NanoMOFs: little crystallites for substantial applications
Synthetic methods for the preparation of metal–organic framework crystallites in the nano-size regime and their potential applications are reviewed.
Chemistry↗
Engineering topics
Farha, O. K.
Publications and source records attributed to Farha, O. K..
Atomic layer deposition of Cu( i ) oxide films using Cu( ii ) bis(dimethylamino-2-propoxide) and water
To grow films of Cu 2 O, bis-(dimethylamino-2-propoxide)Cu( ii ), or Cu(dmap), is used as an atomic layer deposition precursor using only water vapor as a co-reactant.
catalysis (heterogeneous), materials and chemistry↗
Functionalised cyclodextrin-based metal–organic frameworks
A CD-MOF is prepared from amino-functionalized (blue moon) γ-CD, which permanently captures CO 2 as a carbamate (red moon).
Chemistry↗
Second-generation hexavalent molybdenum oxo-amidinate precursors for atomic layer deposition
Here, the synthesis of molybdenum oxo-amidinate complexes MoO 2 (R 2 AMD) 2 [AMD = N,N'-di-R-acetamidinate; R = Cy (2; cyclohexyl) and iPr (3)], and their characterization by 1 H, 13 C NMR, X-ray diffraction, and thermogravimetric analysis is reported. Quartz-crystal microbalance and X-ray photoelectron spectroscopic studies confirm that 3 is an improved ALD precursor versus the R = t-butyl derivative for MoO 3 film growth. Complex 3 is accessible in higher yields (80%+), is easier to handle without mass loss, and in conjunction with O 3 as the second ALD reagent, yields nitride-free MoO 3 films.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗