Transported Low-temperature Geothermal Energy for Thermal End Uses
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Engineering topics
Publications and source records attributed to Gluesenkamp, Kyle R.
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The use of geothermal energy is an emerging area for improving the nation’s energy resiliency. Conventionally, geothermal energy applications have focused on power generation using high temperature hydrothermal resources or enhanced geothermal systems. However, many low temperature (below 150°C/300°F) geothermal resources are also available but have not been fully utilized. For example, it is estimated that 25 billion barrels of geothermal fluid (mostly water and some dissolved solids) at 176°F to 302°F (80°C to 150°C) is coproduced annually at oil and gas wells in the United States (DOE 2015). The heat contained in coproduced geothermal fluid (also referred as “coproduced water”) is typically wasted because the fluid is reinjected back into the ground without extracting the heat.
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The boundary temperatures for any sorption-based technology can be estimated on the basis of Trouton s hypothesis that isosteres, extrapolated to infinite pressure (or analogously to infinite temperature) meet at a single point. In this paper we discuss the consequences of this hypothesis for many sorption devices that are thermally operated, suitable for exploiting renewable energy resources, or making better use of high or low level thermal energy. Trouton s hypothesis is independent of the working fluids making it particularly useful to both liquid-vapor and solid-vapor systems. We exemplify the use of the derived boundary temperatures derived from Trouton s hypothesis to important processes such as ice making, space cooling in hot climates, deep freezing, and residential hot water production. The boundary temperatures help determine which sorption or solar heating technology may be better suited to serve the given application, or whether it is beyond the scope of sorption systems.
During heating of a water heater tank, the vertical temperature stratification of the water can be increased or decreased, depending on the method of heating. Methods that increase stratification during heating include (1) removing cold water from the tank bottom, heating it, and re-introducing it to the tank top at relatively low flow rate, (2) using a heat exchanger wrapped around the tank, through which heating fluid (with finite specific heat) flows from top to bottom, and (3) using an immersed heat element that is relatively high in the tank. Using such methods allows for improved heat pump water heater (HPWH) cycle efficiencies when the heat pump can take advantage of the lower temperatures that exist lower in the tank, and accommodate the resulting glide. Transcritical cycles are especially well-suited to capitalize on this opportunity, and other HPWH configurations (that have been proposed elsewhere) may benefit as well. This work provides several stratification categories of heat pump water heater tank configurations relevant to their stratification potential. To illustrate key differences among categories, it also compiles available experimental data for (a) single pass pumped flow, (b) multi-pass pumped flow, and (c) top-down wrapped tank with transcritical refrigerant.
Gas heat pump water heaters (HPWHs) can improve water heating efficiency with zero GWP and zero ODP working fluids. The energy factor (EF) of a gas HPWH is sensitive to several factors. In this work, expressions are derived for EF of gas HPWHs, as a function of heat pump cycle COP, tank heat losses, burner efficiency, electrical draw, and effectiveness of supplemental heat exchangers. The expressions are used to investigate the sensitivity of EF to each parameter. EF is evaluated on a site energy basis (as used by the US DOE for rating water heater EF), and a primary energy-basis energy factor (PEF) is also defined and included. Typical ranges of values for the six parameters are given. For gas HPWHs, using typical ranges for component performance, EF will be 59 80% of the heat pump cycle thermal COP (for example, a COP of 1.60 may result in an EF of 0.94 1.28). Most of the reduction in COP is due to burner efficiency and tank heat losses. Gas-fired HPWHs are theoretically be capable of an EF of up to 1.7 (PEF of 1.6); while an EF of 1.1 1.3 (PEF of 1.0 1.1) is expected from an early market entry.
This report summarizes the results of a literature review in three areas: available low-temperature/coproduced geothermal resources in the United States, energy use for space conditioning in commercial buildings, and state of the art of geothermal absorption cooling.
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Ionic liquids (ILs) are a unique class of solvents with many potential applications, including absorption heating/cooling. Due to the large number of possible combinations of cations and anions, it is possible to tune the IL to obtain the required properties for the application of interest. Many ILs are very hydrophilic, while even the most hydrophobic ILs often absorb significant amounts of water. The presence of water in an IL can have a large effect on the system properties. For instance, a small amount of dissolved water often leads to a dramatic reduction in the viscosity of the mixture. Dissolved water also affects the ionic conductivity of ILs and alters the solvation power of ILs for both polar and non-polar solutes. Knowledge of the phase diagram of these IL/water mixtures therefore is essential when designing absorption heating systems. Measuring isotherms often requires time consuming and/or expensive experiments, and does not necessarily lead to a deeper understanding of the molecular level interactions responsible for water-IL interactions. In contrast, molecular simulations are relatively inexpensive to perform, allowing one to screen potential ILs for a given application. Simulation also provides a detailed picture of how water and a given IL interact, thereby providing insight into ways of designing an IL to have a desired water solubility. Toward this end, atomistic-level Monte Carlo (MC) simulations have been performed to predict isotherms for a variety of IL/water mixtures. The simulations predict that exchanging some of the IL cations with a small metal cation can lead to an increase in the hydrophilicity of the IL, which impacts the capacity of the fluid and the enthalpy of mixing. Molecular dynamics simulations, which unlike Monte Carlo simulations capture timedependent properties, were also carried out to estimate the relative viscosities of the solutions.
In this study, development of a novel system for combined water heating, dehumidification, and space evaporative cooling is discussed. Ambient water vapor is used as a working fluid in an open system. First, water vapor is absorbed from an air stream into an absorbent solution. The latent heat of absorption is transferred into the process water that cools the absorber. The solution is then regenerated in the desorber, where it is heated by a heating fluid. The water vapor generated in the desorber is condensed and its heat of phase change is transferred to the process water in the condenser. The condensed water can then be used in an evaporative cooling process to cool the dehumidified air exiting the absorber, or it can be drained if primarily dehumidification is desired. Essentially, this open absorption cycle collects space heat and transfers it to process water. This technology is enabled by a membrane-based absorption/desorption process in which the absorbent is constrained by hydrophobic vapor-permeable membranes. Constraining the absorbent film has enabled fabrication of the absorber and desorber in a plate-and-frame configuration. An air stream can flow against the membrane at high speed without entraining the absorbent, which is a challenge in conventional dehumidifiers. Furthermore, the absorption and desorption rates of an absorbent constrained by a membrane are greatly enhanced. Isfahani and Moghaddam (Int. J. Heat Mass Transfer, 2013) demonstrated absorption rates of up to 0.008 kg/m2s in a membrane-based absorber and Isfahani et al. (Int. J. Multiphase Flow, 2013) have reported a desorption rate of 0.01 kg/m2s in a membrane-based desorber. The membrane-based architecture also enables economical small-scale systems, novel cycle configurations, and high efficiencies. The absorber, solution heat exchanger, and desorber are fabricated on a single metal sheet. In addition to the open arrangement and membrane-based architecture, another novel feature of the cycle is recovery of the solution heat energy exiting the desorber by process water (a process-solution heat exchanger ) rather than the absorber exiting solution (the conventional solution heat exchanger ). This approach has enabled heating the process water from an inlet temperature of 15 C to 57 C (conforming to the DOE water heater test standard) and interfacing the process water with absorbent on the opposite side of a single metal sheet encompassing the absorber, process-solution heat exchanger, and desorber. The system under development has a 3.2 kW water heating capacity and a target thermal coefficient of performance (COP) of 1.6.
ABsorption SIMulation, ABSIM, was developed for the simulation of absorption systems by The Oak Ridge National Laboratory during 1980s and 1990s. ABSIM provides a platform for users to investigate various cycle configurations and working fluids, to calculate their operating parameters, to predict their performance, and to compare them with each other on a uniform basis. ABSIM is indeed a very useful and accurate tool for researchers to investigate various absorption systems. However, it has not been well maintained: it is incompatible with recent operating systems; the interface needs improved user-friendliness, and the system needs better parameter setting and debugging tools to help achieve convergence. Therefore, it is highly needed to update and improve ABSIM. The paper presents recent efforts to improve ABSIM s compatibility with current operating systems, user interface, and analysis capabilities. The paper details the features and functions of the newly updated ABSIM software. The new ABSIM still uses the previously validated calculation engine of the old ABSIM. The new graphic user interfaces (GUI) were developed in Qt, which is an open source license GUI software based on C++. XML was used as the database for data storage in the new ABSIM. The new ABSIM has been designed to be easily learned and used. It has enhanced editing and construction functions, plus enhanced analysis features including parametric tables, plotting, property plots, and master panels for debugging. A single effect water/LiBr absorption system is used as a case study in this paper to illustrate the features, capabilities, and functions of the new ABSIM. This case study was actually an example system available in the old ABSIM. The new version of ABSIM will be continuously developed to include additional subroutines for the components in liquid desiccant systems. The new ABSIM will be available to public for free. The ultimate goal of the new ABSIM is to allow it to become a simulation platform for both absorption heat pump and liquid desiccant systems.
Adsorption chillers are capable of utilizing inexpensive or free low grade thermal energy such as waste heat and concentrated solar thermal energy. Recently developed low regeneration temperature working pairs allow adsorption chillers to be driven by even lower temperature sources such as engine coolant and flat plate solar collectors. In this work, synthetic zeolite/water was implemented into a 3kW adsorption chiller test facility driven by hot water at 70 C. The zeolite was coated onto two fin-and-tube heat exchangers, with heat recovery employed between the two. Cyclic steady state parametric studies were experimentally conducted to evaluate the chiller's performance, resulting in a cooling coefficient of performance (COP) ranging from 0.1 to 0.6 at different operating conditions. Its performance was compared with published values for other low regeneration temperature working pairs. The physical limitations of the synthetic zeolite revealed by parametric study results were then discussed. A novel operating control strategy was proposed based on the unique characteristics of synthetic zeolite. In addition, a physics-based COP prediction model was derived to predict the performance of the chiller under equilibrium loading, and was validated by the experiment results. This analytical expression can be used to estimate the cyclic steady state performance for future studies.