Engineering topics

Gonzales, David A.

Publications and source records attributed to Gonzales, David A..

3 records

NASA NTRS1993

Vibration-dissociation coupling in CO, N2 and O2 - An evaluation of analytic transition rate expressions

Closed form expressions for inelastic state-to-state and state-specific dissociative rate coefficients for utilization in vibrational master equation studies of shock heated CO, N2, and O2 highly dilute in Ar are considered. The master equation is linearized by neglecting diatom-diatom collisions and recombination. Master equation results indicate that the most significant contribution to dissociation comes from low and mid lying vibrational levels.

Gonzales, David A.↗

NASA NTRS1992

Rate calculations for the simultaneous vibrational relaxation and dissociation of nitrogen

Experimental data on vibrational relaxation and dissociation rates in highly nonequilibrium gases are scarce. Recently there have been several attempts at generating these rates by direct calculation of inelastic collision cross-sections. Some issues that need to be considered if such calculations are to be used as a basis for analysis and design are examined. In particular, the following are examined: (1) collinear vs 3D scattering models, (2) accurate intermolecular potentials, (3) closed channels and acceleration schemes, (4) thermal averaging and thermal rates, and (5) code validation. It has been necessary to confront these issues during the course of N2-N2 and N2-N inelastic cross-section calculations.

Gonzales, David A.↗

NASA NTRS1991

Vibrational relaxation and dissociation in nitrogen

Calculations of the vibrational and dissociation transition probabilities are made for N2-N2 and N2-N collisions by means of a semiclassical N-state approximation. The flaws in previous techniques are reviewed, with special attention given to the prediction of overtones. The method presented ignores the effects of molecular rotation and employs a revised extended Rydberg intermolecular potential to describe diatom-diatom and diatom-atom collisions. The collision velocities investigated exhibit probabilities of less than unity by means of the N-state method. The continuum is quantized to treat dissociation, and the collision results demonstrate probability enhancements for V-V-T transitions in both bound-bound and bound-free transitions. The technique is of particular interest for the theoretical modeling of reentry flows such as those encountered in aerobraking maneuvers.

Varghese, Philip L.↗