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Gaige Hunter Kerr

Publications and source records attributed to Gaige Hunter Kerr.

Diesel Passenger Vehicle Shares Influenced Covid-19 Changes in Urban Nitrogen Dioxide Pollution

Diesel-powered vehicles emit several times more nitrogen oxides than comparable gasoline-powered vehicles, leading to ambient nitrogen dioxide (NO2) pollution and adverse health impacts. The COVID-19 pandemic and ensuing changes in emissions provide a natural experiment to test whether NO2 reductions have been starker in regions of Europe with larger diesel passenger vehicle shares. Here we use a semi-empirical approach that combines in-situ NO2 observations from urban areas and an atmospheric composition model within a machine learning algorithm to estimate business-as-usual NO2 during the first wave of the COVID-19 pandemic in 2020. These estimates account for the moderating influences of meteorology, chemistry, and traffic. Comparing the observed NO2 concentrations against business-as-usual estimates indicates that diesel passenger vehicle shares played a major role in the magnitude of NO2 reductions. European cities with the five largest shares of diesel passenger vehicles experienced NO2 reductions ∼ 2.5 times larger than cities with the five smallest diesel shares. Extending our methods to a cohort of non-European cities reveals that NO2 reductions in these cities were generally smaller than reductions in European cities, which was expected given their small diesel shares. We identify potential factors such as the deterioration of engine controls associated with older diesel vehicles to explain spread in the relationship between cities’ shares of diesel vehicles and changes in NO2 during the pandemic. Our results provide a glimpse of potential NO2 reductions that could accompany future deliberate efforts to phase out or remove passenger vehicles from cities.

Nitrogen Dioxide↗

Disentangling the Drivers of the Summertime Ozone‐Temperature Relationship Over the United States

Summertime surface-level ozone (O3 ) is known to vary with temperature, but the relative roles of different processes responsible for causing the O3 -temperature relationship are not well quantified. In this study we use simulations of NASA's Global Modeling Initiative (GMI) chemical transport model (CTM) to isolate and assess the relative impact of atmospheric transport, chemistry, and emissions on O3 variability, events, and its correlation with temperature. Using observations from CASTNet in the contiguous United States, we show that the GMI CTM reproduces the spatiotemporal variability of O3 and the O3 -temperature relationship during the summer. We primarily focus on the total change in O3 due to a change in temperature (d O3 /d T). In regions with strong positive correlations between temperature and O3 such as the Northeast, Great Lakes, and Great Plains, temperature's association with transport primarily drives d O3 /d T with smaller contributions from temperature-dependent chemistry and anthropogenic emissions. There are regions, however, with near-zero correlation between temperature and O3 , and our findings suggest that transport is still an important driver of O3 variability in these regions, albeit not correlated with temperature. Transport is not directly dependent on temperature but rather is linked through an indirect association, and it is therefore important to understand the exact mechanisms that link transport to O3 and how these mechanisms will change in a warming world.

ozone, temperature, CTM↗