing comet support the chondritic hypothesis.

Delsemme, A. H.↗
NASA NTRS1981

The spectroscopy of comets: Introductory remarks

Emphasis in cometary spectroscopy is on production rates, becuase they open the door to more fundamental clues about the origin and the history of the solar system, through the understanding of comet chemistry. In order to establish production rates quantitatively, suggestion are provided, in particular: to study the lifetimes of all hypothetical parents, against all processes of decay, namely photodissociations, photoionizations and ion-molecule reactions; and to study the velocity of all molecular fragments resulting from all the decay processes, through the balance sheet of the energy distribution before and after each decay process.

Delsemme, A. H.↗
NASA NTRS1981

Are comets connected to the origin of life

Possible connections between comets and the origin of life on earth are discussed. The orbital evolution of comets and their origin are considered within a framework for the origin of the solar system, with particular attention given to the origin of the biosphere, and the origin of the Oort cloud. Evidence suggesting that cometary nuclei are undifferentiated throughout is considered, and a model of the average composition of a mean new comet is obtained from observational data which is similar to that of an interstellar frost. The chemistry of the model composition giving rise to the species observed in cometary spectra is considered, as well as the relations of cometary to cosmic abundances of oxygen, carbon and sulfur. The characteristics of possible sites for prebiotic chemistry, including interstellar clouds, the protosolar nebula, comets in the Oort cloud, periodic comets and the primitive earth, are examined, and a possible role of comets in bringing the interstellar prebiotic chemistry to earth is suggested.

Delsemme, A. H.↗