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Evans, John

Publications and source records attributed to Evans, John.

At least 19 records

In situ estimation of ice crystal properties at the South Pole using LED calibration data from the IceCube Neutrino Observatory

The IceCube Neutrino Observatory instruments about 1 km 3 of deep, glacial ice at the geographic South Pole. It uses 5160 photomultipliers to detect Cherenkov light emitted by charged relativistic particles. An unexpected light propagation effect observed by the experiment is an anisotropic attenuation, which is aligned with the local flow direction of the ice. We examine birefringent light propagation through the polycrystalline ice microstructure as a possible explanation for this effect. The predictions of a first-principles model developed for this purpose, in particular curved light trajectories resulting from asymmetric diffusion, provide a qualitatively good match to the main features of the data. This in turn allows us to deduce ice crystal properties. Since the wavelength of the detected light is short compared to the crystal size, these crystal properties include not only the crystal orientation fabric, but also the average crystal size and shape, as a function of depth. By adding small empirical corrections to this first-principles model, a quantitatively accurate description of the optical properties of the IceCube glacial ice is obtained. In this paper, we present the experimental signature of ice optical anisotropy observed in IceCube light-emitting diode (LED) calibration data, the theory and parameterization of the birefringence effect, the fitting procedures of these parameterizations to experimental data, and the inferred crystal properties.

54 ENVIRONMENTAL SCIENCES↗

Tailoring Negative Thermal Expansion via Tunable Induced Strain in La–Fe–Si-Based Multifunctional Material

Zero thermal expansion (ZTE) composites are typically designed by combining positive (PTE) with negative thermal expansion (NTE) materials acting as compensators and have many diverse applications, including in high-precision instrumentation and biomedical devices. La(Fe 1-x ,Si x )13-based compounds display several remarkable properties, such as giant magnetocaloric effect and very large NTE at room-temperature. Both are linked via strong magnetovolume coupling, which leads to sharp magnetic and volume changes occurring simultaneously across first-order phase transitions; the abrupt nature of these changes makes them unsuitable as thermal expansion compensators. To make these materials more useful practically, the mechanisms controlling the temperature over which this transition occurs and the magnitude of contraction need to be controlled. In this work, ball-milling was used to decrease particles and crystallite sizes and increase the strain in LaFe 11.9 Mn 0.27 Si 1.29 H x alloys. Such size and strain tuning effectively broadened the temperature over which this transition occurs. The material’s NTE operational temperature window was expanded, and its peak was suppressed by up to 85%. This work demonstrates that induced strain is the key mechanism controlling these materials’ phase transitions. This allows the optimization of their thermal expansion towards room-temperature ZTE-applications.

36 MATERIALS SCIENCE↗

An Assurance Case with a Model at its Core

We describe our pilot study development of an Assurance Case arguing the robustness of a spacecraft demonstration of optical communication. Our Assurance Case addresses the concern that optical communication may be interrupted by the presence of cloud cover, threatening the success of the demonstration. Central to our Assurance Case is its use of a model of atmospheric attenuation to support a key portion of the robustness argument. The conclusion for the demonstration is that its schedule slack plus ability to store data for transmission later accommodates occasional weather-caused atmospheric attenuation.We indicate how the overall structure of the Assurance Case derives from the Objectives Hierarchy set forth in the NASA Reliability and Maintainability standard. We then present the portions of the Assurance Case that argue (1) the atmospheric attenuation model is sufficiently accurate, (2) application of the model shows the desired robustness of the demonstration, and (3) all the model assumptions are satisfied in its application. Lastly, we suggest how an engineering model of the demonstration system and its use could inform the development of the Assurance Case encompassing additional plausible hazards.

DiVenti, Anthony↗

Model Based Engineering for Software Assurance

NASA's successful development of next generation space vehicles, habitats, and robotic systems will require reliable hardware and software systems. The aim of this initiative is to develop modeling methodology and tools to support Model-Based Systems Engineering (MBSE) for software assurance and reliability analysis. This effort expands the Unified Modeling Language (UML) software design models to include fault data for the extraction of Failure Modes and Effects Criticality Analysis (FMECA) and Fault Tree Analysis (FTA) for software. We explored different modeling approaches to integrate the UML software design models with the Systems Modeling Language (SysML) system models to generate an integrated model and reliability tools that take into account software and hardware interfaces.The benefits of this concept directly affect the safety community with quick turnarounds to produce software assurance and reliability analysis artifacts and the ability to visualize failure effects, both hardware and software. The result is enhanced system design integrity and early identification of system risks. This initiative will enable software assurance activities early in the system design lifecycle, facilitating the discovery of design weaknesses and enhancing the capability to produce safe, hazard-free systems

Wang, Lui↗

Monitoring the Formation and Reactivity of Organometallic Alkane and Fluoroalkane Complexes with Silanes and Xe Using Time-Resolved X-ray Absorption Fine Structure Spectroscopy

Complexes with weakly coordinating ligands are often formed in chemical reactions and can play key roles in determining the reactivity, particularly in catalytic reactions. Using time-resolved X-ray absorption fine structure (XAFS) spectroscopy in combination with time-resolved IR (TRIR) spectroscopy and tungsten hexacarbonyl, W(CO) 6 , we are able to structurally characterize the formation of an organometallic alkane complex, determine the W–C distances, and monitor the reactivity with silane to form an organometallic silane complex. Experiments in perfluorosolvents doped with xenon afford initially the corresponding solvated complex, which is sufficiently reactive in the presence of Xe that we can then observe the coordination of Xe to the metal center, providing a unique insight into the metal–xenon bonding. These results offer a step toward elucidating the structure, bonding, and chemical reactivity of transient species by X-ray absorption spectroscopy, which has sensitivity to small structural changes. The XAFS results indicate that the bond lengths of metal–alkane (W–H–C) bond in W(CO) 5 (heptane) as 3.07 (±0.06) Å, which is longer than the calculated W–C (2.86 Å) for binding of the primary C–H, but shorter than the calculated W–C (3.12 Å) for the secondary C–H. Here, a statistical average of the calculated W–C alkane bond lengths is 3.02 Å, and comparison of this value indicates that the value derived from the XAFS measurements is averaged over coordination of all C–H bonds consistent with alkane chain walking. Photolysis of W(CO) 6 in the presence of HSiBu 3 allows the conversion of W(CO) 5 (heptane) to W(CO) 5 (HSiBu 3 ) with an estimated W–Si distance of 3.20 (±0.03) Å. Time-resolved TRIR and XAFS experiments following photolysis of W(CO) 6 in perfluoromethylcyclohexane (PFMCH) allows the characterization of W(CO) 5 (PFMCH) with a W–F distance of 2.65 (±0.06) Å, and doping PFMCH with Xe allows the characterization of W(CO) 5 Xe with a W–Xe bond length of 3.10 (±0.02) Å.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Reliability Estimation for Mission Extension NASA Approach/Recommendations

Present NASA's current and recommended concepts for Mission Extension and De-orbit reliability Methodologies. NASA's current and recommended approaches ensuring de-orbit requirements are not unnecessarily driving mission design efforts or adding incresed costs or risks to manufacturing solutions without providing benefit to missionsand will assist in moving reliability estimation from piece part performance estimates to component history and system-level testing based estimations.

SMA↗

Identifying Where Mission Assurance Can Benefit from Model Based Systems Engineering

Model Based Systems Engineering (MBSE) is being introduced and used to support many aspects of the engineering of complex systems. Our focus is on space systems, with a particular interest in Mission Assurance of those systems. We seek to identify where Mission Assurance can potentially benefit when a space system is developed using an MBSE approach. To do so we consider how MBSE can help provide the evidence that Mission Assurance needs, using the recently developed NASA Reliability and Maintainability Objective Hierarchy as the exposition of those needs. We illustrate this MBSE’s potential contributions using examples drawn from our prior survey of the MBSE literature addressing space mission assurance concerns. The overall conclusion we draw from this is that there are numerous ways in which MBSE may, and in some cases already does, support Mission Assurance.

Feather, Martin S.↗

Goal Structuring Notation in a Radiation Hardening Assurance Case for COTS-Based Spacecraft

A systematic approach is presented to constructing a radiation assurance case using Goal Structuring Notation (GSN) for spacecraft containing commercial-off-the-shelf (COTS) parts. The GSN paradigm is applied to an SRAM single-event upset experiment board designed to fly on a CubeSat November 2016. Construction of a radiation assurance case without use of hardened parts or extensive radiation testing is discussed.

Witulski, Arthur↗

Goal Structured Notation in a Radiation Hardening Safety Case for COTS-Based Spacecraft

A systematic approach is presented to constructing a radiation assurance case using Goal Structured Notation (GSN) for spacecraft containing COTS parts. The GSN paradigm is applied to an SRAM single-event upset experiment board designed to fly on a CubeSat November 2016. Construction of a radiation assurance case without use of hardened parts or extensive radiation testing is discussed.

Assurance Case↗

Model Based Mission Assurance: NASA's Assurance Future

Model Based Systems Engineering (MBSE) is seeing increased application in planning and design of NASA’s missions. This suggests the question: what will be the corresponding practice of Model Based Mission Assurance (MBMA)? Contemporaneously, NASA’s Office of Safety and Mission Assurance (OSMA) is evaluating a new objectives based approach to standards to ensure that the Safety and Mission Assurance disciplines and programs are addressing the challenges of NASA’s changing missions, acquisition and engineering practices, and technology. MBSE is a prominent example of a changing engineering practice. We use NASA’s objectives-based strategy for Reliability and Maintainability as a means to examine how MBSE will affect assurance. We surveyed MBSE literature to look specifically for these affects, and find a variety of them discussed (some are anticipated, some are reported from applications to date). Predominantly these apply to the early stages of design, although there are also extrapolations of how MBSE practices will have benefits for testing phases. As the effort to develop MBMA continues, it will need to clearly and unambiguously establish the roles of uncertainty and risk in the system model. This will enable a variety of uncertainty-based analyses to be performed much more rapidly than ever before and has the promise to increase the integration of CRM (Continuous Risk Management) and PRA (Probabilistic Risk Analyses) even more fully into the project development life cycle. Various views and viewpoints will be required for assurance disciplines, and an over-arching viewpoint will then be able to more completely characterize the state of the project/program as well as (possibly) enabling the safety case approach for overall risk awareness and communication.

Evans, John↗