Engineering topics

Gillis, Robert Chad

Publications and source records attributed to Gillis, Robert Chad.

5 records

DOE OSTI2018

The SNS Moderator Demonstration Facility

We describe a moderator demonstration facility at the Spallation Neutron Source (SNS). We will use the Beam Test Facility (BTF) at SNS to provide a moderator neutronics test stand with which we will verify the performance gains expected from the innovative moderator concepts central to the SNS Second Target Station. These concepts include large-volume para-hydrogen moderators and high-brightness moderators, as well as new moderator materials. The BTF provides a test facility for the new Radio-Frequency Quadrupole accelerator (RFQ) to be installed at SNS and produce a pulsed H− beam of 2.5 MeV energy. We will add to the BTF a beam chopper similar to that already used in the SNS at the RFQ exit, various beam transport components, a neutron-producing target, a cryogenic moderator test stand, a reflector-shielding assembly, and a performance assessment neutron beamline.

Iverson, Erik B.↗

DOE OSTI2018

Raman Spectroscopy as an ortho-para diagnostic of liquid hydrogen moderators

The intense radiation environment of a neutron moderator provides a mechanism for significant up-conversion of parahydrogen to orthohydrogen inside the moderator, as well as intrinsically catalyzing relaxation of orthohydrogen to parahydrogen. It is plausible that the steady-state orthohydrogen fraction of a moderator in a radiation environment such as at the Spallation Neutron Source (SNS) or the European Spallation Source (ESS) is as high as 30 % without supplemental catalysis. Direct measurement of the orthohydrogen fraction in the liquid hydrogen flow itself is essential to predict and monitor moderator performance, especially for thick or flat moderator concepts such as the ones that have been proposed for the ESS and for upgrades to the SNS. Raman spectroscopy provides a well-known method for directly measuring the hydrogen make-up in an unambiguous way. We describe our tests of Raman spectroscopy for application to the measurement of the orthohydrogen fraction of the hydrogen moderators at SNS and at the ESS. As part of this work, we have additionally developed a sample holder that has been used to perform simultaneous Raman and neutron vibrational spectroscopy on the VISION spectrometer at SNS. We discuss our plans to incorporate such a system as a diagnostic for liquid hydrogen moderators at SNS and at the ESS.

Gillis, Robert Chad↗

DOE OSTI2018

Characterization of a Liquid Ammonia Moderator

Liquid ammonia is an attractive intermediate temperature moderating material, offering a high hydrogen density, low tendency toward radiation-initiated polymerization, and broad accessible temperature range. The LENS collaboration has characterized decoupled poisoned liquid ammonia moderators in an attempt to validate scattering kernels we are generating. Additionally, we have measured a borated water moderator in order to test a model for predicting detailed moderator performance at one level of intrinsic homogeneous neutron capture based on measurements at other levels of such capture. We describe both sets of measurements, as well as use them to illustrate some of the reproducibility challenges associated with moderator characterization measurements on compact neutron sources.

Iverson, Erik B.↗

DOE OSTI2018

A sample holder for simultaneous Raman and neutron vibrational spectroscopy

We have built a sample holder (called a center stick or sample stick) for performing simultaneous Raman and neutron vibrational spectroscopy on samples of material at the VISION neutron vibrational spectrometer of the Spallation Neutron Source at Oak Ridge National Laboratory. This equipment holds material samples in the neutron beam within the cryogenic environment of the VISION spectrometer, allowing for samples to be studied at temperatures as low as 5 K. It also provides the capability for gas to be loaded to or evacuated from the sample while it is loaded at VISION. The optical components for directing and filtering light are located within the cryogenic volume, in physical proximity to the sample. We describe the construction of this sample holder and discuss our first measurements of simultaneous Raman and neutron vibrational spectra. Here, the samples that we report on were of 4-nitrophenol at a temperature of 20 K and of cryogenic hydrogen of a number of different orthohydrogen fractions.

4-nitrophenol↗

DOE OSTI2016

Hydrogen adsorption on two catalysts for the ortho- to parahydrogen conversion: Cr-doped silica and ferric oxide gel

Molecular hydrogen exists in two spin-rotation coupled states: parahydrogen and orthohydrogen. Due to the variation of energy with rotational level, the occupation of ortho- and parahydrogen states is temperature dependent, with parahydrogen being the dominant species at low temperatures. Here, the equilibrium at 20 K (99.8% parahydrogen) can be reached by natural conversion only after a lengthy process. With the use of a suitable catalyst, this process can be shortened significantly. Two types of commercial catalysts currently being used for ortho- to parahydrogen conversion are: iron(III) oxide (Fe 2 O 3 , IONEX®), and chromium(II) oxide doped silica catalyst (CrO·SiO 2 , OXISORB®). We investigate the interaction of ortho- and parahydrogen with the surfaces of these ortho–para conversion catalysts using neutron vibrational spectroscopy. The catalytic surfaces have been characterized using X-ray absorption fine structure (XAFS) and X-ray/neutron pair distribution function measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗