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Gonzalez, Fernando

Publications and source records attributed to Gonzalez, Fernando.

3 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Modeling of Reactor Design and Optimization for Scale-Up of the Catalyxx Process for Ethanol Conversion to Higher Alcohol Biofuels

This report summarizes the results of a collaborative efforts between Oak Ridge National Laboratory (ORNL) and Catalyxx Inc. to investigate scale-up of Catalyxx’s Ethanol upgrading to higher alcohols process. The study was funded by the U.S. Department of Energy (DOE) Bioenergy Technologies Office (BETO) under CRADA (Cooperative Research and Development Agreement) No: NFE-20-08396. The project is part of the Direct Funding Opportunity (DFO) for Computational Science to Enable Bioenergy program which utilized computational toolsets developed by the Consortium for Computational Physics and Chemistry, a multi-laboratory consortium in BETO. The report here summarizes a packed-bed reactor modeling effort spanning the range from lab to industrial scale (from 4 gram to 5-ton catalyst beds), and examining reactor design, process optimization strategies, and suggested design and operating conditions for Catalyxx’s ethanol upgrading plants. The results in this report have been shared in monthly steering meetings and presentations are available in the shared data house owned by Catalyxx. The modeling effort helped to define optimum operation conditions for maximum alcohol selectivity and yield: i.e., temperature control scenarios ranging from adiabatic to isothermal, feed rate, pressure, and inlet H 2 /Ethanol ratio. The modeling results were verified at lab-(4 gram) and pre-pilot (4 kg) scales and has been used to evaluate a 5-ton packed-bed reactor and identify operating conditions to maximize the butanol yield. Special focus was given to understanding mass-transfer effects in the pre-pilot and pilot-scale reactors, over the domain of flow rate, pressure, feed composition, pellet size, shape, porosity, bed voidage, and reactor dimensions (i.e., length/diameter). Modeling was also used to evaluate innovative reactor design concepts such as water removal to improve alcohol selectivity and yield, and a reactor with an additional side inlet to facilitate quenching. These concepts were thoroughly explored, and potential benefits were disclosed. The results in this report are summarized and described qualitatively to protect the IP rights of Catalyxx. The details have been shared with the Catalyxx team in the regular steering meetings. At the end of the project, Catalyxx Inc. announced a successful demonstration of pilot scale operation in Seville, Spain.

02 PETROLEUM↗
NASA NTRS2016

Planetary Defense Architecture for Mitigating Short-Term Warning Cosmic Threats: READI Project

Earth is being constantly bombarded by a large variety of celestial bodies and has been since its formation 4.5 billion years ago. Among those bodies, mainly asteroids and comets, there are those that have the potential to create large scale destruction upon impact. The only extinction-level impact recorded to date was 65 million years ago, during the era of dinosaurs. The probability of another extinction-level, or even city-killer, impact may be negligible, but the consequences can be severe for the biosphere and for our species. Therefore it is highly imperative for us to be prepared for such a devastating impact in the near future, especially since humanity is at the threshold of wielding technologies that allow us to do so. Majority of scientists, engineers, and policymakers have focused on long-term strategies and warning periods for Earth orbit crossing Near-Earth Objects (NEOs), and have suggested methods and policies to tackle such problems. However, less attention has been paid to short warning period NEO threats. Such NEOs test current technological and international cooperation capabilities in protecting ourselves, and can create unpredictable devastation ranging from local to global scale. The most recent example is the Chelyabinsk incident in Russia. This event has provided a wakeup call for space agencies and governments around the world towards establishing a Planetary Defense Program. The Roadmap for EArth Defense Initiative (READI) is a project by a team of international, intercultural, and interdisciplinary participants of the International Space University's Space Studies Program 2015 hosted by Ohio University, Athens, OH proposing a roadmap for space agencies, governments, and the general public to tackle NEOs with a short warning before impact. Taking READI as a baseline, this paper presents a technical description of methodologies proposed for detection and impact mitigation of a medium-sized comet (up to 800m across) with a short-warning period of two years on a collision course with Earth. The hypothetical comet is on a highly-inclined orbit having a high probability for Earth impact after its perihelion. For detection, we propose a space-based infrared detection system consisting of two satellites located at the Earth-Moon Lagrange points L1 and L2 coupled with space observatories, like the James Webb telescope and the Centennial telescope. These telescopes are supported by ground-based telescopes, like the Arecibo and Green Bank telescope, in the search for NEOs. Upon detection, the comet is tracked constantly using space- and ground-based telescopes. The deflection system is two-pronged, firstly involving the use of a high energy Directed Energy Laser Terminals (DELT) placed at Sun-Earth Lagrange points L4 and L5 so as to initiate and increase the ablation rate of the comet and deviate it from its collision trajectory, and secondly by the Hypervelocity Comet Intercept Vehicle (HCIV), a space-borne system combining a kinetic impactor with a thermonuclear device. The policy and international collaboration aspects to implement these methods are also outlined in the paper. The techniques mentioned could also be applied to mitigate medium-to-large sized asteroids (up to 2km across).

Laser Applications↗
NASA NTRS2016

Architecture for Mitigating Short-Term Warning Cosmic Threats: READI Project

Earth is being constantly bombarded by a large variety of celestial bodies and has been since its formation 4.5 billion years ago. Among those bodies, mainly asteroids and comets, there are those that have the potential to create large scale destruction upon impact. The only extinction-level impact recorded to date was 65 million years ago, during the era of dinosaurs. The probability of another extinction-level, or even city-killer, impact may be negligible, but the consequences can be severe for the biosphere and for our species. Therefore it is highly imperative for us to be prepared for such a devastating impact in the near future, especially since humanity is at the threshold of wielding technologies that allow us to do so. Majority of scientists, engineers, and policymakers have focused on long-term strategies and warning periods for Earth orbit crossing Near-Earth Objects (NEOs), and have suggested methods and policies to tackle such problems. However, less attention has been paid to short warning period NEO threats. Such NEOs test current technological and international cooperation capabilities in protecting ourselves, and can create unpredictable devastation ranging from local to global scale. The most recent example is the Chelyabinsk incident in Russia. This event has provided a wakeup call for space agencies and governments around the world towards establishing a Planetary Defense Program. The Roadmap for EArth Defense Initiative (READI) is a project by a team of international, intercultural, and interdisciplinary participants of the International Space University's Space Studies Program 2015 hosted by Ohio University, Athens, OH proposing a roadmap for space agencies, governments, and the general public to tackle NEOs with a short warning before impact. Taking READI as a baseline, this paper presents a technical description of methodologies proposed for detection and impact mitigation of a medium-sized comet (up to 800m across) with a short-warning period of two years on a collision course with Earth. The hypothetical comet is on a highly-inclined orbit having a high probability for Earth impact after its perihelion. For detection, we propose a space-based infrared detection system consisting of two satellites located at the Earth-Moon Lagrange points L1 and L2 coupled with space observatories, like the James Webb telescope and the Centennial telescope. These telescopes are supported by ground-based telescopes, like the Arecibo and Green Bank telescope, in the search for NEOs. Upon detection, the comet is tracked constantly using space- and ground-based telescopes. The deflection system is two-pronged, firstly involving the use of a high energy Directed Energy Laser Terminals (DELT) placed at Sun-Earth Lagrange points L4 and L5 so as to initiate and increase the ablation rate of the comet and deviate it from its collision trajectory, and secondly by the Hypervelocity Comet Intercept Vehicle (HCIV), a space-borne system combining a kinetic impactor with a thermonuclear device. The policy and international collaboration aspects to implement these methods are also outlined in the paper. The techniques mentioned could also be applied to mitigate medium-to-large sized asteroids (up to 2km across).

Laser Applications↗