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Feng, Z.

Publications and source records attributed to Feng, Z..

At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Electronegativity-Guided Site Differentiation in High-Entropy Alloy for pH-universal Hydrogen Evolution Reactions

Enhancing the intrinsic activity of transition metal catalysts for the hydrogen evolution reaction (HER) remains a critical challenge in sustainable energy conversion. Herein, we report an electronegativity-guided site differentiation strategy in a single-phase CoNiCuMoW high-entropy alloy (HEA) via electrodeposition by incorporating high-electronegativity 4d/5d orbital transition metals (Mo, W) into the face-centered cubic (fcc) matrix (CoNiCu). The as-synthesized HEA demonstrates exceptional HER performance in all pH conditions, delivering an outstanding overpotential of 65 mV (alkaline), 28 mV (acidic), and 155 mV (neutral) at a current density of 100 mA cm−2, showing performance comparable to commercial Pt/C and has excellent long-term stability at high current density (1 A cm−2, 1000 h). X-Ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations reveal that the incorporation of Mo/W simultaneously alters the local coordination environment and induces element-dependent charge redistribution, accompanied by a system-level d-band center downshift, thereby optimizing the hydrogen binding strength across multimetallic sites. Meanwhile, oxophilic Mo/W sites lower the water dissociation energy barrier. These synergistic effects collectively enable efficient and durable pH-universal HER performance.

Wu, Yutong↗
DOE OSTI2023

Using in-situ strain measurements to evaluate the accuracy of stress estimation procedures from fracture injection/shut-in tests

Fracture injection/shut-in tests are commonly used to measure the state of stress. Injection creates a hydraulic fracture (or in some cases, opens a preexisting fracture), and then the pressure after shut-in is monitored to identify fracture closure. Different interpretation procedures have been proposed for estimating closure, and the procedures sometimes yield significantly different results. In this study, direct, in-situ strain measurements are used to observe fracture reopening and closure. The tests were performed as part of the EGS Collab project, a mesoscale project performed at 1.25 and 1.5 km depth at the Sanford Underground Research Facility. The tests were instrumented with the SIMFIP tool, a double-packer probe with a high-resolution three-dimensional borehole displacement sensor. The measurements provide a direct observation of the fracture closure signature, enabling a high-fidelity estimate of the fracture closure stress (ie, the normal stress on the fracture). In two of the four tests, injection created an opening mode fracture, and so the closure stress can be interpreted as the minimum principal stress. In the other two tests, injection probably opened preexisting natural fractures, and so the closure stress can be interpreted as the normal stress on the fractures. The strain measurements are compared against different proposed methods for estimating closure stress from pressure transients. The shut-in transients are analyzed with two techniques that are widely used in the field of petroleum engineering – the ‘tangent’ method and the ‘compliance’ method. In three of the four tests, the tangent method significantly underestimates the closure stress. The compliance method is reasonably accurate in all four tests. Closure stress is also interpreted using two other commonly-used methods – ‘first deviation from linearity’ and the method of Hayashi and Haimson. In comparison with the SIMFIP data, these methods tend to overestimate the closure stress, evidently because they identify closure from early-time transient effects, such as near-wellbore tortuosity. In two of the tests, microseismic imaging provides an independent estimate of the size of the fracture created by injection. When combined with a simple mass balance calculation, the SIMFIP stress measurements yield predictions of fracture size that are reasonably consistent with the estimates from microseismic. In conclusion, the calculations imply an apparent fracture toughness 2-3x higher than typical laboratory-derived values.

58 GEOSCIENCES↗
DOE OSTI2021

Constraining maximum event magnitude during injection-triggered seismicity

Abstract Understanding mechanisms controlling fluid injection-triggered seismicity is key in defining strategies to ameliorate it. Recent triggered events (e.g. Pohang, Mw 5.5) have exceeded predictions of average energy release by a factor of >1000x, necessitating robust methodologies to both define critical antecedent conditions and to thereby constrain anticipated event size. We define maximum event magnitudes resulting from triggering as a function of pre-existing critical stresses and fluid injection volume. Fluid injection experiments on prestressed laboratory faults confirm these estimates of triggered moment magnitudes for varied boundary conditions and injection rates. In addition, observed ratios of shear slip to dilation rates on individual faults signal triggering and may serve as a measurable proxy for impending rupture. This new framework provides a robust method of constraining maximum event size for preloaded faults and unifies prior laboratory and field observations that span sixteen decades in injection volume and four decades in length scale.

58 GEOSCIENCES↗
DOE OSTI2020

The ongoing need for high-resolution regional climate models: Process understanding and stakeholder information

Regional climate modeling addresses our need to understand and simulate climatic processes and phenomena unresolved in global models. High resolution models are generally more skillful in simulating extremes, such as heavy precipitation, strong winds, and severe storms. In addition, research has shown that fine-scale features such as mountains, coastlines, lakes, irrigation, land use, and urban heat islands can substantially influence a region’s climate and its response to changing forcings. Regional climate simulations explicitly simulating convection are now being performed, providing an opportunity to illuminate new physical behavior that previously was represented by parameterizations with large uncertainties. Regional and global models are both advancing toward higher resolution, as computational capacity increases. However, the resolution and ensemble size necessary to produce a sufficient statistical sample of these processes in global models has proven too costly for contemporary supercomputing systems. Regional climate models are thus indispensable tools that complement global models for understanding regional climate variability and change, and are critical for supporting societal responses to changing climate.

Gutowski, William↗
DOE OSTI2018

Strain partition and rupture analysis of notched tensile multilayered steel specimens

Highlights: • In situ SEM tensile experiments were performed to investigate the fracture processes. • In situ synchrotron x-ray diffraction were carried out to study the microscopic deformation in MLS steel. • The changing trends of the strain in the austenite layer and martensitic layer have been revealed. - Abstract: Multilayered steel composites consisting of alternating martensitic and austenite layers were successfully fabricated with a combination of high strength and ductility. In situ SEM tensile experiments were performed to investigate the fracture processes. Results indicated that the martensitic layer distributed between two ductile austenite layers has better deformation ability, and the dimple fracture mode dominated the fracture of the whole specimen. In situ synchrotron microbeam X-ray diffraction experiments were carried out to study the microscopic deformation in austenitic layer and martensitic layer ahead of notch root under incremental tensile loading. Results indicated that for austenite layer, the maximum strain is located in the middle of the layer at the lower applied load. When at the higher applied load, larger strain is concentrated on the notch root. For martensitic layer, uniform strain is distributed at the region at the lower applied load, with increasing the applied load, small strain appears in the middle of martensitic layer. However, the variation in the strain in the martensitic layer is relatively smaller, which is actually affected by both the notch and the ferrite content in the martensitic layer. The changing trends of the strain in the austenite layer and martensitic layer can still show the better combination of brittle martensitic phase and ductile austenite phase.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Microstructures and mechanical properties of a welded CoCrFeMnNi high-entropy alloy

The response of the CoCrFeMnNi high-entropy alloy to weld thermal cycles was investigated to determine its applicability as an engineering structural material. Two processes were used: high-energy-density, low-heat-input electron beam (EB) welding and low-energy-density, high-heat-input gas tungsten arc (GTA) welding. Weldability was determined through comprehensive microstructural and mechanical property characterisation of the welds. The welds did not develop solidification cracking or heat-affected zone cracks. The microstructures in weld fusion zones are similar to that in the as-cast materials, consisting of large columnar grains with dendrite. The dendrite arm spacing and the extent of elemental segregation were less in the welds than in the cast ingot, and also were less pronounced in the EB weld than in the GTA weld. Compositional microsegregation between dendritic cores and interdendritic regions of the welds was insignificant. Both welds exhibited slightly higher yield strengths than the base metal. The EB weld possessed comparable tensile strength and ductility to that of the base metal. In comparison, the GTA weld maintained ∼80% of the base metal's tensile strength and 50% of the ductility.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Harmonic decomposition of three-particle azimuthal correlations at energies available at the BNL Relativistic Heavy Ion Collider

Here, we present measurements of three-particle correlations for various harmonics in Au+Au collisions at energies ranging from √ s NN=7.7 to 200 GeV using the STAR detector. The quantity < cos(mΦ 1 +nΦ 2 –(m+n)Φ 3 ) >, with Φ being the azimuthal angles of the particles is evaluated as a function of √ s NN, collision centrality, transverse momentum, p T , pseudorapidity difference, Δη, and harmonics (m and n). These data provide detailed information on global event properties such as the three-dimensional structure of the initial overlap region, the expansion dynamics of the matter produced in the collisions, and the transport properties of the medium. A strong dependence on Δη is observed for most harmonic combinations, which is consistent with breaking of longitudinal boost invariance. An interesting energy dependence is observed when one of the harmonics m,n, or m+n is equal to two, for which the correlators are dominated by the two-particle correlations relative to the second-harmonic event plane. These measurements can be used to constrain models of heavy-ion collisions over a wide range of temperature and baryon chemical potential.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2018

Measurement of the H Λ 3 lifetime in Au+Au collisions at the BNL Relativistic Heavy Ion Collider [Measurement of the H Λ 3 lifetime in Au+Au collisions at the Relativistic Heavy Ion Collider]

Here, an improved measurement of the 3 Λ H lifetime is presented. In this paper, the mesonic decay modes 3 Λ H → 3 He + π – and 3 Λ H → d + p + π – are used to reconstruct the 3 Λ H from Au+Au collision data collected by the STAR collaboration at Relativistic Heavy Ion Collider (RHIC). A minimum χ2 estimation is used to determine the lifetime of τ = 142 +24 –21 (stat.) ± 29 (syst.) ps. This lifetime is about 50% shorter than the lifetime τ = 263 ± 2 ps of a free Λ, indicating strong hyperon-nucleon interaction in the hypernucleus system. The branching ratios of the mesonic decay channels are also determined to satisfy B.R. ( 3 He+π – )/( B.R. ( 3 He+π – ) + B.R. (d+p+π – ) ) = 0.32 ± 0.05 (stat.) ± 0.08 (syst.). Our ratio result favors the assignment J( 3 Λ H) = 1/2 over J( 3 Λ H) = 3/2. These measurements will help to constrain models of hyperon-baryon interactions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2017

Coherent diffractive photoproduction of ρ 0 mesons on gold nuclei at 200 GeV/nucleon-pair at the Relativistic Heavy Ion Collider

Here, the STAR Collaboration reports on the photoproduction of π + π - pairs in goldgold collisions at a center-of-mass energy of 200 GeV/nucleon-pair. These pion pairs are produced when a nearly-real photon emitted by one ion scatters from the other ion. We fit the π + π - invariant mass spectrum with a combination of 0 and ! resonances and a direct π + π - continuum. This is the first observation of the ! in ultra-peripheral collisions, and the first measurement of ρ - ω interference at energies where photoproduction is dominated by Pomeron exchange.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2017

Bulk properties of the medium produced in relativistic heavy-ion collisions from the beam energy scan program

We present measurements of bulk properties of the matter produced in Au+Au collisions at $\sqrt{s}$$_ {NN}$= 7.7, 11.5, 19.6, 27, and 39 GeV using identified hadrons (π ± , K ± , p, and $\bar{p}$) from the STAR experiment in the Beam Energy Scan (BES) Program at the Relativistic Heavy Ion Collider (RHIC). Midrapidity (| y | < 0.1) results for multiplicity densities dN / dy, average transverse momenta $\langle$pT$\rangle$, and particle ratios are presented. The chemical and kinetic freeze-out dynamics at these energies are discussed and presented as a function of collision centrality and energy. These results constitute the systematic measurements of bulk properties of matter formed in heavy-ion collisions over a broad range of energy (or baryon chemical potential) at RHIC.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗