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Frederick, John E.

Publications and source records attributed to Frederick, John E..

18 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Scientific Studies in Association with the Halogen Occultation Experiment

This work examines measurements of ozone, NO, NO2, and HCl made by the Halogen Occultation Experiment (HALOE) to track chemical change in the stratosphere. In addition, HALOE observations of two long-lived species, HF and CH4, are used as tracers to distinguish between change due to transport processes and change due to chemistry. The first study investigates the response of NO(x), (NO and NO2) and ozone to the presence of large amounts of sulfate aerosol in the stratosphere following the 1991 eruption of Mount Pinatubo. As the Pinatubo aerosol cleared the atmosphere at 17 mb (about 27-28 km), the partitioning of total reactive nitrogen shifted more toward NO(x), and ozone amounts declined. This trend is opposite that observed at lower altitudes. The second study examines the chemical aftermath of severe ozone depletion over Antarctica in spring. When ozone levels drop to a threshold amount (about 1 ppm near 20 km), the partitioning of the total chlorine family shifts rapidly from reactive species to the reservoir molecule HCl. This sudden repartitioning shuts down further ozone loss and may be significant as filaments of air peel off the polar vortex and mix with mid-latitude air.

Mickley, Lorretta J.↗
NASA NTRS1996

Radiative Transfer in the Lower Atmosphere Based on TOMS/ADEOS Measurements

The long-term objective of this research is to develop and apply methods to compute the solar ultraviolet (UV) spectral irradiance at the earth's surface using information to be provided by the TOMS/ADEOS data set. The broad philosophy is to view the TOMS measurements as a probe of the radiative transfer properties of the earth's atmosphere. Prior to the launch of ADEOS, we have focused on analysis of the Nimbus 7 TOMS data base as well as the development of numerical models for eventual use with ADEOS measurements. The emphasis of recent work has been on numerical modeling of the radiative effects of cloudy skies in the UV part of the spectrum.

Frederick, John E.↗
NASA NTRS1994

Ozone within the El Chichon aerosol cloud inferred from solar backscatter ultraviolet continuous-scan measurements

Large amounts of SO2 injected into the stratosphere by the El Chichon volcanic eruption greatly enhanced the sulfuric acid aerosol loading. According to laboratory studies, the increase in aerosol surface area would lead to a loss of ozone. Radiation measurements from the solar backscatter ultraviolet spectroradiometer are used to probe the absorbing and scattering properties of the stratosphere after the eruption. The backscattered radiation is enhanced for wavelengths greater than 290 nm, with a peak at about 302 nm. The enhancements associated with aerosol backscattering and ozone change can be separated. A decrease in column ozone of 8 to 30 Dobson units was deduced within the aerosol layer at an altitude between 20 and 30 km following the month of the eruption.

Wen, Guoyong↗
NASA NTRS1993

Scientific studies in association with the Shuttle Solar Backscatter Ultraviolet (SSBUV) project

During the past reporting period efforts focused on performing detailed comparisons between measurements made by the SBUV/2 V instruments carried on NOAA-9 and NOAA-11 and the first three flights of the Shuttle Solar Backscatter Ultraviolet (SSBUV) project. The quantities to be compared are the measurables, being the ratio of emergent radiance (I) in the vertical direction to the incoming solar irradiance (F). The backscatter albedo, A(w,j), was defined by: A(w,j) = I(w,j)/F(w,j) where w = 1,2,..., 12 refers to wavelength, and j indicates the instrument and flight on which the data were obtained. The comparisons to be made are NOAA-9 to SSBUV-1, NOAA-11 to SSBUV-2, and NOAA-11 to SSBUV-3. For the comparisons the N-values contained in the data files supplied by GSFC were converted to albedos via: A(w,j) = 10(exp N(w,j)/100). The comparisons described were designed to characterize the differences between the NOAA and SSBUV data sets.

Frederick, John E.↗
NASA NTRS1993

The Halogen Occultation Experiment

The Halogen Occultation Experiment (HALOE) uses solar occultation to measure vertical profiles of O3, HCl, HF, CH4, H2O, NO, NO2, aerosol extinction, and temperature versus pressure with an instantaneous vertical field of view of 1.6 km at the earth limb. Latitudinal coverage is from 80 deg S to 80 deg N over the course of 1 year and includes extensive observations of the Antarctic region during spring. The altitude range of the measurements extends from about 15 km to about 60-130 km, depending on channel. Experiment operations have been essentially flawless, and all performance criteria either meet or exceed specifications. Internal data consistency checks, comparisons with correlative measurements, and qualitative comparisons with 1985 atmospheric trace molecule spectroscopy (ATMOS) results are in good agreement. Examples of pressure versus latitude cross sections and a global orthographic projection for the September 21 to October 15, 1992, period show the utility of CH4, HF, and H2O as tracers, the occurrence of dehydration in the Antarctic lower stratosphere, the presence of the water vapor hygropause in the tropics, evidence of Antarctic air in the tropics, the influence of Hadley tropical upwelling, and the first global distribution of HCl, HF, and NO throughout the stratosphere. Nitric oxide measurements extend through the lower thermosphere.

Russell, James M., III↗
NASA NTRS1992

Trends in column ozone based on TOMS data - Dependence on month, latitude, and longitude

On the basis of the TOMS satellite column ozone data in latitudes 70 deg S-70 deg N from November 1978 to May 1990, a statistical model is used to estimate the trends in ozone as a function of latitude, longitude, and month. The trends in the TOMS ozone data are highly seasonal and dependent on location. Near the equator, the estimated monthly trends are not significantly different from zero. For high latitudes, most of the estimated monthly trends are negative. In January, February, and March, there are some positive trend estimates in the western hemisphere around latitude 60 deg N. The most negative trends for these three months also appear in the high latitudes of the northern hemisphere. Starting in June, more negative trends appear in the latitudes 50 deg S-70 deg S than the trends in the rest of the world considered. A large depletion develops during the spring time (September to November) in the southern high-latitude region, and the area of peak ozone decline is moving eastward during the period. The largest negative trends (about -29 percent per decade) for the area considered in this study appear in October around the latitude 70 deg S and longitudes 20 deg W-100 deg W region. For the northern hemisphere, the year-round trend estimates for latitudes 30 deg N-70 deg N range from -0.96 percent to -7.43 percent per decade. In the latitudes 30 deg N-50 deg N, the winter trend estimates are more negative than those for the summer and the fall. However, this pattern did not hold for latitudes 50 deg N-70 deg N.

Niu, Xufeng↗
NASA NTRS1992

A contribution toward understanding the biospherical significance of Antarctic ozone depletion

The paper presents and compares measurements of biologically active UV radiation made by the NSF scanning spectroradiometer (UV-monitor) at Palmer Station, Antarctica, during the Austral springs of 1988, 1989, and 1990. Column ozone abundance above Palmer Station is computed from these measurements using a multiple wavelength algorithm. Two contrasting action spectra are employed to estimate the biologically relevant dose from the spectral measurements: a standard weighting function for damage to DNA, and a new action spectrum representing the potential for photosynthesis inhibition in Antarctic phytoplankton. The former weights only UV-B wavelengths (280-320 nm) and gives the most weight to wavelengths shorter than 300 nm, while the latter includes large contributions out to 355 nm. Ozone abundances and dose-weighted irradiances provided by the NSF UV-monitor are used to derive the radiation amplification factors for both DNA- and phytoplankton-effective irradiance.

Lubin, Dan↗
NASA NTRS1991

Ultraviolet radiation changes

A major consequence of ozone depletion is an increase in solar ultraviolet (UV) radiation received at the Earth's surface. This chapter discusses advances that were made since the previous assessment (World Meteorological Organization (WMO)) to our understanding of UV radiation. The impacts of these changes in UV on the biosphere are not included, because they are discussed in the effects assessment.

Mckenzie, Richard L.↗
NASA NTRS1990

An approach to the detection of long-term trends in upper stratospheric ozone from space

A central problem in the detection of long-term trends in the upper stratospheric ozone from orbiting remote sensors involves the separation of instrument drifts from true geophysical changes. Periodic flights of a Solar Backscatter Ultraviolet radiometer (SSBUV) on the Space Shuttle will allow the detection of drifts in optically identical sensors (SBUV/2) carried on operational satellites. A detailed simulation of the SSBUV and SBUV/2 datasets defines the accuracy that can be attained by the in-orbit calibration procedure. The repeatability of the SSBUV calibration from one flight to the next is the most critical variable in the analysis. A repeatability near + or - 1.0 percent is essential for detection and correction of drifts in the SBUV/2 radiance measurements. The simulations show that true geophysical trends in backscattered radiance can be inferred to an accuracy of approximately + or - 1.0 percent per decade when SSBUV flies approximately once per year and provides a precise calibration correction to the SBUV/2 dataset over a full decade.

Frederick, John E.↗
NASA NTRS1989

The ultraviolet radiation environment of Antarctica - McMurdo Station during September-October 1987

Daily data from the Nimbus-7 TOMS were combined with a model of atmospheric radiative transfer to compute the time evolution of ultraviolet irradiance, at wavelengths from 290 to 350 nm, incident on McMurdo Station during September-October 1987. Large changes in column ozone occur as the polar vortex moves over the site. This is accompanied by correspondingly large variations in UV radiation at the earth's surface. At a wavelength near 305 nm, the irradiance in early October exceeds values appropriate to an unperturbed ozone layer by a factor of 5-6. As December 21 approaches, the noontime UV irradiance increases, irrespective of changes in ozone.

Lubin, Dan↗
NASA NTRS1989

The detection and interpretation of long-term changes in ozone from space

Long-term measurements of backscattered ultraviolet radiances, now being acquired by orbiting monochromators, will provide the basis for seeking trends in atmospheric ozone. The unambiguous detection of ozone trends on decadal time scales demands a data set that is essentially free of instrument drifts. Periodic flights of an ultraviolet monochromator on the space shuttle will provide an independent means of evaluating the long-term stability of identical instruments operating on free-flying satellites. A successful calibration of the free-flying sensors using the shuttle instrument places strict demands on calibration repeatability from one flight to the next. In addition, spatial and temporal variability in cloud cover could pose further complications in carrying out these in-flight calibrations.

Frederick, John E.↗
NASA NTRS1988

Ultraviolet radiation levels during the Antarctic spring

The decrease in atmospheric ozone over Antarctica during spring implies enhanced levels of ultraviolet (UV) radiation received at the earth's surface. Model calculations show that UV irradiances encountered during the occurrence of an Antarctic 'ozone hole' remain less than those typical of a summer solstice at low to middle latitudes. However, the low ozone amounts observed in October 1987 imply biologically effective irradiances for McMurdo Station, Antarctica, that are comparable to or greater than those for the same location at December solstice. Life indigenous to Antarctica thereby experiences a greatly extended period of summerlike UV radiation levels.

Frederick, John E.↗
NASA NTRS1988

The budget of biologically active ultraviolet radiation in the earth-atmosphere system

This study applies the concept of a budget to describe the interaction of solar ultraviolet (UV) radiation with the earth-atmosphere system. The wavelength ranges of interest are the biologically relevant UV-B between 280 and 320 nm and the UV-A from 32000 to 400 nm. The Nimbus 7 solar backscattered ultraviolet (SBUV) instrument provides measurements of total column ozone and information concerning cloud cover which, in combination with a simple model of radiation transfer, define the fractions of incident solar irradiance absorbed in the atmosphere, reflected to space, and absorbed at the ground. Results for the month of July quantify the contribution of fractional cloud cover and cloud optical thickness to the radiation budget's three components. Scattering within a thick cloud layer makes the downward radiation field at the cloud base more isotropic than is the case for clear skies. For small solar zenith angles, typical of summer midday conditions, the effective pathlength of this diffuse irradiance through tropospheric ozone is greater than that under clear-sky conditions. The result is an enhanced absorption of UV-B radiation in the troposphere during cloud-covered conditions. Major changes in global cloud cover or cloud optical thicknesses could alter the ultraviolet radiation received by the biosphere by an amount comparable to that predicted for long-term trends in ozone.

Frederick, John E.↗
NASA NTRS1988

The detection and interpretation of long-term changes in ozone from space

Long-term measurements of backscattered ultraviolet radiances, now being acquired by orbiting monochromators, will provide the basis for seeking trends in atmospheric ozone. The unambiguous detection of ozone trends on decadal time scales demands a data set that is essentially free of instrument drifts. Periodic flights of an ultraviolet monochromator on the space shuttle will provide an independent means of evaluating the long-term stability of identical instruments operating on free-flying satellites. A successful calibration of the free-flying sensors using the shuttle instrument places strict demands on calibration repeatability from one flight to the next. In addition, spatial and temporal variability in cloud cover could pose further complications in carrying out these in-flight calibrations.

Frederick, John E.↗
NASA NTRS1987

TOMS as a monitor of the ultraviolet radiation environment: Applications to photobiology

The flux of biologically relevant ultraviolet radiation that reaches the surface of the Earth varies with the ozone amount, surface reflectivity, and cloudcover. The Total Ozone Mapping Spectrometer (TOMS) provides information relevant to all three items. A recent application of satellite-based ozone measurements has been to develop climatologies of the biologically significant UV-B radiation reaching the Earth's surface. A growing body of research suggests that UV-B radiation tends to suppress the immune system of laboratory mice. At tropical latitudes, it is likely that parasitical diseases develop most readily in people who have experienced immune system suppression from UV-B exposure. The computed distribution of surface radiation combined with information on disease incidence may clarify the role of UV-B as a suppressor of the human immune system. TOMS used in conjunction with radiative transfer calculations can provide information of relevance in photobiology.

Frederick, John E.↗
NASA NTRS1987

The detection and interpretation of long-term atmospheric change: Tasks in association with the shuttle solar backscatter ultraviolet spectral radiometer

The objectives are to develop techniques to detect and remove long-term instrument drifts from the operational Solar Backscatter Ultraviolet (SBUV/2) data base using periodic measurements made by the Shuttle Solar Backscatter Ultraviolet Spectral Radiometer and to evaluate the potential effects of scattering by atmospheric aerosols on our ability to detect trends in ozone using SBUV-class instruments.

Frederick, John E.↗
NASA NTRS1987

The ultraviolet spectral albedo of planet earth

The solar backscattered ultraviolet spectral radiometer on the Nimbus 7 satellite provides a unique set of radiation measurements which allows an evaluation of the spectral albedo of the earth and its atmosphere in the wavelength range 300 to 340 nm. Near 340 nm, the derived spectral albedo expressed as a function of latitude and month exceeds that in the visible part of the spectrum, with values near 45 percent existing equatorward of 30 deg and an increase to 60-80 percent toward the poles. At middle to high latitudes, the monthly mean spectral albedo exceeds the contribution from Rayleigh scattering alone by factors of 1.4 to 2.2. At wavelengths from 300 to 310 nm, where absorption by stratospheric ozone is significant, the daylight averaged spectral albedos receive negligible contribution from scattering by tropospheric clouds, yet the derived values exceed those predicted for Rayleigh scattering from a clean stratosphere. These observations are consistent with the presence of an atmospheric scattering layer, distinct from cloudiness, located at an altitude above the tropopause.

Frederick, John E.↗