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Ganapathy, R.

Publications and source records attributed to Ganapathy, R..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

The trace element chemistry of CaS in enstatite chondrites and some implications regarding its origin

The trace element distribution in oldhamite (CaS) extracted from enstatite chondrites was determined by INAA. Prior to extraction, the petrologic setting of the grains was studied microscopically, and their minor element contents determined by microprobe analysis; samples that displayed a wide range of minor element contents were selected for detailed elementary analysis. Those samples of CaS suspected to be more primitive on the basis of their minor element and petrologic siting contain the entire inventory of the host meteorite's light REE (LREE) and Eu, plus 30-50 percent of the heavy-REE inventory. In less primitive samples, the LREE are less enriched although Eu remains highly concentrated. Several other elements, including lithophiles and chalcophiles, are most enriched in the most primitive CaS. It is suggested that oldhamite played a key role in the redistribution of these elements during the metamorphism and evolution of enstatite-rich material.

Larimer, John W.↗
NASA NTRS1983

Nickel-iron spherules in tektites - Non-meteoritic in origin

The concentrations of several diagnostic trace elements were determined in two comparatively large NiFe spherules extracted from tektites. The purpose of the study was to obtain some clues about the chemistry of the projectile that is presumed responsible for the formation of these tektites. However, the trace element pattern is distinctly terrestrial implying that the spherules are the result of in-situ reduction of the host rock and are not meteoritic in origin.

Ganapathy, R.↗
NASA NTRS1980

A meteoritic component rich in volatile elements - Its characterization and implications

An analysis of a study of minerals unique to enstatite chondrites, an unusual group of meteorites characterized by highly reduced mineral assemblages, is presented. Various samples of crushed fragments of the Abee meteorite were studied and the normal procedures for identifying the minerals in sections and then extracting them were reversed. An unusual carbon-rich material was found that is highly enriched in volatile elements by factors of 10000 relative to the case for nonvolatile elements. It is believed that this volatile-rich material forms in the solar nebula toward the end of accretion, when small amounts of residual dust acquire all the uncondensed volatile elements.

Ganapathy, R.↗
NASA NTRS1979

Interplanetary dust - Trace element analysis of individual particles by neutron activation

Although micrometeorites of cometary origin are thought to be the dominant component of interplanetary dust, it has never been possible to positively identify such micrometer-sized particles. Two such particles have been identified as definitely micrometeorites since their abundances of volatile and nonvolatile trace elements closely match those of primitive solar system material.

Ganapathy, R.↗
NASA NTRS1979

Trace elements in the Allende meteorite. IV - Amoeboid olivine aggregates

INAA data for Ca, Sc, Hf, La, Ce, Sm, Eu, Tb, Yb, Lu, Os, Ir, Ru, Na, Cl, Br, Fe, Mn, Cr, Co, Au, As, and Sb are presented for ten amoeboid aggregates from the Allende meteorite. Only one lacks olivine. Seven of the remainder, as a group, have cosmic proportions of refractory lithophile and siderophile elements and appear to have formed when coarse-grained Allende inclusion material underwent partial reaction with a low-temperature nebular gas and mixture with FeO-rich olivine. The other two have highly fractionated abundances of refractory elements relative to one another compared to Cl chondrites, including Group II REE patterns, and probably formed by the mixing of fine-grained Allende inclusion material with FeO-rich olivine. Non-refractory siderophile components are also different in composition in each type of amoeboid olivine aggregate.

Grossman, L.↗
NASA NTRS1978

Silicate spherules from deep-sea sediments - Confirmation of extraterrestrial origin

Silicate spherules larger than 100 microns were extracted from 100 kg of box core samples of Pacific red clay taken in the mid-Pacific at a depth of 5 km, and the concentration of nonvolatile trace elements was determined for three spheres. One of the spheres shows excellent resemblance to C1 chondrite nonvolatile trace-element abundance patterns, and the relative abundances of the other two spheres are also very similar to those of C1 chondrites. One of these two spheres is depleted in Ir and Ru, while the other is depleted for Ni and Cr; possible explanations for the depletions are considered. Since the elemental abundances of the third sphere match the abundances of C1 chondrites, it is suggested that this sphere must be of extraterrestrial origin.

Ganapathy, R.↗
NASA NTRS1977

Trace elements in the Allende meteorite. III - Coarse-grained inclusions revisited

Radiochemical neutron activation analytic determinations of several elements in coarse-grained inclusions of the Allende meteorite are reported. The condensation and fractionation behavior of these and other elements are described. Evidence was found for a post-accretion thermal event which redistributed some trace elements. The solar system ratio of Zr/Hf is computed on the basis of the minimum variation in the inclusion, and the percentage of high-temperature condensates in the earth and moon are calculated on the basis of the mean U content of the inclusions. The mean value of the enrichment factors of 21 refractory elements relative to C1 chondrites is provided, and the elements that did or did not condense in a solid solution of melilite are listed.

Grossman, L.↗
NASA NTRS1977

'Mysterite' - A late condensate from the solar nebula

An attempt is made to clarify the nature of 'mysterite', a material that had been postulated to explain the overabundance of Tl, Bi, and Ag in certain chondrites. Four dark clasts and a vein sample from the H6 chondrite Supuhee were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Rb, Re, Sb, Se, Te, Tl, and Zn. One of the clasts is enriched in all volatile elements, while the other four samples are enriched only in the siderophile volatiles Ag, Bi, and Tl. The enrichments range up to 100 times typical H6 chondrite abundances. The proportions of Ag, Bi, and Tl suggest the presence of at least two, Tl-rich and Tl-poor, varieties of mysterite. The former seems to dominate in Supuhee and Krymka, and the latter in Mezo-Madaras. Apparently mysterite is a late condensate from the solar nebula that collected volatiles left behind by earlier generations of chondrites. It was incorporated in Supuhee and perhaps in other chondrites (mainly of low petrologic types) during brecciation events.

Higuchi, H.↗
NASA NTRS1977

Pontlyfni - A differentiated meteorite related to the group IAB irons

The abundances of 23 major and trace elements in the Pontlyfni meteorite have been measured by instrumental neutron activation analysis. The compositions of the metal and silicate fractions suggest a genetic relationship between Pontlyfni and the group IAB irons.

Davis, A. M.↗
NASA NTRS1977

Yes, Kakangari is a unique chondrite

The position of the Kakangari chondrite as the representative of a new class of chondrites is considered, taking into account the results of the analysis of a 17.1-mg piece of Kakangari for 20 elements. Elemental concentration data are compared for Kakangari and other meteorite groups. Data for the most similar groups, C2, C3(V), L, and E4 chondrites are represented in a graph along with Kakangari data. It is found that pronounced differences exist between Kakangari and the other meteorite classes.

Davis, A. M.↗
NASA NTRS1977

Meteoritic material on the moon

Three types of meteoritic material are found on the moon: micrometeorites, ancient planetesimal debris from the "early intense bombardment," and debris of recent, craterforming projectiles. Their amounts and compositions have been determined from trace element studies. The micrometeorite component is uniformly distributed over the entire lunar surface, but is seen most clearly in mare soils. It has a primitive, C1-chondrite-like composition, and comprises 1 to 1.5 percent of mature soils. Apparently it represents cometary debris. The ancient component is seen in highland breccias and soils. Six varieties have been recognized, differing in their proportions of refractories (Ir, Re), volatiles (Ge, Sb), and Au. All have a fractionated composition, with volatiles depleted relative to siderophiles. The abundance patterns do not match those of the known meteorite classes. These ancient meteoritic components seem to represent the debris of an extinct population of bodies (planetisimals, moonlets) that produced the mare basins during the first 700 Myr of the moon's history. On the basis of their stratigraphy and geographic distribution, five of the six groups are tentatively assigned to specific mare basins: Imbrium, Serenitatis, Crisium, Nectaris, and Humorum or Nubium.

Morgan, J. W.↗
NASA NTRS1976

Chemical fractionations in meteorites. X - Ureilites

An investigation involving the measurement of 17 trace elements in 4 ureilites was conducted with the objective to obtain information for the characterization of the two components of the ureilites. The groundmass of the mineral is an olivine-clinopyroxene rock which is presumably the residue left after partial melting of a more primitive precursor. This ultramafic rock is permeated by a network of veins containing diamond, graphite, nickel-iron, and primordial noble gases. Attention is given to the vein material, the origin of the vein material, the 'constant' siderophile component and ultramafic rock, and questions concerning the origin of ureilites.

Higuchi, H.↗
NASA NTRS1976

Chemical fractionations in meteorites. IX - C3 chondrites

Radiochemical neutron activation is applied to the analysis of four C3V chondrites and three C3O chondrites for 17 trace elements (U, Re, Ir, Ni, Au, Sb, Ge, Ag, Rb, Cs, Bi, Tl, Br, Se, Te, In, and Cd). It is shown that both classes exhibit a typical chondritic step pattern, reflecting loss of volatiles during chondrule formation. It appears that the H2S/H2 ratio is the key variable to account for the condensation of chalcophile elements as a function of H2S. C3O's seem to have condensed in a region where enough metallic Fe was present to buffer the H2S pressure, whereas C3V's condensed in a more oxidized region where H2S was in excess. Accretion temperatures for both subclasses is determined. Sb and Au show variable depletion, presumably reflecting variable loss during chondrule formation.

Anders, E.↗
NASA NTRS1976

The case for an unfractionated Pu-244/U-238 ratio in high-temperature condensates

The coarse-grained, Ca-rich inclusions in the Allende meteorite are the highest-temperature condensates from the cooling solar nebula and, as such, the oldest solid objects in the solar system. All refractory elements with condensation points above the accretion temperature of the inclusions whose concentrations in them have been measured are seen to be present in the inclusions in unfractionated proportion to one another relative to Cl chondrites when data are averaged for a large number of inclusions. Observational data for U and theoretical data for both U and Pu suggest that these elements exhibited refractory behavior in the solar nebula. An experiment is proposed in which fissiogenic Xe and U contents are measured in a suite of these inclusions to obtain the Pu-244/U-238 ratio of the solar system at the time of initial condensation with an uncertainty of plus or minus 15%.

Ganapathy, R.↗