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Fegley, Bruce, Jr.

Publications and source records attributed to Fegley, Bruce, Jr..

At least 19 records

Chemical Weathering Kinetics of Basalt on Venus

The purpose of this project was to experimentally measure the kinetics for chemical weathering reactions involving basalt on Venus. The thermochemical reactions being studied are important for the CO2 atmosphere-lithosphere cycle on Venus and for the atmosphere-surface reactions controlling the oxidation state of the surface of Venus. These reactions include the formation of carbonate and scapolite minerals, and the oxidation of Fe-bearing minerals. These experiments and calculations are important for interpreting results from the Pioneer Venus, Magellan, Galileo flyby, Venera, and Vega missions to Venus, for interpreting results from Earth-based telescopic observations, and for the design of new Discovery class (e.g., VESAT) and New Millennium missions to Venus such as geochemical landers making in situ elemental and mineralogical analyses, and orbiters, probes and balloons making spectroscopic observations of the sub-cloud atmosphere of Venus.

Fegley, Bruce, Jr.↗

Kinetics of Thermochemical Reactions Important in the Venus Atmospheric Sulfur Cycle

The purpose of this project was to experimentally measure the rates of several thermochemical gas-solid reactions between sulfur gases in the Venus atmosphere and reactive minerals on the hot Venus surface. Despite the great importance of these reactions for the maintenance of significant amounts of sulfur gases (and thus for the maintenance of the global cloud cover) in the atmosphere of Venus, essentially no kinetic data are currently available for them.

Fegley, Bruce, Jr.↗

Lyman Alpha Photochemistry in the Solar Nebula

The purpose of the project "Lyman Alpha Photochemistry in the Solar Nebula" was to model photochemistry in the primitive solar nebula and the early solar systems. As part of the modeling, it was necessary to model the composition of the gas and dust accreted by the solar nebula. This final report contains a list of publications where the results of this project have been published.

Fegley, Bruce, Jr.↗

Sulfur Chemistry in the Wake of Comet Shoemaker-Levy 9

A curious and unexpected result of the impact of P/Shoemaker Levy 9 with Jupiter was the production of enormous amounts of molecular sulfur (S2). Here we show that S2 is the natural product of disequilibrium chemistry at low pressures in shocked Jovian air, its formation a byproduct of hydrogen recombination. The species observed by the Hubble Space Telescope (HST) - S2, CS2, and H2S - imply that the G fragment penetrated the NH4SH cloud but did not reach the water table. A typical impact within or below the NH4SH clouds produces about 0.03 - 0.1 impactor masses of S2. Because comets are relatively hydrogen-poor, SO2, not S2, is the major product of shocking a water-rich comet, while S2, CS2 and OCS are major products of a dessicated comet. In all cases we find that as the gas cools, S2 converts to the stable low temperature allotrope S8, although other chemical fates not modeled here might intervene first.

Zahnle, Kevin↗

Carbonate-sulfate volcanism on Venus?

Venusian canali, outflow channels, and associated volcanic deposits resemble fluvial landforms more than they resmeble volcanic features on Earth and Mars. Some canali have meandering habits and features indicative of channel migration that are very similar to meandering river channels and flood plains on Earth, venusian outflow channels closely resemble water-carved outflow channels on Mars and the Channeled Scabland in Washington, collapsed terrains at the sources of some venusian channels resemble chaotic terrains at the sources of martian outflow channels, venusian lava deltas are similar to bird's-foot deltas such as the Mississippi delta, and venusian valley networks indicate sapping. We have developed an alternative possibility that the lava had a water-like rheology and a melting point slightly greater than Venus' surface temperature, thus accounting for the unusual behavior of the lava. Unlike silicate lavas, some carbonatites (including carbonate-sulfate-rich liquids) have these properties; thus they can flow great distances while retaining a high fluidity, significant mechanical erosiveness, and substantial capacity to transport and deposit sediment. Venusian geochemistry and petrology are consistent with extensive eruptions of carbonatite lavas, which could have crustal and/or mantle origins. Venus' atmosphere (especially CO2, HCl, and HF abundances) and rocks may be in local chemical equilibrium, which suggests that the upper crust contains large amounts of calcite, anhydrite, and other salts. Chemical analyses indicate, according to some models, that Venusian rocks may contain 4-19% calcite and anhydrite. Mixtures of crustal salts could melt at temperatures a few tens to a few hundred Kelvins higher than Venus' surface temperature; hence, melting may be induced by modest endogenetic or impact heating. Salts may have many of the same geologic roles on Venus as water and ice have on Mars. A molten salt (carbonatite) 'aquifer' may exist beneath a few hundred meters to several kilometers of solidified salt-rich 'permafrost.' Many geologic features can be explained by carbonatite magmatism: (1) impact melting of crustal salts can explain crater outflows, (2) small, sustained eruptions from molten salt aquifers can explain sapping valleys, (3) large, sustained eruptions may explain canali and their flood plans, and (4) catastrophic outbursts amy have formed outflow channels and chaotic terrain. Landforms created by carbonate-rich lavas would be thermally stable on Venus' surface, though some minerals may weather to other solid substances.

Kargel, Jeffrey S.↗

Chemical models of the deep atmospheres of Jupiter and Saturn

New and updated chemical kinetic data, elemental abundances, and thermodynamic data are used for thermochemical equilibrium and, where relevant, thermochemical kinetic calculations of gas abundances and condensate stability in the hot, deep atmospheres of Jupiter and Saturn. Over 2000 compounds of all naturally occurring elements in the periodic table are considered. The calculations range from 298 to 2000 K and are done for adiabatic models of the two planetary atmospheres. The results predict the abundances of many gases which are potentially observable by the Galileo probe to Jupiter, by the Cassini mission to Saturn, and by Earth-based and Earth-orbital telescopes. In addition, the results also predict many new species which are potentially observable by a new generation of entry probes capable of penetrating deeper into the atmospheres of Jupiter and Saturn.

Fegley, Bruce, Jr.↗

A ferroelectric model for the low emissivity highlands on Venus

A model to explain the low emissivity venusian highlands is proposed utilizing the temperature-dependent dielectric constant of ferroelectric minerals. Ferroelectric minerals are known to occur in alkaline and carbonite rocks, both of which are plausible for Venus. Ferroelectric minerals possess extremely high dielectric constants (10(exp 5)) over small temperature intervals and are only required in minor (much less than 1%) abundances to explain the observed emissivities. The ferroelectric model can account for: (1) the observed reduction in emissivity with increased altitude, (2) the abrupt return to normal emissivities at highest elevations, and (3) the variations in the critical elevation observed from region to region.

Shepard, Michael K.↗

Lanthanide and actinide chemistry at high C/O ratios in the solar nebula

Chemical equilibrium calculations were performed to study the condensation chemistry of the REE and actinides under the highly reducing conditions which are necessary for the formation of the enstatite chondrites. Our calculations confirm that the REE and actinides condensed into oldhamite (CaS), the major REE and actinide host phase in enstatite chondrites, at a carbon-oxygen (C/O) ratio not less than 1 in an otherwise solar gas. Five basic types of REE abundance patterns, several of which are analogous to REE abundance patterns observed in the Ca, Al-rich inclusions in carbonaceous chondrites, are predicted to occur in meteoritic oldhamites. All of the reported REE patterns in oldhamites in enstatite chondrites can be interpreted in terms of our condensation calculations. The observed patterns fall into three of the five predicted categories. The reported Th and U enrichments and ratios in meteoritic oldhamites are also consistent with predictions of the condensation calculations. Pure REE sulfides are predicted to condense in the 10 exp -6 to 10 exp -9 bar range and may be found in enstatite chondrites if they formed in this pressure range.

Lodders, Katharina↗

Chemical models of volcanic outgassing on Mars

During the MSATT workshop in Boulder, CO, several participants emphasized the importance of constraints on the composition and temporal evolution of outgassed volatiles on Mars. I present the results of some preliminary calculations that model the composition of volcanic gases as a function of temperature, pressure, oxygen fugacity, and quench function of temperature. These results can be used in combination with cosmochemical models for the accretion of Mars to assess the plausibility of different atmospheric compositions during the planet's early history.

Fegley, Bruce, Jr.↗

Atmosphere-surface interactions and atmospheric evolution on Mars

A knowledge of the original volatile endowment of Mars is essential for any discussion of atmospheric loss on this planet. Cosmochemical models which postulate that planetary bulk compositions and volatile contents were controlled by the radial temperature profile in the solar nebula, and estimated bulk compositions based on the assumption that Mars is the parent body for the SNC meteorites predicts that Mars is volatile-rich. However, contrary views can also be found. For illustrative purposes, it is assumed that Mars was volatile-rich initially like the Earth. Taking terrestrial volatiles as the sum of the atmospheric, crustal, and oceanic volatiles and assuming that Mars accreted with the same volatile content on a g/g basis, the volatile endowments for an Earth-like Mars correspond to approximately 14 bars CO2, 800 mbars N2, and 1.2 km H2O. Subsequent topics discussed are: composition of outgassing volatiles; rates of present day atmospheric-surface reactions; constraints on CO2 loss via carbonate formation; constraints on H2O loss; and loss of other volatiles.

Fegley, Bruce, Jr.↗

Venus surface mineralogy - Observational and theoretical constraints

Earth-based, earth-orbital, and spacecraft observations of the atmosphere and surface of Venus, thermodynamic models of atmosphere-lithosphere interactions, and where available kinetic data on relevant gas-solid reactions to place constraints on the mineralogy of the surface of Venus are used. Which minerals and mineral assemblages are stable on the surface of Venus and which, if any, of these minerals are involved in controlling the abundances of reactive gases in the atmosphere of Venus. It is concluded by identifying key issues facing us today about the mineralogy and geochemistry of the surface of Venus and suggest experimental, observational, and theoretical studies that can improve knowledge of these important questions are discussed.

Fegley, Bruce, Jr.↗

Chemistry of atmosphere-surface interactions on Venus and Mars

Earth-based, earth-orbital, and spacecraft observational data are used in the present evaluation of Venus atmosphere-surface interactions to quantitatively characterize the reactions between C, H, S, Cl, F, and N gases and plausible surface minerals. Calculation results are used to predict stable minerals and mineral assemblages on the Venus surface, in order to ascertain which (if any) of the atmospheric gases are buffeted by mineral assemblages. Chemical equilibrium calculations using extant thermodynamic data on scapolite minerals predict that carbonate-bearing scapolite and sulfate meionite are unstable on the surface of Venus, while chloride-bearing scapolite is stable.

Fegley, Bruce, Jr.↗

Workshop on Innovative Instrumentation for the In Situ Study of Atmosphere-Surface Interactions on Mars

The speakers in the first session of the workshop addressed some of the continuing enigmas regarding the atmospheric composition, surface composition, and atmosphere-surface interactions on Mars; provided a description of a database of proposed payloads and instruments for SEI missions that is scheduled to be accessible in 1993; discussed potential uses of atmospheric imaging from landed stations on Mars; and advocated the collection and employment of high-spectral-resolution reflectance and emission data.

Fegley, Bruce, Jr.↗

MSATT Workshop on Innovative Instrumentation for the In Situ Study of Atmosphere-Surface Interactions on Mars

Papers accepted for the Mars Surface and Atmosphere Through Time (MSATT) Workshop on Innovative Instruments for the In Situ Study of Atmosphere-Surface Interaction of Mars, 8-9 Oct. 1992 in Mainz, Germany are included. Topics covered include: a backscatter Moessbauer spectrometer (BaMS) for use on Mars; database of proposed payloads and instruments for SEI missions; determination of martian soil mineralogy and water content using the Thermal Analyzer for Planetary Soils (TAPS); in situ identification of the martian surface material and its interaction with the martian atmosphere using DTA/GC; mass spectrometer-pyrolysis experiment for atmospheric and soil sample analysis on the surface of Mars; and optical luminescence spectroscopy as a probe of the surface mineralogy of Mars.

Fegley, Bruce, Jr.↗

Thermodynamic models of the chemistry of lunar volcanic gases

Thermodynamic models and mass-balance arguments are used to constrain the chemistry of lunar volcanic gases. The results predict that lunar gases were dominated by reduced C and S gases such as CO, COS, CS2, S2. The more oxidized gases CO2 and SO2 were also important, but only in limited temperature ranges. Gases such as Cl2, CCl4, and CF4 were more abundant than HF and HCl, which were the two major H compounds in the lunar gases. Chlorides and fluorides were important species for transporting many volatile and ore-forming metals, and the implications for fractionating and concentrating metals into lunar ore-deposits merit further study.

Fegley, Bruce, Jr.↗

Spectroscopy and chemistry of the atmosphere of Uranus

A comprehensive review of the chemistry and spectroscopy of the Uranian atmosphere is presented by means of earth-based, earth-orbital, and Voyager 2 observations covering the UV, visible, infrared, and radio wavelength regions. It is inferred from these observations, in concert with the average density of about 1.3 g/cu cm, that the Uranian atmosphere is enriched in heavy elements relative to solar composition. Pre-Voyager earth-based observations of CH4 bands in the visible region and Voyager radio occultation data imply a CH4/H2 volume mixing ratio of about 2 percent corresponding to an enrichment of approximately 24 times the solar value of 0.000835. In contrast to CH4, microwave observations indicate an apparent depletion of NH3 in the 155-to-200-K region of the atmosphere by 100 to 200 times relative to the solar NH3/H2 mixing ratio of -0.000174. It is suggested that the temporal and latitudinal variations deduced for the NH3/H2 mixing ratio in this region of the Uranian atmosphere are due to atmospheric circulation effects.

Fegley, Bruce, Jr.↗

The applications of chemical thermodynamics and chemical kinetics to planetary atmospheres research

A review of the applications of chemical thermodynamics and chemical kinetics to planetary atmospheres research during the past four decades is presented with an emphasis on chemical equilibrium models and thermochemical kinetics. Several current problems in planetary atmospheres research such as the origin of the atmospheres of the terrestrial planets, atmosphere-surface interactions on Venus and Mars, deep mixing in the atmospheres of the gas giant planets, and the origin of the atmospheres of outer planet satellites all require laboratory data on the kinetics of thermochemical reactions for their solution.

Fegley, Bruce, Jr.↗

Estimation of the rate of volcanism on Venus from reaction rate measurements

Laboratory rate data for the reaction between SO2 and calcite to form anhydrite are presented. If this reaction rate represents the SO2 reaction rate on Venus, then all SO2 in the Venusian atmosphere will disappear in 1.9 Myr unless volcanism replenishes the lost SO2. The required volcanism rate, which depends on the sulfur content of the erupted material, is in the range 0.4-11 cu km of magma erupted per year. The Venus surface composition at the Venera 13, 14, and Vega 2 landing sites implies a volcanism rate of about 1 cu km/yr. This geochemically estimated rate can be used to determine if either (or neither) of two discordant geophysically estimated rates is correct. It also suggests that Venus may be less volcanically active than the earth.

Fegley, Bruce, Jr.↗