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Farfan, Bernardo

Publications and source records attributed to Farfan, Bernardo.

Extreme compression of planetary gases: High-accuracy pressure-density measurements of hydrogen-helium mixtures above fourfold compression

Hydrogen (H 2 ) and helium (He), the most abundant elements in the universe, pose a unique challenge in measuring the equation of state of the mixture, owing to their differing physical properties. There remains a need for data with high enough precision to discriminate between existing equation of state (EOS) mix models in order to understand the internal structure of gas-giant planets. Here, we have measured the EOS of precompressed H 2 - He mixtures at conditions directly relevant to the planetary interiors using hypervelocity gas guns and Sandia’s Z machine with less than 10% uncertainty in density, enabling validation of mixture models. We precompressed 50:50 molar mixtures of H 2 -He to 0.1–0.2 GPa and directly measured particle velocity (in gas-gun experiments) and shock velocities (in Z-machine experiments). To complement the experimental efforts, we also computed the Hugoniots of precompressed H 2 -He mixtures using density-functional-theory-based molecular dynamics. Furthermore, we observe approximately 3- to 4.3-fold density compression at pressures up to 44 GPa.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Samarium: from a distorted-fcc phase to melting under dynamic compression using in-situ x-ray diffraction

Abstract Lattice and electronic structure interactions for f -electrons are fundamental challenges for lanthanide equation of state development. Difficulties in first-principles calculations, such as density functional theory (DFT), emphasize the need for well-characterized experimental data. Here, we measure in-situ x-ray diffraction of shocked samarium (Sm) and temperature along the Hugoniot for the first time, providing direct evidence for phase transitions. We report direct evidence of a distorted fcc (dfcc) phase at 23 GPa. Shocked samarium melts from the dfcc phase starting at 33 GPa (1333 K), with complete melt at 40 GPa (1468 K). Previous work indicated shock melt at 27 GPa (1200 K), underscoring the significance of x-ray measurements for detecting phase transitions. Interestingly, our observed melting is in sharp contrast with the melting reported by a diamond anvil cell study. These experimental data can tightly constrain first principles calculations and serve as key touchstones for equation of state modeling.

36 MATERIALS SCIENCE↗

Dynamic compression of TiO 2 to 221 GPa

The high-pressure dynamic response of titanium dioxide (TiO 2 ) is not only of interest because of its numerous industrial applications but also because of its structural similarities to silica (SiO 2 ). We performed plate impact experiments in a two-stage light gas gun, at peak stresses from 64 to 221 GPa to determine the TiO 2 response along the Hugoniot. The lower stress experiment at 64 GPa shows an elastic behavior followed by an elastic–plastic transition, whereas the high stress experiments above 64 GPa show a single wave structure. Previous shock studies have shown the presence of high-pressure phases (HPP) I (26 GPa) and HPP II (100 GPa); however, our data suggest that the HPP I phase is stable up to 150 GPa. Using a combination of data from our current study and our previous Z-data, we determine that TiO 2 likely melts on the Hugoniot at 157 GPa. Furthermore, our data confirm that TiO 2 is not highly incompressible as shown by a previous study.

36 MATERIALS SCIENCE↗