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Giguere, P. T.

Publications and source records attributed to Giguere, P. T..

A model of a comet coma with interstellar molecules in the nucleus

The coma of a comet is modeled assuming the icy nucleus contains interstellar molecules. This composition overcomes discrepancies between observation and earlier model predictions for CN, C2, C3, and NH2 abundances. It is found that the abundances of CN, C2, and C3-bearing compounds in the nucleus must be constrained to trace amounts in order to account for the observed column densities. NH3 also cannot be abundant by more than about 1%. The model gives good agreement with observed relative ranges of neutral species in the coma as well as with their observed relative intensity dependence on heliocentric distance. The size of the nucleus and the heliocentric ranges considered are relevant to comet Halley.

Biermann, L.

Photochemical processes in the inner coma

Models for the inner-coma chemistry of comets are reviewed. The physics relevant to the coma's chemistry is summarized, and the interaction of solar radiation with the coma is described, along with photolytic and chemical processes. The formation and destruction of several observed species are traced through a chemical reaction network, and model results are compared with observations. The species considered include CN, C2, C3, NH2, CH, CO, CO(+), OH, H2O, HCO, C2H4, and C2H3. The models most consistent with observations are shown to indicate that only trace amounts (2% in all) of molecules bearing CN, C2, C3, and NH2 can be present in the nucleus of a comet.

Huebner, W. F.

Observational data needs useful for modeling the coma

A computer model of comet comae is described; results from assumed composition of frozen gases are summarized and compared to coma observations. Restrictions on relative abundance of some frozen constituents are illustrated. Modeling, when tightly coupled to observational data, can be important for comprehensive analysis of observations, for predicting undetected molecular species and for improved understanding of coma and nucleus. To accomplish this, total gas production rates and relative elemental abundances of H:C:N:O:S are needed as a function of heliocentric distance of the comet. Also needed are relative column densitites and column density profiles with well defined diaphragm range and pointing position on the coma. Production rates are less desirable since they are model dependent. Total number (or upper limits) of molecules in the coma and analysis of unidentified spectral lines are needed also.

Huebner, W. F.

Radio observation of comet Meier /1978f/ in 18-cm OH lines

Observations of 18-cm OH spectral lines in comet Meier (1978f) with the 1000-ft. Arecibo telescope show spatial resolution of the OH coma by the 2.9 arcmin beam (=3.7 x 10 to the 5th km). The data agree with predictions of the solar Fraunhofer spectrum-pumping theory of comet OH excitation. On the assumption that the OH parent molecule (e.g., H2O) has a Haser-model scale length of about 1.0 x 10 to the 5th km at heliocentric distance 1 AU, an OH scale length of less than 10 to the 6th km, and probably near 1.0 x 10 to the 5th km is derived. Assuming a recently calculated value of the OH lifetime and the solar radiative pumping model, the results indicate an OH production rate of 10 to the 29th Kayser at heliocentric distance 2 AU.

Giguere, P. T.

A model of comet comae. II - Effects of solar photodissociative ionization

Improvements to a computer model of coma photochemistry are described. These include an expansion of the chemical reactions network and new rate constants that have been measured only recently. Photolytic reactions of additional molecules are incorporated, and photolytic branching ratios are treated in far greater detail than previously. A total of 25 photodissociative ionization (PDI) reactions are now considered (as compared to only 3 PDI reactions previously). Solar PDI of the mother molecule CO2 is shown to compete effectively with photoionization of CO in the production of observed CO(+). The CO(+) density peak predicted by the improved model, for CO2 or CO mother molecules, is deep in the inner coma, in better agreement with observation than the old CO2 model. However, neither CO2 nor CO mother molecule calculations reproduce the CO(+)/H2O(+) ratio observed in comet Kohoutek. PDI products of CO2, CO, CH4, and NH3 mother molecules fuel a complex chemistry scheme, producing inner coma abundances of CN, C2, and C3 much greater than previously calculated.

Huebner, W. F.

Constraints on the molecular properties of interstellar X-ogen derived from radio observations

Twenty-eight X-ogen emission sources at 89.189 GHz have been detected and observed. Twenty of these are new X-ogen sources which also contain other interstellar molecules. No infrared stars are found to be X-ogen sources. A new rest frequency (89,188.65 MHz) is derived for X-ogen. It is shown that X-ogen is not SiC, C2H, or any molecule with spin-doubling, hyperfine structure, or both.

Hollis, J. M.

Radio detection of interstellar dimethyl ether

The detection of interstellar dimethyl ether, in emission from the direction of the Orion Nebula molecular cloud, is reported. The largest molecule detected in space, dimethyl ether has a large collisional cross section and C (sub 2V) symmetry. Hence, it should be useful for future studies of molecular pumping models.

Snyder, L. E.