Spreading monoclinic boundary network between hexagonal primary grains for high performance Ni-rich
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Xu, Xing↗
Engineering topics
Du, Chunyu
Publications and source records attributed to Du, Chunyu.
Stacking fault disorder induced by Mn doping in Ni(OH)[subscript 2] for supercapacitor electrodes
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Zhang, Zhiguo↗
Enabling Highly Stable Li–O 2 Batteries with Full Discharge–Charge Capability: The Porous Binder- and Carbon-Free IrNi Nanosheet Cathode
Rechargeable aprotic Li-O 2 batteries have drawn much attention in light of their ultrahigh theoretical energy density. However, the sluggish kinetics of oxygen cathode reactions lead to huge energy loss, while the unfavorable side reactions associated with the widely used carbon and binder account for fast battery decay during cycles. In this work, hierarchically holey IrNi alloy nanosheets are facilely designed on Ni foam substrate as a freestanding, binder- and carbon-free cathode to address these challenges. The IrNi nanosheets consist of numerous interconnected nanoparticles, forming abundant nanoholes, benefiting active-site exposure. Moreover, the meso-/macropores pave channels for the transfer of oxygen and lithium ions and provide enough accommodation for the insoluble Li 2 O 2 product. The corresponding Li-O 2 batteries demonstrate low polarization and excellent cycle stability with full discharge/charge capability (up to 292 cycles at a current density of 0.2 mA cm -2 within a voltage range from 2.3 to 4.3 V). The long-term cycling performance is principally attributed to the exclusive catalytic stability of the holey IrNi nanosheets and its good compatibility with dimethyl sulfoxide-based electrolyte. Our research provides novel insights into the design of robust and freestanding porous cathodes for high energy density Li-O 2 batteries.
25 ENERGY STORAGE↗