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Fuller, E. J.

Publications and source records attributed to Fuller, E. J..

Scanning ultrafast electron microscopy reveals photovoltage dynamics at a deeply buried $p^- \mathrm{Si/SiO_2}$ interface

The understanding and control of charge carrier interactions with defects at buried insulator/semiconductor interfaces is essential for achieving optimum performance in modern electronics. In this work, we report on the use of scanning ultrafast electron microscopy (SUEM) to remotely probe the dynamics of excited carriers at a Si surface buried below a thick thermal oxide. Our measurements illustrate a previously unidentified SUEM contrast mechanism, whereby optical modulation of the space-charge field in the semiconductor modulates the electric field in the thick oxide, thus affecting its secondary electron yield. By analyzing the SUEM contrast as a function of time and laser fluence we demonstrate the diffusion mediated capture of excited carriers by interfacial traps.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A multi-technique approach to understanding delithiation damage in LiCoO2 thin films

Abstract We report on the delithiation of LiCoO 2 thin films using oxalic acid (C 2 H 2 O 4 ) with the goal of understanding the structural degradation of an insertion oxide associated with Li chemical extraction. Using a multi-technique approach that includes synchrotron radiation X-ray diffraction, scanning electron microscopy, micro Raman spectroscopy, photoelectron spectroscopy and conductive atomic force microscopy we reveal the balance between selective Li extraction and structural damage. We identify three different delithiation regimes, related to surface processes, bulk delithiation and damage generation. We find that only a fraction of the grains is affected by the delithiation process, which may create local inhomogeneities. However, the bulk delithiation regime is effective to delithiate the LCO film. All experimental evidence collected indicates that the delithiation process in this regime mimics the behavior of LCO upon electrochemical delithiation. We discard the formation of Co oxalate during the chemical extraction process. In conclusion, the chemical route to Li extraction provides additional opportunities to investigate delithiation while avoiding the complications associated with electrolyte breakdown and simplifying in-situ measurements.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Integrated CFD modeling of gas turbine combustors

3D, curvilinear, multi-domain CFD analysis is becoming a valuable tool in gas turbine combustor design. Used as a supplement to experimental testing. CFD analysis can provide improved understanding of combustor aerodynamics and used to qualitatively assess new combustor designs. This paper discusses recent advancements in CFD combustor methodology, including the timely integration of the design (i.e. CAD) and analysis (i.e. CFD) processes. Allied Signal's F124 combustor was analyzed at maximum power conditions. The assumption of turbulence levels at the nozzle/swirler inlet was shown to be very important in the prediction of combustor exit temperatures. Predicted exit temperatures were compared to experimental rake data, and good overall agreement was seen. Exit radial temperature profiles were well predicted, while the predicted pattern factor was 25 percent higher than the harmonic-averaged experimental pattern factor.

Fuller, E. J.↗

Navier-Stokes calculations for 3D gaseous fuel injection with data comparisons

Results from a computational study and experiments designed to further expand the knowledge of gaseous injection into supersonic cross-flows are presented. Experiments performed at Mach 6 included several cases of gaseous helium injection with low transverse angles and injection with low transverse angles coupled with a low yaw angle. Both experimental and computational data confirm that injector yaw has an adverse effect on the helium core decay rate. An array of injectors is found to give higher penetration into the freestream without loss of core injectant decay as compared to a single injector. Lateral diffusion plays a major role in lateral plume spreading, eddy viscosity, injectant plume, and injectant-freestream mixing. Grid refinement makes it possible to capture the gradients in the streamwise direction accurately and to vastly improve the data comparisons. Computational results for a refined grid are found to compare favorably with experimental data on injectant overall and core penetration provided laminar lateral diffusion was taken into account using the modified Baldwin-Lomax turbulence model.

Fuller, E. J.↗

Mixing studies of helium in air at Mach 6

Concentration and mean flow measurements with nanoshadowgraphs and surface flow visualization have been obtained by a study of mixing phenomena during gas injection into hypersonic flow. At Mach 6, a comparison of the matched-pressure injection case with the underexpanded case indicated a greater injectant core penetration rate and a greater concentration-decay rate, leading to a shorter distance for the injectant core to reach an H2-air stoichiometric ratio. The entire injectant plume remained supersonic, and only moderate pressure losses were found. While injector yaw did not increase the mixing rates, it led to an increase in overall injectant plume cross-section, with consequent increase in the size of the mixing region.

Thomas, R. H.↗

Effects of yaw on low angle injection into a supersonic flow

This paper presents the results of a study of transverse gas injection into supersonic/hypersonic streams with low downstream transverse angles in addition to yaw angles varying from zero to approximately 30 deg. The primary data are concentration measurements, with nanoshadowgraphs and oil flow visualization pictures also included. Two sets of experiments were performed. The first set studied the effects of yaw angle, specifically beta = 15 and 28 deg, on a helium injector with a 30-deg transverse angle in a Mach 3 freestream. Axial measurement stations were x/d = 30, 50, and 100. It was found that, as beta was increased, the maximum concentration mixing rate did not vary, but the jet core penetration decreased more at beta = 15 deg than at beta = 28 deg. A shearing effect between the portion of the jet in the boundary layer and the portion in the freestream increased the area of a typical constant concentration contour. The second set of experiments, conducted at NASA Langley, studied the effect of yawed injection at a transverse angle of 15 deg in a Mach 6 flow. Axial stations of x/d = 20, 40, 60, and 80 were used. A yaw angle of beta = 15 deg was found to decrease both the jet core mixing rate and penetration. The primary benefit of yaw was to increase lateral spreading. For similar injection conditions, the results show less near-field mixing at Mach 6 than Mach 3, but a faster mixing rate in the far-field at Mach 6.

Thomas, R. H.↗