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Giuliano Liuzzi

Publications and source records attributed to Giuliano Liuzzi.

The Climatology of Carbon Monoxide on Mars as Observed by NOMAD Nadir-geometry Observations

More than a full Martian year of observations have now been made by the Nadir Occultation for MArs Discovery (NOMAD) instrument suite on-board the ExoMars Trace Gas Orbiter. Radiative transfer modeling of NOMAD observations taken in the nadir geometry enable the seasonal and global-scale variations of carbon monoxide gas in the Martian atmosphere to be characterized. These retrievals show the column-averaged volume mixing ratio of carbon monoxide to be about 800 ppmv, with significant variations at high latitudes caused by the condensation and sublimation of the background CO2 gas. Near summer solstice in each hemisphere, the CO volume mixing ratio falls to 400 ppmv in the south and 600 ppmv in the north. At low latitudes, carbon monoxide volume mixing ratio inversely follows the annual cycle of surface pressure. Comparison of our retrieved CO volume mixing ratio against that computed by the GEM-Mars general circulation model reveals a good match in their respective seasonal and spatial trends, and can provide insight into the physical processes that control the distribution of CO gas in the current Martian atmosphere.

Mars↗

Water Heavily Fractionated as it Ascends on Mars as Revealed by ExoMars/NOMAD

Isotopic ratios, and in particular the water D/Hratio, are powerful tracers of the evolutionand transportof water on Mars. From measurements performed with ExoMars/NOMAD, we observe dramatic and rapid variability of the D/H along altitude on Mars and across the whole planet. The observations (from April 2018 to April 2019) sample a broad range of events on Mars, including aglobal dust storm, the evolution ofwater released from the southern polar cap during southern summer, the equinox phases, and a short but intense regional dust storm. In three instances, we observe water at very high altitudes (>80 km), the prime region where water is photo-dissociated andstarts its escape to space.Rayleigh distillation appears the be the driving force affecting the D/H in many cases, yet in someinstances,the exchange of water reservoirs with distinctive D/H could be responsible.

Geronimo L Villanueva↗

Comprehensive Investigation of Mars Methane and Organics with ExoMars/NOMAD

Methane (CH4) on Mars has attracted a great deal of attention since it was first detected in January 2003. As methane is considered a potential marker for past/present biological or geological activity, any possible detection would require evidence with strong statistical significance. Ethane (C2H6) and ethylene (C2H4) are also relevant chemical species as their shorter lifetimes in the Martian atmosphere make them excellent tracers for recent and ongoing releases. If detected, a CH4/C2Hn ratio could aid in constraining the potential source of organic production. Here we present the results of an extensive search for hydrocarbons in the Martian atmosphere in 240,000 solar occultation measurements performed by the ExoMars Trace Gas Orbiter/NOMAD instrument from April 2018 to April 2019. The observations are global, covering all longitudes and latitudes from 85°N to 85°S, and sampled from 6-100 km altitude with a typical vertical resolution of 2km. There were no statistically significant detections of organics and new stringent upper limits for global ethane and ethylene were set at 0.1 ppbv and 130.7 ppbv, respectively. No global background level of methane was observed, obtaining an upper limit of 0.06 ppbv, in agreement with early results from ExoMars (Korablev et al., 2019). Dedicated searches for localized plumes at more than 2000 locations provided no positive detections, implying that if methane were released in strong and rapid events, the process would have to be sporadic.

Elise W Knutsen↗

Martian Dust Storm Impact on Atmospheric H2o and D/H Observed By Exomars Trace Gas Orbiter

Global dust storms on Mars are rare1,2 but can affect the Martian atmosphere for several months. They can cause changes in atmospheric dynamics and inflation of the atmosphere3, primarily owing to solar heating of the dust3. In turn, changes in atmospheric dynamics can affect the distribution of atmospheric water vapour, with potential implications for the atmospheric photochemistry and climate on Mars4. Recent observations of the water vapour abundance in the Martian atmosphere during dust storm conditions revealed a high-altitude increase in atmospheric water vapour that was more pronounced at high northern latitudes5,6, as well as a decrease in the water column at low latitudes7,8. Here we present concurrent, high-resolution measurements of dust, water and semiheavy water (HDO) at the onset of a global dust storm, obtained by the NOMAD and ACS instruments onboard the ExoMars Trace Gas Orbiter. We report the vertical distribution of the HDO/H2O ratio (D/H) from the planetary boundary layer up to an altitude of 80 kilometres. Our findings suggest that before the onset of the dust storm, HDO abundances were reduced to levels below detectability at altitudes above 40 kilometres. This decrease in HDO coincided with the presence of water-ice clouds. During the storm, an increase in the abundance of H2O and HDO was observed at altitudes between 40 and 80 kilometres. We propose that these increased abundances may be the result of warmer temperatures during the dust storm causing stronger atmospheric circulation and preventing ice cloud formation, which may confine water vapour to lower altitudes through gravitational fall and subsequent sublimation of ice crystals3. The observed changes in H2O and HDO abundance occurred within a few days during the development of the dust storm, suggesting a fast impact of dust storms on the Martian atmosphere.

Ann Carine Vandaele↗

No detection of methane on Mars from early ExoMars Trace Gas Orbiter observations

The detection of methane on Mars has been interpreted as indicating that geochemical or biotic activities could persist on Mars today. A number of different measurements of methane show evidence of transient, locally elevated methane concentrations and seasonal variations in background methane concentrations. These measurements, however, are difficult to reconcile with our current understanding of the chemistry and physics of the Martian atmosphere, which—given methane’s lifetime of several centuries—predicts an even, well mixed distribution of methane. Here we report highly sensitive measurements of the atmosphere of Mars in an attempt to detect methane, using the ACS and NOMAD instruments onboard the ESA-Roscosmos ExoMars Trace Gas Orbiter from April to August 2018. We did not detect any methane over a range of latitudes in both hemispheres, obtaining an upper limit for methane of about 0.05 parts per billion by volume, which is 10 to 100 times lower than previously reported positive detections. We suggest that reconciliation between the present findings and the background methane concentrations found in the Gale crater would require an unknown process that can rapidly remove or sequester methane from the lower atmosphere before it spreads globally.

Michael Doyle Smith↗