Engineering topics

Gottlieb, C. A.

Publications and source records attributed to Gottlieb, C. A..

14 records

NASA NTRS1997

First astronomical detection of the cumulene carbon chain molecule H2C6 in TMC-1

The cumulene carbenes are important components of hydrocarbon chemistry in low-mass star-forming cores. Here we report the first astronomical detection of the long-chain cumulene carbene H2C6 in the interstellar cloud TMC-1, from observations of two of its rotational transitions: J(K,K') = 7(1,7) --> 6(1,6) at 18.8 GHz and 8(1,8) --> 7(1,7) at 21.5 GHz, using NASA's Deep Space Network 70 m antenna at Goldstone, California. In addition we also observed the shorter cumulene carbene H2C4 at the same position. The fractional abundance of H2C6 relative to H2 is about 4.7 x 10(-11) and that of H2C4 is about 4.1 x 10(-9). The abundance of H2C6 is in fairly good agreement with gas-phase chemical models for young molecular cloud cores, but the abundance of H2C4 is significantly larger than predicted.

NASA Discipline Exobiology↗

NASA NTRS1996

First Astronomical Detection of the Carbene Chain H2C6

The cumulene carbenes are important components of hydrocarbon chemistry in low mass star forming cores. Here we report the first astronomical detection of the long chain cumulene carbene H(sub 2)C(sub 6), in the insterstellar cloud TMC1, from observations of two of its rotational transitions:...

interstellar molecules star formation hydrocarbon ↗

NASA NTRS1987

The radio spectrum of cyclopropene

Twenty-eight millimeter-wave lines in the rotational spectrum of the three-membered hydrocarbon ring cyclopropene, C3H4, have been measured in the laboratory to high precision. When combined with previous measurements, these determine the rotational and centrifugal distortion constants of C3H4 sufficiently well to allow its entire radio spectrum to be calculated to an accuracy adequate for foreseeable astronomical applications, i.e., to an equivalent radial velocity of 0.1 km/s or better. With the recent discovery that the related ring C3H2 is widespread in the Galaxy, cyclopropene has become a plausible candidate for astronomical detection. Upper limits in Sgr B2 and TMC-1 indicate that in these sources C3H4 cannot be much more abundant than C3H2.

Vrtilek, J. M.↗

NASA NTRS1987

Laboratory and astronomical spectroscopy of C3H2, the first interstellar organic ring

The first laboratory and astronomical observations of the carbene ring molecule C3H2 briefly reported in a recent Letter are described in detail. In the laboratory, 22 millimeter-wave lines have been measured in a He and C2H2 discharge. From these the three rotational constants and the five fourth-order centrifugal distortion constants of C3H2 have been determined to high precision, allowing, in turn, calculation to 0.1 km/s of the most important lines in the radio and far-IR spectrum; 123 lines in the rotational spectrum with E/K less than 100 K are tabulated. Eleven astronomical transitions have been identified, and in Sgr B2 and Orion KL, rotational temperatures and column densities were derived and compared with those of other hydrocarbons with a similar number of C atoms.

Vrtilek, J. M.↗

NASA NTRS1986

Laboratory detection of the C5H radical

The new linear molecule reported by Cernicharo et al. (1986) has been found in the same laboratory discharge in which C3H is observed, establishing conclusively that the molecule is C5H in its 2Pi ground state. Six rotational transitions in the 2Pi(1/2) ladder and four in the 2Pi(3/2), each split by lambda doubling, were observed. The twenty millimeter-wave lines were simultaneously fit by a standard Hamiltonian with five free parameters: the fine-structure constant, the rotational constant, the centrifugal distortion constant, and two lambda-doubling constants.

Gottlieb, C. A.↗

NASA NTRS1986

The rotational spectrum of the C3H radical

The rotational spectrum of the recently discovered C3H radical in both fine-structure ladders of its electronic ground state (X2Pi) with lambda doubling and hyperfine structure has been determined to high accuracy, and the strongest transitions at frequencies less than 376 GHz are tabulated. Recently published spectroscopic constants derived from astronomical and laboratory data (Gottlieb et al., 1985) allowed calculation of the spectrum to a radial velocity of 0.4 km/s at frequencies less than 200 GHz, the uncertainties above being somewhat larger. The hyperfine constants of the sequence of four hydrocarbon radicals CH, C2H, C3H, and C4H are briefly described.

Gottlieb, C. A.↗

NASA NTRS1985

Laboratory and astronomical identification of cyclopropenylidene, C3H2

Twenty-seven rotational lines of C3H2 have been identified in the laboratory or in astronomical sources, and the rotational and centrifugal distortion constants of this previously unobserved carbene ring determined to high accuracy. The assigned astronomical transitions include the strong, ubiquitous interstellar lines at 85,338 MHz and 18,343 MHz, which are the lowest lying transitions of ortho C3H2:2(12) to 1(01) and 1(10) to 1(01), respectively. Interstellar C3H2 can be rapidly formed by dissociative recombination of the very stable ion C3H3(+), which in turn can be produced from acetylene in only two stars. In standard molecular sources such as Ori A and Sgr B2, C3H2 is only moderately abundant, but in diffuse molecular clouds it may be one of the most abundant molecules. There is some radio spectroscopic evidence for two related molecules in Sgr B2 or TMC-1: ethynylmethylene HCCCH, a hypothetical carbon chain isomer, and cyclopropene, C3H4, a known, stable three-membered ring.

Thaddeus, P.↗

NASA NTRS1985

Laboratory and astronomical detection of the deuterated ethynyl radical CCD

Two rotational transitions of CCD, N = 1-2 at 144 GHz and 2-3 at 216 GHz, were detected in a laboratory glow discharge through deuterated acetylene and helium, after which one, N = 2-1, was detected toward the rich molecular cloud behind the Orion Nebula. The 144 GHz transition is a well-resolved spin doublet split by 55 MHz, the components of which contain hyperfine structure of the order of 1 MHz, so far only partially resolved. From observations toward two positions in Orion, at and near the Kleinmann-Low nebula, the column density of CCD is determined to be 1.8 x 10 to the 13th/sq cm and the isotopic ratio CCD/CCH = 0.05. CCD was not detected at two positions in TMC-1.

Vrtilek, J. M.↗

NASA NTRS1985

Astronomical identification of the C3H radical

The C3H radical has been identified in the millimeter-wave spectra of IRC +10216 and TMC-1. In IRC +10216, four rotational transitions have been observed, three in the lower fine-structure ladder (2Pi1/2) and one in the upper (2Pi3/2), each a resolved or partially resolved lambda-doublet. In TMC-1, both lambda components of the lowest lying 3/2-1/2 transition of the 2Pi1/2 ladder have been observed, each with well-resolved hfs. In IRC +10216, the excitation of C3H is similar to that of SiCC: the rotational temperature Trot within the 2Pi1/2 ladder is low (8.5 K), because of rapid radiative decay, while Trot across the ladders is high (about 52 K), because interconnecting far-IR radiative transitions are only weakly permitted. The column density of C3H in IRC +10216 averaged over the estimated source diameter of 84 arcsec is 2.8 x 10 to the 13th/sq cm, an order of magnitude less than that of C2H and C4H.

Thaddeus, P.↗

NASA NTRS1985

Laboratory detection of the C3H radical

Millimeter-wave lines of the C3H radical, including six of the lines observed in space, were detected in a laboratory glow discharge through a flowing mixture of C2H2, He, and CO. Each of the 10 rotational transitions measured, five between 98 and 185 GHz in the 2Pi1/2 ladder and five between 80 and 194 GHz in the 2Pi3/2 ladder, is split by lambda-type doubling, and all but three possess resolved hyperfine structure. The excellent agreement between the fine-structure, rotation, lambda-doubling, and hyperfine constants derived from the laboratory data and from the astronomical observations conclusively confirms the identifications in IRC +10216 and TMC-1 by Thaddeus and colleagues (1985). An accurate set of spectroscopic constants, which allow calculation of the entire radio spectrum of C3H to a radial velocity of 0.1 km/s, was derived from a simulataneous fit to the laboratory frequencies and to the well-resolved hfs observed in the narrow-line astronomical source TMC-1.

Gottlieb, C. A.↗

NASA NTRS1983

Laboratory detection of the C3N an C4H free radicals

The millimeter-wave spectra of the linear carbon chain free radicals C3N and C4H, first identified in IRC + 10216 and hitherto observed only in a few astronomical sources, have been detected with a Zeeman-modulated spectrometer in laboratory glow discharges through low pressure flowing mixtures of N2 + HC3N and He + HCCH, respectively. Four successive rotational transitions between 168 and 198 GHz have been measured for C3N, and five rotational transitions between 143 and 200 GHz for C4H; each is a well-resolved spin doublet owing to the unpaired electron present in both species. Precise values for the rotational, centrifugal distortion, and spin doubling constants have been obtained, which, with hyperfine constants derived from observations of the lower rotational transitions in the astronomical source TMC 1, allow all the rotational transitions of C3N and C4H at frequencies less than 300 GHz to be calculated to an absolute accuracy exceeding 1 ppm.

Gottlieb, C. A.↗

NASA NTRS1983

Laboratory and astronomical measurement of the millimeter wave spectrum of the ethynyl radical CCH

The N = 0 yields 1 and 1 yields 2 rotational transitions of CCH at 87 and 174 GHz, respectively, have been detected in a laboratory glow discharge in a mixture of He and C2H2. The spectroscopic constants of CCH derived from measurements of the hfs of the transitions agree well with those derived from astronomical observations, confirming the astronomical detection of CCH. As the CCH lines in the Orion Nebula are narrower than the laboratory lines but less certain in rest frequency owing to uncertainty in the radial velocity, the most accurate values for the spectroscopic constants of CCH are obtained from a simultaneous fit of both the laboratory and astronomical data. For the rotation, centrifugal distortion, spin-rotation, and hyperfine constants, respectively, the values found are within 0.006 of 43674.534 MHz, within 0.0008 of 0.1071 MHz, within 0.004 of -62.606 MHz, b = within 0.019 MHz of 40.426, and c is within 0.026 of 12.254 MHz.

Gottlieb, C. A.↗

NASA NTRS1980

Molecular line observations of AFGL sources

HCN and (with three exceptions) CH emission lines have been detected from 14 molecular clouds associated with AFGL sources and/or Sharpless regions. Eleven are molecular cloud-H II region complexes. The remaining three appear to be similar (perhaps younger) objects; they are strong in the far infrared, but have no visible H II regions. Enhancement of the lower satellite transition of CH is seen in most cases. CH was also detected in association with the Herbig B8-A2e star V380 Ori. This emission was the most intense of all the CH detections. An effort was made to find a maser transition for a carbon-bearing molecule in late-type stars. A search was made for rotational transitions in the HCN bending mode (first overtone at 89.1 GHz) and stretching mode (fundamental at 88.0 GHz) as well as the CH ground state lambda-doublet in carbon stars.

Dinger, A. S. C.↗

NASA NTRS1977

Detection of interstellar ethyl cyanide

Twenty-four millimeter-wave emission lines of ethyl cyanide (CH3CH2CN) have been detected in the Orion Nebula (OMC-1) and seven in Sgr B2. To derive precise radial velocities from the astronomical data, a laboratory measurement of the rotational spectrum of ethyl cyanide has been made at frequencies above 41 GHz. In OMC-1, the rotational temperature of ethyl cyanide is 90 K (in good agreement with other molecules), the local-standard-of-rest radial velocity is 4.5 + or - 1.0 km/s (versus 8.5 km/s for most molecules), and the column density is 1.8 by 10 to the 14th power per sq cm (a surprisingly high figure for a complicated molecule). The high abundance of ethyl cyanide in the Orion Nebula suggests that ethane and perhaps larger saturated hydrocarbons may be common constituents of molecular clouds and have escaped detection only because they are nonpolar or only weakly polar.

Johnson, D. R.↗