Engineering topics

Gasnault, O.

Publications and source records attributed to Gasnault, O..

16 records

DOE OSTI2024

Manganese-Rich Sandstones as an Indicator of Ancient Oxic Lake Water Conditions in Gale Crater, Mars

Manganese has been observed on Mars by the NASA Curiosity rover in a variety of contexts and is an important indicator of redox processes in hydrologic systems on Earth. Within the Murray formation, an ancient primarily fine-grained lacustrine sedimentary deposit in Gale crater, Mars, have observed up to 45× enrichment in manganese and up to 1.5× enrichment in iron within coarser grained bedrock targets compared to the mean Murray sediment composition. This enrichment in manganese coincides with the transition between two stratigraphic units within the Murray: Sutton Island, interpreted as a lake margin environment, and Blunts Point, interpreted as a lake environment. On Earth, lacustrine environments are common locations of manganese precipitation due to highly oxidizing conditions in the lakes. Here, we explore three mechanisms for ferromanganese oxide precipitation at this location: authigenic precipitation from lake water along a lake shore, authigenic precipitation from reduced groundwater discharging through porous sands along a lake shore, and early diagenetic precipitation from groundwater through porous sands. All three scenarios require highly oxidizing conditions and we discuss oxidants that may be responsible for the oxidation and precipitation of manganese oxides. This work has important implications for the habitability of Mars to microbes that could have used Mn redox reactions, owing to its multiple redox states, as an energy source for metabolism.

58 GEOSCIENCES↗

DOE OSTI2021

The SuperCam Instrument Suite on the Mars 2020 Rover: Science Objectives and Mast-Unit Description

On the NASA 2020 rover mission to Jezero crater, the remote determination of the texture, mineralogy and chemistry of rocks is essential to quickly and thoroughly characterize an area and to optimize the selection of samples for return to Earth. As part of the Perseverance payload, SuperCam is a suite of five techniques that provide critical and complementary observations via Laser-Induced Breakdown Spectroscopy (LIBS), Time-Resolved Raman and Luminescence (TRR/L), visible and near-infrared spectroscopy (VISIR), high-resolution color imaging (RMI), and acoustic recording (MIC). SuperCam operates at remote distances, primarily 2–7 m, while providing data at sub-mm to mm scales. We report on SuperCam’s science objectives in the context of the Mars 2020 mission goals and ways the different techniques can address these questions. The instrument is made up of three separate subsystems: the Mast Unit is designed and built in France; the Body Unit is provided by the United States; the calibration target holder is contributed by Spain, and the targets themselves by the entire science team. This publication focuses on the design, development, and tests of the Mast Unit; companion papers describe the other units. The goal of this work is to provide an understanding of the technical choices made, the constraints that were imposed, and ultimately the validated performance of the flight model as it leaves Earth, and it will serve as the foundation for Mars operations and future processing of the data.

47 OTHER INSTRUMENTATION↗

DOE OSTI2020

SuperCam Calibration Targets: Design and Development

Abstract SuperCam is a highly integrated remote-sensing instrumental suite for NASA’s Mars 2020 mission. It consists of a co-aligned combination of Laser-Induced Breakdown Spectroscopy (LIBS), Time-Resolved Raman and Luminescence (TRR/L), Visible and Infrared Spectroscopy (VISIR), together with sound recording (MIC) and high-magnification imaging techniques (RMI). They provide information on the mineralogy, geochemistry and mineral context around the Perseverance Rover. The calibration of this complex suite is a major challenge. Not only does each technique require its own standards or references, their combination also introduces new requirements to obtain optimal scientific output. Elemental composition, molecular vibrational features, fluorescence, morphology and texture provide a full picture of the sample with spectral information that needs to be co-aligned, correlated, and individually calibrated. The resulting hardware includes different kinds of targets, each one covering different needs of the instrument. Standards for imaging calibration, geological samples for mineral identification and chemometric calculations or spectral references to calibrate and evaluate the health of the instrument, are all included in the SuperCam Calibration Target (SCCT). The system also includes a specifically designed assembly in which the samples are mounted. This hardware allows the targets to survive the harsh environmental conditions of the launch, cruise, landing and operation on Mars during the whole mission. Here we summarize the design, development, integration, verification and functional testing of the SCCT. This work includes some key results obtained to verify the scientific outcome of the SuperCam system.

Manrique, J. A. (ORCID:0000000220532819)↗

NASA NTRS2020

Characterisation of Float Rocks at Ireson Hill, Gale Crater

Float rocks discovered by surface missions on Mars have given unique insights into the sedimentary, diagenetic and igneous processes that have operated throughout the planet’s history. In addition, Gale sedimentary rocks, both float and in situ, record a combination of source compositions and diagenetic overprints. We examine a group of float rocks that were identified by the Mars Science Laboratory mission’s Curiosity rover at the Ireson Hill site, circa. sol 1600 using ChemCam LIBS, APXS and images from the MastCam, Mars Hand Lens Imager (MAHLI) and ChemCam Remote Micro-Imager (RMI) cameras. Geochemical data provided by the APXS and ChemCam instruments allow us to compare the compositions of these rocks to known rock types from Gale crater, as well as elsewhere on Mars. Ireson Hill is a 15 m long butte in the Murray formation with a dark cap-ping unit with chemical and stratigraphic consistency with the Stimson formation. A total of 6 float rocks have been studied on the butte.

Bowden, D. L.↗

NASA NTRS2020

Apatites in Gale Crater

ChemCam is an active remote sensing instrument suite that has operated successfully on MSL since landing Aug. 6th, 2012. It uses laser pulses to remove dust and to analyze rocks up to 7 m away. Laser-induced breakdown spectroscopy (LIBS) obtains emission spectra of materials ablated from the samples in electronically excited states. The intensities of the emission lines scale with the abundances of the related element. ChemCam is sensitive to most major rock-forming elements as well as to a set of minor and trace elements such as F, Cl, Li, P, Sr, Ba, and Rb. The measured chemical composition can then be used to infer the mineralogical composition of the ablated material. Here, we report a summary of inferred apatite detections along the MSL traverse at Gale Crater. We present the geologic settings of these findings and derive some interpretations about the formation conditions of apatite in time and space.

Forni, O.↗

NASA NTRS2020

First Gale Western Butte Capping-Unit Compositions, and Relationships to Earlier Units Along Curiosity's Traverse

The Curiosity rover has been traversing through the clay-bearing unit (Glen Torridon; GT), approaching Greenheugh pediment, a large, fan-shaped surface surrounding the mouth of Gediz Vallis on the lower slope of Mt. Sharp. The pediment unconformably overlies the underlying bedrock, and is hence younger than units of the Mt. Sharp group. Orbital imaging of the pediment has shown it to have a slightly lower albedo and higher thermal inertia than neighboring units, to be relatively retentive of craters (e.g., erosion resistant), and to exhibit curved bedforms suggestive of lithified eolian bedforms. No diagnostic spectral signature has been observed from orbit. Recent rover positions allowed remote imaging of the contact between Greenheugh pediment and the eroded Murray formation strata below it, showing that the pediment capping material is cross-bedded and relatively thin (1-3 m), and suggesting that the pediment may have been much larger at one time. As Curiosity approached the edge of the pediment, the team investigated two buttes named Central and Western. The latter butte contains dark capping material that initially looked similar to the pediment cap, but close inspection revealed important physical differences. Here we report on compositions from ChemCam of two float rocks that appear to have rolled down from the capping unit, and on potential relation-ships to other targets along the traverse of the rover.

Wiens, R. C.↗

NASA NTRS2020

The Role of Diagenesis at Vera Rubin Ridge in Gale Crater, Mars, and the Chemostratigraphy of the Murray Formation as Observed by the Chemcam Instrument

The Mars Science Laboratory (MSL) Curiosity rover explored Vera Rubin ridge (VRR) in Gale crater, Mars, for almost 500 sols (Mars days) between arriving at the ridge on sol 1809 of the mission in September 2017 and leaving it on sol 2302 upon entering the Glen Torridon area south of the ridge. VRR is a topographic ridge on the central mound, Aeolis Mons (Mt. Sharp), in Gale crater that displays a strong hematite spectral signature from orbit. In-situ observations on the ridge led to the recognition that the ridge-forming rocks belong to the Murray formation, the lowermost exposed stratigraphic unit of the Mt. Sharp group, that was first encountered at the Pahrump Hills location. Including VRR rocks, the Murray formation, interpreted to be primarily deposited in an ancient lacustrine environment in Gale crater, is more than 300 m thick. VRR itself is composed of two stratigraphic members within the Murray formation, the Pettegrove Point member overlain by the Jura member. The Pettegrove Point member overlies the Blunts Point member of the Murray formation. Areas of gray coloration are observed in the Jura member predominantly, but also in the Pettegrove Point member. Generally, gray areas are found in local topographic depressions, but contacts between red and gray rocks crosscut stratigraphy. Additionally, cm-scale dark concretions with very high iron-content are commonly observed in gray rocks, typically surrounded by a lighttoned zone that is conversely depleted in iron. A key goal for the VRR campaign was to characterize geochemical variations in the ridge-forming rocks to investigate the role of primary and diagenetic controls on the geochemistry and morphology of VRR. Here, we present observations by the ChemCam instrument on VRR and compare these to the full Murray formation chemostratigraphy. This work was recently submitted to a special issue of JGRPlanets that detail the full VRR campaign.

Frydenvang, J.↗

NASA NTRS2019

Using Chemcam Derived Geochemistry to Identify the Paleonet Sediment Transport Direction and Source Region Characteristics of the Stimson Formation in Gale Crater, Mars

The NASA Curiosity rover has encountered both ancient and modern dune deposits within Gale crater. The modern dunes are actively migrating across the surface within the Bagnold Dune field of which Curiosity conducted analysis campaigns at two different localities. Variations in mafic-felsic mineral abundances between these two sites have been related to the aeolian mineral sorting regime for basaltic environments identified on the Earth which become preferentially enriched in olivine relative to plagioclase feldspar with increasing distance from the source. This aeolian mineral sorting regime for basaltic minerals has also been inferred for Mars from orbital data. The aim of this study is to investigate whether this aeolian mafic-felsic mineral sorting trend has left a geochemical signature in the ancient dune deposits preserved within the Stimson formation. The Stimson formation unconformably overlies the Murray formation and consists of thickly laminated, cross-bedded sandstone. Stimson outcrops have a variable thickness up to 5 meters covering a total area of 17 square kilometers. A dry, aeolian origin was determined for this sandstone due to the high sphericity and roundness of the grains, uniform bimodal grain size distribution (250-710 microns), and 1-meter-thick cross-beds. Identifying the geochemical signature of mineral sorting can provide insights about the paleo-net sediment transport direction of the dunes and prevailing wind direction at the time of deposition.

Bedford, C. C.↗

NASA NTRS2016

Calibration of the Fluorine, Chlorine and Hydrogen Content of Apatites With the ChemCam LIBS Instrument

Determining the composition of apatites is important to understand the behavior of volatiles during planetary differentiation. Apatite is an ubiquitous magmatic mineral in the SNC meteorites. It is a significant reservoir of halogens in these meteorites and has been used to estimate the halogen budget of Mars. Apatites have been identified in sandstones and pebbles at Gale crater by ChemCam, a Laser-Induced Breakdown Spectroscometer (LIBS) instrument onboard the Curiosity rover. Their presence was inferred from correlations between calcium, fluorine (using the CaF molecular band centered near 603 nm, whose detection limit is much lower that atomic or ionic lines and, in some cases, phosphorus (whose detection limit is much larger). An initial quantification of fluorine, based on fluorite (CaF2)/basalt mixtures and obtained at the LANL laboratory, indicated that the excess of F/Ca (compared to the stoichiometry of pure fluorapatites) found on Mars in some cases could be explained by the presence of fluorite. Chlorine was not detected in these targets, at least above a detection limit of 0.6 wt% estimated from. Fluorapatite was later also detected by X-ray diffraction (with CheMin) at a level of approx.1wt% in the Windjana drill sample (Kimberley area), and several points analyzed by ChemCam in this area also revealed a correlation between Ca and F. The in situ detection of F-rich, Cl-poor apatites contrasts with the Cl-rich, F-poor compositions of apatites found in basaltic shergottites and in gabbroic clasts from the martian meteorite NWA 7034, which were also found to be more Cl-rich than apatites from basalts on Earth, the Moon, or Vesta. The in situ observations could call into question one of the few possible explanations brought forward to explain the SNC results, namely that Mars may be highly depleted in fluorine. The purpose of the present study is to refine the calibration of the F, Cl, OH and P signals measured by the ChemCam LIBS instrument, initiated for F, for Cl in soils, for P, and estimate their limit of detection. For this purpose, different types of apatites and mixtures of basalt powder and apatites were analyzed using ChemCam Engineering Qualification Model (EQM) at IRAP, Toulouse. The present abstract presents the initial results from the laboratory analyses. Differences between the response function of the EQM and the Flight Model of ChemCam are still to be refined to apply these new results to the Martian dataset.

Meslin, P.-Y.↗

NASA NTRS2015

Centimeter to Decimeter Size Spherical and Cylindrical Features in Gale Crater Sediments

The Curiosity rover traverse in Gale crater has explored a large series of sedimentary deposits in an ancient lake on Mars. Over the nine kilometers of traverse a recurrent observation has been southward-dipping sedimentary strata, from Shaler at the edge of Yellowknife Bay to the striated units near the Kimberley. Within the sedimentary strata cm- to decimeter- size hollow spheroidal objects and some apparent cylindrical objects have been observed. These features have not been seen by previous landed missions. The first of these were observed on sol 122 in the Gillespie Lake member at Yellowknife Bay. Additional hollow features were observed in the Point Lake outcrop in the same area. More recently a spherical and apparently hollow object, Winnipesaukee, was observed by ChemCam and Mastcam on sol 653. Here we describe the settings, morphology, and associated compositions, and we discuss possible origins of these objects.

Wiens, R. C.↗

NASA NTRS2015

Diagenetic Features Analyzed by ChemCam/Curiosity at Pahrump Hills, Gale Crater, Mars

Onboard the Mars Science Laboratory (MSL) Curiosity rover, the ChemCam instrument consists of : (1) a Laser-Induced Breakdown Spectrometer (LIBS) for elemental analysis of targets and (2) a Remote Micro Imager (RMI), which provides imaging context for the LIBS. The LIBS/ChemCam performs analysis typically of spot sizes 350-550 micrometers in diameter, up to 7 meters from the rover. Within Gale crater, Curiosity traveled from Bradbury Landing toward the base of Mount Sharp, reaching Pahrump Hills outcrop circa sol 750. This region, as seen from orbit, represents the first exposures of lower Mount Sharp. In this abstract we focus on two types of features present within the Pahrump Hills outcrop: concretion features and light-toned veins.

Nachon, M.↗

NASA NTRS2015

Fluorine and Lithium at the Kimberley Outcrop, Gale Crater

ChemCam is an active remote sensing instrument which has operated successfully on MSL since landing in August, 2012. Its laser pulses remove dust and to profile through weathering coatings of rocks up to 7 m away. Laser-induced breakdown spectroscopy (LIBS) produces emission spectra of materials ablated from the samples in electronically excited states. As the plasma cools, elements can recombine and molecular emission lines are observed. Recent experiments have shown that some of these molecular emissions can be much brighter than the associated atomic lines, especially when halo-gens and rare earth elements are present. We observed these molecular emissions in some of the ChemCam spectra and report the first detection of chlorine and fluorine with ChemCam. It is also the first time ever that fluorine has been detected on the surface of Mars. Among all the F-bearing observations, one third are observed in the Kimberley outcrop. We will dis-cuss the potential mineralogies related to these observations as well as the related elemental correlations and propose interpretations.

Forni, O.↗

NASA NTRS2014

Calcium Sulfate Characterized by ChemCam/Curiosity at Gale Crater, Mars

Onboard the Mars Science Laboratory (MSL) Curiosity rover, the ChemCam instrument consists of :(1) a Laser-Induced Breakdown Spectrometer (LIBS) for elemental analysis of the targets [1;2] and (2) a Remote Micro Imager (RMI), for the imaging context of laser analysis [3]. Within the Gale crater, Curiosity traveled from Bradbury Landing through the Rocknest region and into Yellowknife Bay (YB). In the latter, abundant light-toned fracture-fill material were seen [4;5]. ChemCam analysis demonstrate that those fracture fills consist of calcium sulfates [6].

Nachon, M.↗

NASA NTRS2014

Terrain Physical Properties Derived from Orbital Data and the First 360 Sols of Mars Science Laboratory Curiosity Rover Observations in Gale Crater

Physical properties of terrains encountered by the Curiosity rover during the rst 360 sols of operations have been inferred from analysis of the scour zones produced by Sky Crane Landing System engine plumes, wheel touch down dynamics, pits produced by Chemical Camera (ChemCam) laser shots, rover wheel traverses over rocks, the extent of sinkage into soils, and the magnitude and sign of rover-based slippage during drives. Results have been integrated with morphologic, mineralogic, and thermophysical properties derived from orbital data, and Curiosity-based measurements, to understand the nature and origin of physical properties of traversed terrains. The hummocky plains (HP) landing site and traverse locations consist ofmoderately to well-consolidated bedrock of alluvial origin variably covered by slightly cohesive, hard-packedbasaltic sand and dust, with both embedded and surface-strewn rock clasts. Rock clasts have been addedthrough local bedrock weathering and impact ejecta emplacement and form a pavement-like surface in whichonly small clasts (5 to 10 cm wide) have been pressed into the soil during wheel passages. The beddedfractured (BF) unit, site of Curiositys rst drilling activity, exposes several alluvial-lacustrine bedrock unitswith little to no soil cover and varying degrees of lithication. Small wheel sinkage values (1 cm) for both HPand BF surfaces demonstrate that compaction resistance countering driven-wheel thrust has been minimaland that rover slippage while traversing across horizontal surfaces or going uphill, and skid going downhill,have been dominated by terrain tilts and wheel-surface material shear modulus values.

Mars Science Laboratory Curiosity Gale Crater↗

NASA NTRS2014

Calcium Sulfate Characterized by Chemcam/Curiousity at Gale Crater, Mars

Onboard the Mars Science Laboratory (MSL) Curiosity rover, the ChemCam instrument consists of : (1) a Laser-Induced Breakdown Spectrometer (LIBS) for elemental analysis of the targets and (2) a Remote Micro Imager (RMI), for the imaging context of laser analysis. Within the Gale crater, Curiosity traveled from Bradbury Landing through the Rocknest region and into Yellowknife Bay (YB). In the latter, abundant light-toned fracture-fill material occur. ChemCam analysis demonstrates that those fracture fills consist of calcium sulfates.[

Nachon, M.↗

NASA NTRS2014

Elemental Geochemistry of Sedimentary Rocks at Yellowknife Bay, Gale Crater, Mars

Sedimentary rocks examined by the Curiosity rover at Yellowknife Bay, Mars, were derived from sources that evolved from an approximately average martian crustal composition to one influenced by alkaline basalts. No evidence of chemical weathering is preserved, indicating arid, possibly cold, paleoclimates and rapid erosion and deposition. The absence of predicted geochemical variations indicates that magnetite and phyllosilicates formed by diagenesis under low-temperature, circumneutral pH, rock-dominated aqueous conditions. Analyses of diagenetic features (including concretions, raised ridges, and fractures) at high spatial resolution indicate that they are composed of iron- and halogen-rich components, magnesium-iron-chlorine-rich components, and hydrated calcium sulfates, respectively. Composition of a cross-cutting dike-like feature is consistent with sedimentary intrusion. The geochemistry of these sedimentary rocks provides further evidence for diverse depositional and diagenetic sedimentary environments during the early history of Mars.

Research Support, U.S. Gov't, Non-P.H.S.↗