Engineering topics

Fan, S.

Publications and source records attributed to Fan, S..

6 records

DOE OSTI2024

Capping Effects on Spin and Charge Excitations in Parent and Superconducting Nd 1-x Sr x⁢ NiO 2

Superconductivity in infinite layer nickelates Nd 1-x⁢ Sr x NiO 2 has so far been achieved only in thin films, raising questions on the role of substrates and interfaces. Given the challenges associated with their synthesis it is imperative to identify their intrinsic properties. We use resonant inelastic x-ray scattering to investigate the influence of the SrTiO 3 capping layer on the excitations of Nd 1-x ⁢Sr x⁢ NiO 2 (x =0 and 0.2). Spin excitations are observed in parent and 20% doped Nd 1-x Sr x ⁢NiO 2 regardless of capping, proving that magnetism is intrinsic to infinite-layer nickelates and appears in a significant fraction of their phase diagram. In parent and superconducting Nd 1-x Sr x ⁢NiO 2 , the spin excitations are slightly hardened in capped samples compared to the noncapped ones. Additionally, a weaker Ni-Nd charge transfer peak at ~0.6 eV suggests that the hybridization between Ni 3⁢d and Nd 5⁢d orbitals is reduced in capped samples. In conclusion, from our data, capping induces only minimal differences in Nd 1-x Sr x NiO 2 and we phenomenologically discuss these differences based on the reconstruction of the SrTiO 3 -NdNiO 2 interface and other mechanisms such as crystalline disorder.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Spin–phonon interactions and magnetoelectric coupling in Co 4 B 2 O 9 ( B = Nb, Ta)

In order to explore the consequences of spin–orbit coupling on spin–phonon interactions in a set of chemically similar mixed metal oxides, we measured the infrared vibrational properties of Co 4 B 2 O 9 (B = Nb, Ta) as a function of temperature and compared our findings with lattice dynamics calculations and several different models of spin–phonon coupling. Frequency vs temperature trends for the Co 2+ shearing mode near 150 cm –1 reveal significant shifts across the magnetic ordering temperature that are especially large in relative terms. Bringing these results together and accounting for noncollinearity, we obtain spin–phonon coupling constants of –3.4 and –4.3 cm –1 for Co 4 Nb 2 O 9 and the Ta analog, respectively. Analysis reveals that these coupling constants are derived from interlayer (rather than intralayer) exchange interactions and that the interlayer interactions contain competing antiferromagnetic and ferromagnetic contributions. At the same time, beyond-Heisenberg terms are minimized due to fortuitous symmetry considerations, different from most other 4d- and 5d-containing oxides. Comparison with other contemporary oxides shows that spin–phonon coupling in this family of materials is among the strongest ever reported, suggesting an origin for magnetoelectric coupling.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS2004

Dust Transport and Deposition Observed from the Terra-MODIS Space Observations

Meteorological observations, in situ data and satellite images of dust episodes were used already in the 1970s to estimate that 100 tg of dust are transported from Africa over the Atlantic Ocean every year between June and August and deposited in the Atlantic Ocean and the Americas. Desert dust is a main source of nutrients to oceanic biota and the Amazon forest, but deteriorates air quality and caries pathogens as shown for Florida. Dust affects the Earth radiation budget, thus participating in climate change and feedback mechanisms. There is an urgent need for new tools for quantitative evaluation of the dust distribution, transport and deposition. The Terra spacecraft launched at the dawn of the last millennium provides first systematic well calibrated multispectral measurements from the MODIS instrument, for daily global analysis of aerosol. MODIS data are used here to distinguish dust from smoke and maritime aerosols and evaluate the African dust column concentration, transport and deposition. We found that 230+/-80 tg of dust are transported annually from Africa to the Atlantic Ocean, 30 tg return to Africa and Europe, 70 tg reach the Caribbean, 45 tg fertilize the Amazon Basin, 4 times as previous estimates thus explaining a paradox regarding the source of nutrition to the Amazon forest, and 120+/-40 tg are deposited in the Atlantic Ocean. The results are compared favorably with dust transport models for particle radius less than or equal to 12 microns. This study is a first example of quantitative use of MODIS aerosol for a geophysical study.

Kaufman, Y. J.↗

NASA NTRS2003

Dust Transport, Deposition and Radiative Effects Observed from MODIS

Carlson (1977) used satellite (AVHRR) observation of dust episodes 3 estimate that 90 tg of dust are emitted from Africa (0-30 N) to the Atlantic Ocean between June and August. MODIS systematic measurements of aerosol optical thickness (AOT) and the fraction of the AOT (f) due to the fine mode (see Remer et al abstract), are used to derive the column concentration, flux and deposition of African dust over the Atlantic Ocean. The main data set is for 2001 but the results are consistent with MODIS measurements from 2002. The analysis first determines the properties of maritime baseline aerosol (AOT=0.06, f=0.5); followed by linear scaling of the dust AOT and the anthropogenic AOT, based on MODIS measured values of the fraction "f" being 0.9 for anthropogenic aerosol and 0.5 for dust. NCEP winds are used in the analysis and are evaluated against observed dust movements between the Terra and Aqua passes (see Koren et al. abstract). Monthly values of dust transport and deposition are calculated. Preliminary results show that 280 tg of dust are emitted annually from Africa to the Atlantic Ocean between 20s and 30N, with 40 tg returning to Africa and Europe between 30N and 50N. 85 tg reach the Americas, with 130-150 tg are deposited in the Atlantic Ocean. The results are compared with dust transport models that indicate 110-230 tg of dust being deposited in the Ocean. It is interesting to note that the early estimates of Carlson (1977) and Carlson & Prosper0 (1972) are very close to our estimate from MODIS of 100 tg for the same latitude range and monthly period.

Kaufman, Y. J.↗

NASA NTRS1992

Numerical simulation of turbomachinery flows with advanced turbulence models

A three dimensional full Navier-Stokes (FNS) code is used to simulate complex turbomachinery flows. The code incorporates an explicit multistep scheme and solves a conservative form of the density averaged continuity, momentum, and energy equations. A compressible low Reynolds number form of the k-epsilon turbulence model, and a q-omega model and an algebraic Reynolds stress model have been incorporated in a fully coupled manner to approximate Reynolds stresses. The code is used to predict the viscous flow field in a backswept transonic centrifugal compressor for which laser two focus data is available. The code is also used to simulate the tip clearance flow in a cascade. The code has been extended to include unsteady Euler solutions for predicting the unsteady flow through a cascade due to incoming wakes, simulating rotor-stator interactions.

Lakshminarayana, B.↗

NASA NTRS1973

Forecasting the demand potential for STOL air transportation

A process for predicting the potential demand for STOL aircraft was investigated to provide a conceptual framework, and an analytical methodology for estimating the STOL air transportation market. It was found that: (1) schedule frequency has the strongest effect on the traveler's choice among available routes, (2) work related business constitutes approximately 50% of total travel volume, and (3) air travel demand follows economic trends.

Fan, S.↗