Engineering topics

Gluesenkamp, Kyle R.

Publications and source records attributed to Gluesenkamp, Kyle R..

42 records · Page 3

DOE OSTI2020

Experimental study on a novel three-phase absorption thermal battery with high energy density applied to buildings

Buildings contribute to 75% of total electricity consumption and 80% of peak electricity demand in the United States. A significant portion of building electricity consumption goes to space conditioning. Therefore, using thermal energy storage (TES) to decouple the building electricity consumption and the fluctuating space-conditioning load has significant potential to shift peak electricity demand and improve the stability of the grid. To provide effective TES within the spatial constraints in buildings, a three-phase absorption thermal battery (TATB) system with very high energy storage density was designed and studied. The TATB stores low-temperature heat in hydrate crystals of salts and supports space conditioning through absorption systems. In this study, a benchtop TATB using lithium chloride (LiCl) hydrate crystals as the storage material was tested under practical operating conditions for its energy storage density and discharge rate. We report the TATB successfully generated LiCl hydrate crystals during charging mode and then dissolved the crystals during discharging mode. A material-based energy storage density of 300 kWh/m 3 (specific energy of 903 kJ/kg) was achieved with a discharge rate of up to 1.3 kW thermal energy. The test results verified the high performance of the TATB and encouraged further development of this technology.

25 ENERGY STORAGE↗

DOE OSTI2020

Ammonia-based chemisorption heat pumps for cold-climate heating applications: A comprehensive review

This paper reviews the state of the art of chemisorption heat pumps that use ammonia as the refrigerant for cold-climate heating applications. In such a system, ammonia vapor is adsorbed by the solid salt through reversible chemisorption reactions, and the thermal effect of the reaction and ammonia phase change is used to extract heat from a cold environment and supply heat to a warm environment. With the high latent heat and low boiling point of ammonia as a low-temperature refrigerant and the high sorption capacity of ammonia-based chemisorption reactions, chemisorption heat pumps have the potential to produce high-efficiency heating, particularly for cold climates. This review first briefly introduces the basics of ammonia-based chemisorption heat pump systems. Then, the latest development of sorbent materials, including ammoniate salts and heat-conductive porous matrix materials, are summarized with the focus on low-temperature heating conditions. The design of system components, as well as cycle configurations, in the literature are summarized. This review concludes with highlights of recent developments on these topics and suggestions of areas for further research.

42 ENGINEERING↗

DOE OSTI2020

Design screening and analysis of gas-fired ammonia-based chemisorption heat pumps for space heating in cold climate

Thermally-driven ammonia-based chemisorption heat pumps (CSHP) have the potential to provide high-efficiency space heating in cold climates. Using the reversible chemical bond between sorbent salt and ammonia, CSHP thermochemically pumps heat from the cold ambient to the end-uses of space heating at 50 °C. The heating coefficient of performance (COP) of a CSHP largely depends on the selection of the sorbent salts, cycle configuration, and the system operation. This study uses a thermodynamic model to investigate the performance of six CSHP system configurations, including four single-effect and two double-effect cycles. The feasibility and performance of 121 available NH 3 /salt reactions are studied for each configuration. The thermal COP of the cycles and the primary energy COP of the gas-fired CSHP systems are evaluated assuming 50 °C supply temperature for building space heating and the optimal system designs are identified. The highest thermal COP for single-effect and double-effect cycles under -25 °C ambient temperatures are predicted to be 1.22 and 1.57, respectively. The corresponding primary energy COPs are above 1.0 and 1.15, which are 30% higher than condensing furnaces and is sustained into the same cold temperatures.

42 ENGINEERING↗

DOE OSTI2020

Nanoarray-Based Monolithic Adsorbers for SO 2 Removal

Nanoarray-based monolithic catalysts have been developed for various applications, including CO oxidation, hydrocarbon combustion, lean NO x trapping, and low-pressure CO 2 hydrogenation. In this work, SO 2 adsorption properties have been explored and evaluated on the cordierite honeycomb monoliths grown with zinc oxide nanoarray (ZnO), zinc oxide nanoarray washcoated by BaCO 3 nanoparticles (ZnO/BaCO 3 ), and manganese oxide nanowire array with cryptomelane structure (MnO x ) at a temperature range from 50 to 425 °C. All samples show temperature-dependent SO 2 adsorption behaviors. The adsorption results reveal the performance order: MnO x > ZnO/BaCO 3 > ZnO, with ~ 90% SO 2 adsorbed in MnO x at 425 °C. Washcoated BaCO 3 contributes to the improvement of SO 2 adsorption in ZnO nanoarray, and the best performance displayed in MnO x may be attributed to their high specific surface area. After regeneration, nanoarrays all exhibit good thermal stability during test-regeneration cycles. No additional phase is formed in regenerated ZnO nanoarrays (ZnO-R), while BaCO 3 is converted to BaSO 4 in the regenerated ZnO/BaCO 3 nanoarrays (ZnO/BaCO 3 -R), and the sulfur species (possibly MnSO 4 ) and Mn 2 O 3 are found in regenerated MnO x nanoarrays (MnO x -R). It is noted that a small amount of sulfur species (possibly MnSO 4 ) may promote the SO 2 adsorption of MnO x -R at a lower temperature, while the formed Mn 2 O 3 contributes to the deactivation of MnO x -R.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Measurement and analysis of clothes dryer air leakage

Each year clothes dryer appliances are sold globally in the tens of millions. Both vented and ventless types are common and are heated by combustion, electric resistance, or electric heat pumps. In the dyer air path, segments can be defined between components such as the drum, blower, filter, screens or grills, and heat exchangers (where applicable). In this work, a technique was developed to experimentally measure air leakage into and from the segments of a clothes dryer. Detailed leakage measurements were taken on two vented and one ventless residential clothes dryer. The measurements were quantified as a leakage flow coefficient for each segment. For two dryers (one vented and one ventless), these flow coefficients were combined with in situ operating pressure measurements to determine leakage flow rates for each segment. For these two units under normal operation with air pressures within 0.5 kPa (50 mm water column) of ambient pressure, volumetric system air leakage was found to be about 20–60% of the blower airflow. Furthermore, a quasi–steady state psychrometric analysis was conducted on vented dryers with negatively pressurized drums. The analysis revealed that leakage quantity, location, and direction are essential to achieving an acceptable energy balance and accurate modeling results for a vented heat pump clothes dryer but are of limited significance for vented electric resistance clothes dryers.

42 ENGINEERING↗

DOE OSTI2020

Experimentally Measured Thermal Masses of Adsorption Heat Exchangers

The thermal masses of components influence the performance of many adsorption heat pump systems. However, typically when experimental adsorption systems are reported, data on thermal mass are missing or incomplete. This work provides original measurements of the thermal masses for experimental sorption heat exchanger hardware. Much of this hardware was previously reported in the literature, but without detailed thermal mass data. The data reported in this work are the first values reported in the literature to thoroughly account for all thermal masses, including heat transfer fluid. The impact of thermal mass on system performance is also discussed, with detailed calculation left for future work. The degree to which heat transfer fluid contributes to overall effective thermal mass is also discussed, with detailed calculation left for future work. This work provides a framework for future reporting of experimental thermal masses. The utilization of this framework will enrich the data available for model validation and provide a more thorough accounting of adsorption heat pumps.

30 DIRECT ENERGY CONVERSION↗