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Eck, R. V.

Publications and source records attributed to Eck, R. V..

Venus - Atmospheric evolution.

Thermodynamic equilibrium composition of Venus atmosphere computed from atomic composition deduced spectroscopically

SPECTROSCOPY

Thermodynamic Equilibrium in the Origin of Organic Matter

Theoretical and experimental support is presented for the hypothesis that organic compounds occurring in carbonaceous chondrites may have formed under equilibrium or near equilibrium conditions. The equilibrium distributions of organic compounds at temperature between 300 and 1000 K and pressures of 10(exp 16) to 50 atmospheres for the C-H-O system have been computed. At high temperatures and low pressures aromatic compounds may form even in the presence of excess hydrogen. Equilibrium concentrations of numerous compounds possible at 1000 K when N, S, and C1 are added to the system have also been determined. A limited equilibrium method is employed in which those few compounds which form with most difficulty are excluded from the computations. This approach is shown to be useful in the interpretation of certain experimental data. In preliminary experiments it has been found that gases, converted to the plasma state by high energy radio frequency discharge, yield product mixtures which are in qualitative agreement with those predicted.

CHEMICAL EQUILIBRIUM

Program RELATE

Computer program to compare sequences of amino acids in two proteins to determine regions of identical or related structure

AMINO ACID

Program ALLELE

Computer program to formulate matrix of relative deviations from random pairing of amino acids

COMPUTER PROGRAM