Elshorbany, Yasin | Search NASA

DOE OSTI2020

Potential impacts of mercury released from thawing permafrost

Abstract Mercury (Hg) is a naturally occurring element that bonds with organic matter and, when converted to methylmercury, is a potent neurotoxicant. Here we estimate potential future releases of Hg from thawing permafrost for low and high greenhouse gas emissions scenarios using a mechanistic model. By 2200, the high emissions scenario shows annual permafrost Hg emissions to the atmosphere comparable to current global anthropogenic emissions. By 2100, simulated Hg concentrations in the Yukon River increase by 14% for the low emissions scenario, but double for the high emissions scenario. Fish Hg concentrations do not exceed United States Environmental Protection Agency guidelines for the low emissions scenario by 2300, but for the high emissions scenario, fish in the Yukon River exceed EPA guidelines by 2050. Our results indicate minimal impacts to Hg concentrations in water and fish for the low emissions scenario and high impacts for the high emissions scenario.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2019

Divergence in land surface modeling: linking spread to structure

Divergence in land carbon cycle simulation is persistent and widespread. Regardless of model intercomparison project, results from individual models diverge significantly from each other and, in consequence, from reference datasets. Here we link model spread to structure using a 15-member ensemble of land surface models from the Multi-scale synthesis and Terrestrial Model Intercomparison Project (MsTMIP) as a test case. Our analysis uses functional benchmarks and model structure as predicted by model skill in a machine learning framework to isolate discrete aspects of model structure associated with divergence. We also quantify how initial conditions prejudice present-day model outcomes after centennial-scale transient simulations. Overall, the functional benchmark and machine learning exercises emphasize the importance of ecosystem structure in correctly simulating carbon and water cycling, highlight uncertainties in the structure of carbon pools, and advise against hard parametric limits on ecosystem function. We also find that initial conditions explain 90% of variation in global satellite-era values—initial conditions largely predetermine transient endpoints, historical environmental change notwithstanding. As MsTMIP prescribes forcing data and spin-up protocol, the range in initial conditions and high levels of predetermination are also structural. Our results suggest that methodological tools linking divergence to discrete aspects of model structure would complement current community best practices in model development.

58 GEOSCIENCES↗