Microstructure development of calcium carbonate cement through polymorphic transformations
Not Available
Hargis, Craig W. (ORCID:0000000170097328)↗
Engineering topics
Gilliam, Ryan J.
Publications and source records attributed to Gilliam, Ryan J..
Calcium Carbonate Cement: A Carbon Capture, Utilization, and Storage (CCUS) Technique
A novel calcium carbonate cement system that mimics the naturally occurring mineralization process of carbon dioxide to biogenic or geologic calcium carbonate deposits was developed utilizing carbon dioxide-containing flue gas and high-calcium industrial solid waste as raw materials. The calcium carbonate cement reaction is based on the polymorphic transformation from metastable vaterite to aragonite and can achieve >40 MPa compressive strength. Due to its unique properties, the calcium carbonate cement is well suited for building materials applications with controlled factory manufacturing processes that can take advantage of its rapid curing at elevated temperatures and lower density for competitive advantages. Examples of suitable applications are lightweight fiber cement board and aerated concrete. The new cement system described is an environmentally sustainable alternative cement that can be carbon negative, meaning more carbon dioxide is captured during its manufacture than is emitted.
36 MATERIALS SCIENCE↗
Ion exchange membranes, electrochemical systems, and methods
Disclosed herein are ion exchange membranes, electrochemical systems, and methods that relate to various configurations of the ion exchange membranes and other components of the electrochemical cell.
36 MATERIALS SCIENCE↗
Ion exchange membranes, electrochemical systems, and methods
Disclosed herein are ion exchange membranes, electrochemical systems, and methods that relate to various configurations of the ion exchange membranes and other components of the electrochemical cell.
36 MATERIALS SCIENCE↗
Systems and methods for separation and purification of products
There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with an unsaturated hydrocarbon and/or a saturated hydrocarbon to form products. Separation and/or purification of the products as well as of the metal ions in the lower oxidation state and the higher oxidation state, is provided herein.
Weiss, Michael Joseph↗
Electrochemical systems and methods
Disclosed herein are ion exchange membranes, electrochemical systems, and methods that relate to various configurations of the ion exchange membranes and other components of the electrochemical cell.
30 DIRECT ENERGY CONVERSION↗
On-line monitoring of process/system
Disclosed herein are methods and systems that relate to an on-line monitoring of a process/system by controlling rate of oxidation of metal ions at an anode in an anode electrolyte of an electrochemical process and controlling rate of reduction of the metal ions in a catalysis process to achieve steady state.
Gilliam, Ryan J.↗
Ion exchange membranes, electrochemical systems, and methods
Disclosed herein are ion exchange membranes, electrochemical systems, and methods that relate to various configurations of the ion exchange membranes and other components of the electrochemical cell.
Gilliam, Ryan J.↗
Systems and methods for preparation and separation of products
There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with hydrogen gas, an unsaturated hydrocarbon, and/or a saturated hydrocarbon to form products.
25 ENERGY STORAGE↗
Electrochemical systems and methods using metal halide to form products
There are provided electrochemical methods and systems to form one or more organic compounds or enantiomers thereof selected from the group consisting of substituted or unsubstituted dioxane, substituted or unsubstituted dioxolane, dichloroethylether, dichloromethyl methyl ether, dichloroethyl methyl ether, chloroform, carbon tetrachloride, phosgene, and combinations thereof.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Measurement of ion concentration in presence of organics
Disclosed herein are systems and methods that relate to use of ultramicroelectrodes (UME) in measurement of ion concentration in presence of one or more organic compound(s).
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Systems and methods for separation and purification of products
There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with an unsaturated hydrocarbon and/or a saturated hydrocarbon to form products. Separation and/or purification of the products as well as of the metal ions in the lower oxidation state and the higher oxidation state, is provided herein.
36 MATERIALS SCIENCE↗
Systems and methods for preparation and separation of products
There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with hydrogen gas, an unsaturated hydrocarbon, and/or a saturated hydrocarbon to form products.
30 DIRECT ENERGY CONVERSION↗