Techno-economic Analysis and Life Cycle Assessment of Biomass-Derived Polyhydroxyurethane and Nonisocyanate Polythiourethane Production and Reprocessing
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Engineering topics
Dunn, Jennifer B.
Publications and source records attributed to Dunn, Jennifer B..
Toward Enhancing Wastewater Treatment with Resource Recovery in Integrated Assessment and Computable General Equilibrium Models
Sustainable water management is essential to increasing water availability and decreasing water pollution. The wastewater sector is expanding globally and beginning to incorporate technologies that recover nutrients from wastewater. Nutrient recovery increases energy consumption but may reduce the demand for nutrients from virgin sources. We estimate the increase in annual global energy consumption (1,100 million GJ) and greenhouse gas emissions (84 million t CO2e) for wastewater treatment in the year 2030 compared to today’s levels to meet sustainable development goals. To capture these trends, integrated assessment and computable general equilibrium models that address the energy-water nexus must evolve. We reviewed 16 of these models to assess how well they capture wastewater treatment plant energy consumption and GHG emissions. Only three models include biogas production from the wastewater organic content. Four explicitly represent energy demand for wastewater treatment, and eight include explicit representation of wastewater treatment plant greenhouse gas emissions. Of those eight models, six models quantify methane emissions from treatment, five include representation of emissions of nitrous oxide, and two include representation of emissions of carbon dioxide. Our review concludes with proposals to improve these models to better capture the energy-water nexus associated with the evolving wastewater treatment sector.
42 ENGINEERING↗
Reducing Economy-Wide Greenhouse Gas Emissions with Electrofuels and Biofuels as the Grid Decarbonizes
Biofuels and electrofuels have the potential to complement electrification in speeding greenhouse gas emissions reductions, especially in hard-to-decarbonize sectors. Concentrated waste CO 2 streams that can be used as a feedstock for electrofuels, however, may become less available as the share of renewable electricity increases and industries undergo decarbonization. Here, we conduct an analysis with detailed treatment of biofuels and electrofuels to probe their role in decarbonizing multiple industrial sectors and transportation. We examine how the changing availability of CO 2 could affect electrofuel production and the potential role of direct air capture in stabilizing the supply of CO 2 . The results indicate that biofuels could fulfill 12% of the total final energy demand across all U.S. sectors in 2050. Using seven industrial source points of CO 2 available in 2050, 15,388 PJ of electrofuels could be produced, which amounts to 25% of the total final energy demand. This result holds even upon decarbonization that requires direct air capture to boost the CO 2 supply. Biofuels and e-fuels have the potential to reduce economy-wide GHG emissions by 7 and 21% beyond electrification alone. However, electricity consumption and land use grow markedly with decarbonization at scale.
29 ENERGY PLANNING, POLICY, AND ECONOMY↗
Energy, economic, and environmental impacts assessment of co-optimized on-road heavy-duty engines and bio-blendstocks
Renewable MCCI bio-blendstocks with advantageous properties co-optimized with engines and a ducted fuel injection could reduce engine-out emissions leading to reduced total cost of vehicle ownership and a potential to penetrate the market at scale.
09 BIOMASS FUELS↗
Life-Cycle Assessment of Biochemicals with Clear Near-Term Market Potential
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Plastics to fuel or plastics: Life cycle assessment-based evaluation of different options for pyrolysis at end-of-life
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Techno-Economic Analysis and Life-Cycle Assessment of Emerging Technologies for Bioprocessing Separations
Limited availability, rising costs, and environmental concerns about fossil fuels have generated considerable interest in finding alternative, renewable sources including biomass, which can be converted into a number of biofuels and bioproducts. In comparison to petroleum-based products, high processing costs, mainly associated with bioprocessing separations, limit widespread implementation of biofuels and bioproducts. Bioprocess-related separations are also complicated, regardless of the conversion pathway, due to the dilute nature of products and the chemically complex mixtures that result from biomass deconstruction. In many cases, bioprocessing separation approaches lack a technology baseline, or definition of the state of technology (SOT). This work focuses on evaluating the technology readiness of novel separations technologies for the conversion of biomass into biofuels and bioproducts and will address three key topics: 1) SOT description, 2) economic viability analysis of both SOT and innovative separations, and 3) environmental impact assessment of both SOT and novel processes. The current SOT for lignin valorization, dilute carbon recovery, and impurity removal is used to identify potential opportunities for improvement and provide a baseline for comparison with the emerging technologies. Detailed techno-economic analysis (TEA) and life cycle assessment (LCA) are applied to understand the key drivers and challenges related to the economic feasibility and environmental impacts, respectively.
BASIC BIOLOGICAL SCIENCES,BIOMASS FUELS↗
Electrification potential of U.S. industrial boilers and assessment of the GHG emissions impact
Electrification is a key strategy for decarbonizing the industrial sector. Industrial process heating, which still relies heavily on fossil fuel combustion and accounts for the majority of sector wide GHG emissions, is a particularly attractive electrification target. Electrifying industrial boilers represents a cross-cutting opportunity for GHG emissions reductions, given their widespread use in most manufacturing industries. Yet, there are gaps in the understanding of the current population of conventional industrial boilers in the United States that preclude a characterization of boiler electrification's technical potential to reduce fuel consumption and GHG emissions. In this study, we develop an up-to-date dataset of the industrial boiler population in the U.S. and quantify the county-level electricity requirements and net changes in fuel use and GHG emissions under the current electric grid and theoretical future grid scenarios. Our results show an increase of 105 MMmtCO 2 e and 73 MMmtCO 2 e in GHG emissions from boiler electrification, with and without the replacement of byproduct fuels, respectively, under the current electric grid, and a reduction of 19 MMmtCO2e and 7 MMmtCO2e in GHG emissions under a future high renewables electric grid. GHG emissions savings are currently possible only in certain regions of the U.S. unless future grids are decarbonized. We also provide discussion that could be useful for policy makers and manufacturing facilities for advancing the electrification of industrial boilers in locations and industries toward fuel savings and GHG emissions reductions.
29 ENERGY PLANNING, POLICY, AND ECONOMY↗
The contribution of biomass and waste resources to decarbonizing transportation and related energy and environmental effects
Analyzed the extent to which biomass can contribute to the decarbonization of transportation as electrification of the light-duty fleet increases.
09 BIOMASS FUELS↗
Carbon Calculator for Land Use and Land Management Change from Biofuels Production (CCLUB)
The Carbon Calculator for Land Use and Land Management Change from Biofuels Production (CCLUB) has been developed as an integral part of Argonne National Laboratory’s Greenhouse Gases, Regulated Emissions, and Energy use in Technologies (GREET) model to analyze greenhouse gas (GHG) emissions from land use change (LUC) and land management change (LMC) in the context of overall biofuel life-cycle analysis (LCA). CCLUB relies on i) biofuel production scenarios, ii) LUC and LMC scenarios, and iii) emission factors (EF) to generate GHG emissions of LUC and LMC for biofuel production in gram carbon dioxide equivalent (CO2e) per MJ of fuel produced. Figure 1 outlines the calculations and data sources within CCLUB that are described in this document and Table 1 identifies where these data are stored and used within CCLUB, which is built in Microsoft Excel.
09 BIOMASS FUELS↗
Examining the Characteristics of the Cropland Data Layer in the Context of Estimating Land Cover Change
The United States Department of Agriculture (USDA) Cropland Data Layer (CDL) provides spatially explicit information about crop production area and has served as a prevalent data source for characterizing cropland change in the U.S. in the last decade. Understanding the accuracy of the CDL is paramount because of the reliance on it for management and policy making. This study examined the characteristics of the CDL from 2007 to 2017 using comparisons to other USDA datasets. The results showed when examining the cropland area for the same year, the CDL produced comparable trends with other datasets (R 2 > 0.95), but absolute area differed. The estimated area of cropland changes from 2007 to 2012, 2008 to 2012 and 2012 to 2017 varied from weak to moderate correlation between the CDL and the tabular data (R 2 = 0.005~0.63). Differences in area of cropland change varied widely between data sources with the CDL estimating much larger change area. A series of image processing techniques designed to improve the confidence in cropland change estimated using the CDL reduced the area of estimated cropland change. The techniques also, unexpectedly, lowered the correlation in change estimated between the CDL and the tabular datasets. Estimated land cover change area varied widely based on analyses applied and could reverse from increasing to declining area in cropland. Further analyses showed unlikely change scenarios when comparing different year combinations. The authors recommend the CDL only be used for land cover change analysis if the error can be estimated and is within change estimates.
58 GEOSCIENCES↗
Bioprocessing Separations Consortium: Three-Year Overview. Technical advances, process economics influence, and State of the Science
This report summarizes the efforts undertaken by the Bioprocessing Separations Consortium since its inception in 2016. During this time, four critical challenges in biochemical and thermochemical processing were addressed.
09 BIOMASS FUELS↗
Carbon Calculator for Land Use and Land Management Change from Biofuels Production (CCLUB)
The Carbon Calculator for Land Use and Land Management Change from Biofuels Production (CCLUB) has been developed as an integral part of Argonne National Laboratory’s Greenhouse Gases, Regulated Emissions, and Energy use in Technologies (GREET) model to analyze greenhouse gas (GHG) emissions from land use change (LUC) and land management change (LMC) in the context of overall biofuel life-cycle analysis (LCA).
09 BIOMASS FUELS↗
Energy, economic, and environmental benefits assessment of co-optimized engines and bio-blendstocks
A systems-level modeling suite underpins estimates of greenhouse gas and other benefits of deploying co-optimized fuels and engines.
29 ENERGY PLANNING, POLICY, AND ECONOMY↗
Bioprocessing Separations Consortium Three-Year Overview: Technical Advances, Process Economics Influence, and State of the Science
The Bioprocessing Separations Consortium solves separations challenges that are unique to bioprocessing. To do this, the Consortium uses two methods: applying existing technologies to new challenges and developing new technologies that may address these unique challenges better than today’s commercial technologies. In its research and development, the Consortium leverages its three core capabilities: materials development and evaluation, process development, and analysis and computation. In its first three years, from 2016 to 2019, the Consortium addressed four critical challenges in biochemical and thermochemical processing. First, the Consortium targeted the fractionation of lignin to enable valorization of this portion of biomass that offers diverse, complex, and valuable building blocks and products. Second, Consortium researchers developed technologies to enable process intensification, which can reduce equipment needs, energy consumption, and waste generation, thereby cutting bioprocessing capital costs and rendering processes more efficient. Third, the Consortium sought to recover carbon from dilute aqueous streams that are common to bioprocessing; recovering dilute carbon can improve process efficiency and economics. Finally, Consortium researchers designed and developed new materials and catalysts to reduce targeted foulants and poisons in bioprocessing streams that can limit the lifetime of downstream catalysts or fermenting microorganisms. Table 1 lists the technologies that were examined and places them in the context of the Consortium’s capabilities, types of bioprocesses, and critical challenges in bioprocessing separations. Overall, across these projects, we have developed separations technologies for 10 bioprocesses, addressed 9 target compounds in bioprocessing, developed 10 materials, and evaluated 4 processes for cost and sustainability.
09 BIOMASS FUELS↗
Bioprocessing Separations Consortium Three-Year Overview: Technical Advances Process Economics Influence, and State of the Science
The Bioprocessing Separations Consortium solves separations challenges that are unique to bioprocessing. To do this, the Consortium uses two methods: applying existing technologies to new challenges and developing new technologies that may address these unique challenges better than today’s commercial technologies. In its research and development, the Consortium leverages its three core capabilities: materials development and evaluation, process development, and analysis and computation. In its first three years, from 2016 to 2019, the Consortium addressed four critical challenges in biochemical and thermochemical processing. First, the Consortium targeted the fractionation of lignin to enable valorization of this portion of biomass that offers diverse, complex, and valuable building blocks and products. Second, Consortium researchers developed technologies to enable process intensification, which can reduce equipment needs, energy consumption, and waste generation, thereby cutting bioprocessing capital costs and rendering processes more efficient. Third, the Consortium sought to recover carbon from dilute aqueous streams that are common to bioprocessing; recovering dilute carbon can improve process efficiency and economics. Finally, Consortium researchers designed and developed new materials and catalysts to reduce targeted foulants and poisons in bioprocessing streams that can limit the lifetime of downstream catalysts or fermenting microorganisms. Table 1 lists the technologies that were examined and places them in the context of the Consortium’s capabilities, types of bioprocesses, and critical challenges in bioprocessing separations. Overall, across these projects, we have developed separations technologies for 10 bioprocesses, addressed 9 target compounds in bioprocessing, developed 10 materials, and evaluated 4 processes for cost and sustainability.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Bioprocessing Separations Consortium: Three-Year Overview - Technical Advances, Process Economics Influence, and State of the Science
The Bioprocessing Separations Consortium solves separations challenges that are unique to bioprocessing. To do this, the Consortium uses two methods: applying existing technologies to new challenges and developing new technologies that may address these unique challenges better than today’s commercial technologies. In its research and development, the Consortium leverages its three core capabilities: materials development and evaluation, process development, and analysis and computation. In its first three years, from 2016 to 2019, the Consortium addressed four critical challenges in biochemical and thermochemical processing. First, the Consortium targeted the fractionation of lignin to enable valorization of this portion of biomass that offers diverse, complex, and valuable building blocks and products. Second, Consortium researchers developed technologies to enable process intensification, which can reduce equipment needs, energy consumption, and waste generation, thereby cutting bioprocessing capital costs and rendering processes more efficient. Third, the Consortium sought to recover carbon from dilute aqueous streams that are common to bioprocessing; recovering dilute carbon can improve process efficiency and economics. Finally, Consortium researchers designed and developed new materials and catalysts to reduce targeted foulants and poisons in bioprocessing streams that can limit the lifetime of downstream catalysts or fermenting microorganisms. Table 1 lists the technologies that were examined and places them in the context of the Consortium’s capabilities, types of bioprocesses, and critical challenges in bioprocessing separations. Overall, across these projects, we have developed separations technologies for 10 bioprocesses, addressed 9 target compounds in bioprocessing, developed 10 materials, and evaluated 4 processes for cost and sustainability.
09 BIOMASS FUELS↗