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Gibson, E. K., Jr.

Publications and source records attributed to Gibson, E. K., Jr..

At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

Sulfur abundances and distributions in the valley of Taurus-Littrow

Total sulfur abundances have been determined for 36 Apollo 17 soil, breccia and crystalline rock samples. Sulfur concentrations range from 550 to 1300 micrograms S/g for soil samples, with the orange soil containing the lowest amount of sulfur. Noritic breccias contain between 720 and 950 micrograms S/g, while the anorthositic rocks have sulfur contents of 270 and 368 micrograms S/g. The dunite 72415 contained the lowest sulfur content (44 micrograms S/g) of any Apollo 17 sample studied. Apollo 17 basalts have unusually high sulfur contents (1580-2770 micrograms S/g) as compared to Apollo 12 and 15 basalts and terrestrial basalts. Sulfur abundances for the Apollo 17 basalts are almost identical to those from Apollo 11 basalts. A negative correlation between percent metallic iron and total sulfur for the Apollo 17 and 15 basalts was found and suggests that a portion of the metallic iron in lunar basalts may result from desulfuration of the melt prior to crystallization from the lunar magma.

Gibson, E. K., Jr.↗
NASA NTRS1973

Variable carbon contents of lunar soil 74220

Total carbon, sulfur, and inorganic gas release studies have been carried out on an additional split of orange soil 74220. The total carbon content was found to be 4 plus or minus 3 ppm C for this sample as compared to an earlier reported value of 100 plus or minus 10 ppm C. Gas release studies on the two splits of 74220 indicate that the carbon may be present as a surface condensate on the sample showing the higher carbon content. The 'surface condensate' evolves CO2 upon heating to temperatures below 400 C.

Gibson, E. K., Jr.↗
NASA NTRS1973

Volatile-rich lunar soil - Evidence of possible cometary impact.

A subsurface Apollo 16 soil, 61221, is much richer in volatile compounds than soils from any other locations or sites as shown by thermal analysis-gas release measurements. A weight loss of 0.03% during the interval 175 to 350 C was associated with the release of water, carbon dioxide, methane, hydrogen cyanide, hydrogen, and minor amounts of hydrocarbons and other species. These volatile components may have been brought to this site by a comet, which may have formed North Ray crater.

Gibson, E. K., Jr.↗
NASA NTRS1973

How to lose Rb, K, and change the K/Rb ratio - An experimental study

Thermal volatilization studies on Apollo 16 soils and crystalline rocks have been carried out to measure the depletion of K, Rb, and Na and changes in K/Rb ratios during heating under vacuum. Rubidium can be lost from both soils and rocks at temperatures as low as 1000 C. Because of the greater volatility of Rb as compared to K, the K/Rb ratio can be changed from normal values of 330-360 for the Apollo 16 samples to values as high as 1100 by thermal volatilization. Rapid heating experiments on soil samples were carried out to approximate agglutinate formation conditions in order to measure changes in alkali element abundances. Equal changes in K/Rb ratios can be produced with longer heating at lower temperatures or heating at higher temperatures for shorter times.

Gibson, E. K., Jr.↗
NASA NTRS1973

Carbon and sulfur distributions and abundances in lunar fines

Total sulfur abundances have been determined for 20 Apollo 14, 15, and 16 soil samples and one Apollo 14 breccia. Sulfur concentrations range from 474 to 844 microg S/g. Volatilization experiments on selected samples have been carried out using step-wise heating. Sample residues have been analyzed for their total carbon and sulfur abundances to establish the material balance in lunar fines for these two elements. Volatilization experiments have established that between 31 to 54 microg C/g remains in soils which have been heated at 1100 C for 24 hours under vacuum. The residual carbon is believed to be indigenous lunar carbon whereas all forms of carbon lost from samples below 1100 C is extralunar carbon. Total carbon and sulfur abundances taken from the literature have been used to show the depletion of volatile elements with increasing grade for the Apollo 14 breccias.

Gibson, E. K., Jr.↗
NASA NTRS1973

Total carbon contents of Apollo 15 and 16 lunar samples

The total carbon contents in Apollo 15 fines range from 29 to 170 micrograms/g. Fines from Apollo 16 range from 65 to 280 micrograms/g. These samples are similar to those from Apollo 11, 12, and 14, with dark colored fines generally containing more carbon than lighter fines. Sample 61221 (light colored fines) is anomalously high with 100 micrograms/g total carbon. Correlations between total carbon content and sample collection station for each mission are evident. Basalts from Apollo 15 have less than 27 micrograms/g total carbon. Anorthositic rocks from Apollo 15 and 16 have less than 20 micrograms/g total carbon. Breccias show complex and variable carbon distributions.

Moore, C. B.↗
NASA NTRS1972

Compounds of the organogenic elements in Apollo 11 and 12 lunar samples - A review.

Investigations of low molecular weight compounds of the organogenic elements on lunar samples are reviewed. The three general techniques of vacuum pyrolysis, acid hydrolysis, and crushing have been employed by most investigators. Vacuum pyrolysis of lunar fines produce a variety of gaseous species which are either: (1) indigenous, (2) solar wind products and/or (3) chemical reaction products of mineral phases found in the lunar samples. Acid hydrolysis of lunar fines using deuterium-labeled acids yields evidence for indigenous methane and ethane. Methane and ethane found in the lunar fines are largely derived from the solar wind with only trace amounts indigenous to the samples. Crushing experiments with lunar fines and breccias produce methane, ethane, hydrogen, nitrogen, hydrogen sulfide and the rare gases.

Gibson, E. K., Jr.↗
NASA NTRS1972

Thermogravimetric-quadrupole mass-spectrometric analysis of geochemical samples.

Thermogravimetric-quadrupole mass-spectrometric-analysis techniques can be used to study a wide variety of problems involving decomposition processes and identification of released volatile components. A recording vacuum thermoanalyzer has been coupled with a quadrupole mass spectrometer. The rapid scan capabilities of the quadrupole mass spectrometer are used to identify the gaseous components released. The capability of the thermogravimetric-quadrupole mass spectrometer to provide analytical data for identification of the released volatile components, for determination of their sequence of release and for correlation of thermal-decomposition studies is illustrated by an analysis of the Orgueil carbonaceous chondrite.

Gibson, E. K., Jr.↗
NASA NTRS1972

Thermal volatilization studies on lunar samples.

The results of thermal volatilization studies on lunar basalts, breccias, and soils, carried out to measure the depletion of selected elemental abundances during heating under vacuum, are evaluated. The kinetics of K, Rb, and Pb loss are found to be sufficiently fast to permit vaporization and loss of these elements during the production of impact glasses. There is little probability that lunar basalt flows have lost a significant percentage of K, Rb, and Na by volatilization, unless the flow is extensively stirred. The uniformly low Na concentrations of mare basalts cannot be attributed to post eruption vaporization and loss on Na.

Gibson, E. K., Jr.↗