Engineering topics
Publications and source records attributed to Flamm, D. L..
Plasma reaction chamber removes trace contaminants from spacecraft, submarines, and other closed environments by oxidizing contaminants to produce carbon dioxide and water. Contaminants are alcohols, esters, hydrogen sulfide, and ammonia. Others are lubricant solvents such as Freons, aromatics, and Ketones. Contaminants are removed from chamber by scrubber.
A radio frequency glow discharge reactor is described for removing trace oxidizable contaminants from an oxygen bearing atmosphere. The reaction chamber is defined by an inner metal electrode facing a dielectric backed by an outer conductive electrode. In one embodiment, a conductive liquid forms the conductor of an outer electrode and cools the dielectric. A resonator coupled to a variable radio frequency source generates the high voltages for creating a glow discharge in the chamber at a predetermined pressure whereby the trace contaminants are oxidized into a few simple non-toxic products that may be easily recovered. The corresponding process for removal of trace contaminants from an oxygen-bearing atmosphere with high efficiency independent of the concentration level is also disclosed.
The radiofrequency discharge, previously shown to oxidize trace levels of methane in oxygen, was studied with contaminated air at 50, 600, and 760 torr. As with oxygen, the concentration of methane traces could be reduced by several orders of magnitude, and no organic reaction products were detected in the effluent; however, substantial concentrations of NOx (0.1-6%) were formed during treatment. The concentration of NOx was decreased by using a large diameter electrode. There is evidence that the process will oxidize N2 and NO as well as organic impurities in oxygen or oxygen/inert gas atmospheres.
The production of ozone and nitric oxides and the oxidation of two organic contaminants, methane and acetylene, were studied in the corona discharge of a model cylindrical electrostatic precipitator. Both air and oxygen streams were passed through the discharge while current, voltage, electrode/wall radius ratio, residence time and wall temperature were varied. Under all conditions using air, much more ozone was produced in the negative than in the positive corona, in agreement with qualitative data reported in the literature. However, using oxygen, as much as three to four times more ozone is produced by the positive corona. Over a wide range of conditions ozone production is proportional to current. Limited analyses of nitric oxides formation in air indicated that levels were higher in the negative than in the positive corona. In contrast to previous work using an RF discharge, methane contamination was not removed by the corona discharge. However, the oxidation of acetylene was affected by the discharge and could not be accounted for by homogeneous ozonation alone.
An 11.8 MHz glow discharge was used to oxidize trace levels of methane in oxygen. The concentration of methane can be reduced by three orders of magnitude. The effects of power (0-400 W), flow rate (10-1000 cc-STP/min) and concentration (70-8000 ppm) were investigated at pressures ranging from 50 torr to almost 1 atm. No organic reaction products were detected in the treated gas stream. The process may prove useful for the removal of atmospheric trace contaminants at ambient pressure.