Volatile elements in Apollo 16 samples - Implications for highland volcanism and accretion history of the moon
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Nine petrographically distinct separates from Apollo 15 coarse soils were characterized by electron microprobe and analyzed by neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Rb, Re, Sb, Se, Te, Tl, U, and Zn. Like some alkali-poor anorthosites from Apollo 16, 15102 anorthosite is low in meteoritic siderophiles but enriched in Tl, perhaps by volcanic processes. Norites from 15102 and troctolites from 15302 are lower in KREEP than are Apollo 12 or 14 norites. A possible progenitor of KREEP-rich norite breccias has been found: a mesostasis-rich basalt from 15272 high in KREEP-related elements, but very low in the siderophiles Ir, Re, Au, Sb, and Ge, and hence lacking the ancient meteoritic component that occurs in all lunar norites. At least two varieties of ancient meteoritic component are present in the soil separates from this site, consistent with the complex impact history of the Pre-Imbrian surface.
Eighteen achondrites and 4 terrestrial basalts (3 ocean ridge, 1 continental) were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Co, Cs, Cu, Ga, In, Ir, Rb, Se, Tl and Zn. Samples included 7 eucrites, 5 howardites, 2 nakhlites, 2 shergottites, an angrite, and an aubrite. Light and dark portions of the gas-rich meteorites Kapoeta and Pesyanoe were analyzed separately. Nakhlites and shergottites have volatile element abundances similar to those in ocean ridge basalts; eucrites, howardites, and angrites show greater depletions by an order of magnitude and less similar abundance patterns. In terms of a two-component model of planetary accretion, the parent planets contained the following percentages of low-temperature material: eucrites 0.8, nakhlites 38, shergottites 28. Shergottites may be genetically related to L-chondrites. The siderophile element pattern of achondrites resembles that of the moon, but with less extreme depletions.
Soils from the Apollo 14 site contain nearly three times as much meteoritic material as soils from the Apollo 11, Apollo 12, and Luna 16 sites. Part of this material consists of the ubiquitous micrometeorite component, of primitive (carbonaceous-chondrite-like) composition. The remainder, seen most conspicuously in coarse glass and norite fragments, has a decidedly fractionated composition, with volatile elements less than one-tenth as abundant as siderophiles. This material seems to be debris of the Cyprus-sized planetesimal that produced the Imbrian Basin. Compositionally this planetesimal has no exact counterpart among known meteorite classes, though group IVA irons come close. It also resembles the initial composition of the earth as postulated by the two-component model. Apparently the Imbrian planetesimal was an earth satellite swept up by the moon during tidal recession or capture, or an asteroid deflected by Mars into terrestrial space.
Two Luna 16 soils have been analyzed for Ag, Au, Bi, Br, Cd, Co, Cs, Cu, Ga, Ge, In, Ur, Ni, Rb, Re, Sb, Se, Te, Tl, and Zn. A meteoritic component similar to that in Apollo 11 and 12 soils seems to be present, corresponding to about 1.5 to 2% Cl chondrites or equivalent. It probably consists largely of micrometeorites. Three elements show strong enrichments compared to Apollo 11 and 12 soils: Cd (5 x to 200 x), Ag (5 x to 10 x), and Bi (3 x). Presumably these elements were brought in by Cd-Ag-Bi rich material, similar to that in Unit VI of Apollo core 12028.
Seventeen trace elements have been determined by neutron activation analysis in 33 lunar samples from Apollo 14, 5 from Apollo 12, and 2 from Luna 16. Apollo 14 soils and breccias contain at least two, and possibly three, ancient meteoritic components of unusual composition, probably derived from the Imbrian and Serenitatis impacts, and mixed planetesimal debris from the pre-Imbrian regolith. These components have a lower ratio of volatiles to siderophiles than any known class of chondrites. They also have Ir/Au, Ge/Au ratios outside the range for most iron meteorites, except groups IVA and possibly IIIA. One of these components, of very low Ir/Au, Re/Au ratio, occurs in light norites, 14321 microbreccias, and KREEP separates from 12033 soil. Another is found in dark norites, glasses, and several other Apollo 14 samples, as well as rock 12013 and Apollo 11 anorthosite. From these compositional clues it appears that the Imbrian body and the pre-Imbrian planetesimals, like the earth, were relatively rich in iron, but depleted in volatiles. Such a composition is consistent with the Imbrian body originating as an earth-crossing planetesimal.
Five Apollo 15 soils and four rocks were examined by neutron activation analysis for 18 volatile and siderophile elements. The results obtained are initially interpreted in terms of local geologic problems at the Apollo 15 site. Implications bearing on the meteorite influx and volatile element depletion on the moon are then examined. Elbow Crater soil 15081, collected 65 m from the rim, contains a meteoritic component equivalent to 1.72% Cl material, similar to that at other lunar sites. Other soils are lower owing to dilution by fresh bedrock or talus from the Apennine Front. The moon-earth difference in volatile elements is discussed from the viewpoint of a difference in the efficiency of accretion from the solar nebula.
Glazed lunar rocks, explaining origin as result of nearby meteoritic impact
Chemical fractionations in meteorites, considering trace elements abundance in L chondrites and implications for cosmothermometry
Neutron activation analysis for trace elements depleted on lunar surface with implications for origin of moon and meteorite influx rate
Lunar rock volatile and siderophile elements, comparing with terrestrial and meteoritic basalts
Meteoritic material characterization from trace elements in Apollo lunar soil, core samples, breccia and anorthositic fragments by neutron activation analysis
Apollo 12 lunar core and soil samples indicating meteoritic trace elements abundance
Trace element abundances in L-chondrites determined by neutron activation analysis, and implications cosmothermometry
Apollo 11 lunar material trace elements, examining chemical processes during and after formation and meteoritic matter influx rate
Calcium rich achondrites radiation ages determined from measuring He, Ne and Ar in howardites, nakhlites and angrite