Engineering topics

Gottlieb, E. W.

Publications and source records attributed to Gottlieb, E. W..

11 records

NASA NTRS1994

The Diurnal Variation of Hydrogen, Nitrogen, and Chlorine Radicals: Implications for the Heterogeneous Production of HNO2

In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained through sunrise and sunset in the lower stratosphere during SPADE are compared to results from a photochemical model constrained by observed concentrations of radical precursors and environmental conditions. Models allowing for heterogeneous hydrolysis of N205 on sulfate aerosols agree with measured concentrations of NO, NO2, and ClO throughout the day, but fail to account for high concentrations of OH and H02 observed near sunrise and sunset. The morning burst of [OH] and [HO2] coincides with the rise of [NO] from photolysis of N02, suggesting a new source of HO, that photolyzes in the near UV (350 to 400 nm) spectral region. A model that allows for the heterogeneous production of HN02 results in an excellent simulation of the diurnal variations of [OH] and [HO2].

Salawitch, R. J.↗

NASA NTRS1994

The Distribution of Hydrogen, Nitrogen, and Chlorine Radicals in the Lower Stratosphere: Implications for Changes in O3 due to Emission of NO(y) from Supersonic Aircraft

In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained in the lower stratosphere during the Stratospheric Photochemistry, Aerosols and Dynamics Expedition (SPADE) are compared to results from a photochemical model that assimilates measurements of radical precursors and environmental conditions. Models allowing for heterogeneous hydrolysis of N2O5 agree well with measured concentrations of NO and ClO, but concentrations of HO2 and OH are underestimated by 10 to 25%, concentrations of NO2 are overestimated by 10 to 30%, and concentrations of HCl are overestimated by a factor of 2. Discrepancies for [OH] and [HO2] are reduced if we allow for higher yields of O(sup 1)D) from 03 photolysis and for heterogeneous production of HNO2. The data suggest more efficient catalytic removal of O3 by hydrogen and halogen radicals relative to nitrogen oxide radicals than predicted by models using recommended rates and cross sections. Increases in [O3] in the lower stratosphere may be larger in response to inputs of NO(sub y) from supersonic aircraft than estimated by current assessment models.

Salawitch, R. J.↗

NASA NTRS1993

Chemical loss of ozone in the Arctic polar vortex in the winter of 1991- 1992

In situ measurements of chlorine monoxide, bromine monoxide, and ozone are extrapolated globally, with the use of meteorological tracers, to infer the loss rates for ozone in the Arctic lower stratosphere during the Airborne Arctic Stratospheric Expedition II (AASE II) in the winter of 1991-1992. The analysis indicates removal of 15 to 20 percent of ambient ozone because of elevated concentrations of chlorine monoxide and bromine monoxide. Observations during AASE II define rates of removal of chlorine monoxide attributable to reaction with nitrogen dioxide (produced by photolysis of nitric acid) and to production of hydrochloric acid. Ozone loss ceased in March as concentrations of chlorine monoxide declined. Ozone losses could approach 50 percent if regeneration of nitrogen dioxide were inhibited by irreversible removal of nitrogen oxides (denitrification), as presently observed in the Antarctic, or without denitrification if inorganic chlorine concentrations were to double.

Salawitch, R. J.↗

NASA NTRS1993

Chemical Loss of Ozone in the Arctic Polar Vortex in the Winter of 1991-1992

Salawitch, R. J.↗

NASA NTRS1986

Laboratory detection of the C5H radical

The new linear molecule reported by Cernicharo et al. (1986) has been found in the same laboratory discharge in which C3H is observed, establishing conclusively that the molecule is C5H in its 2Pi ground state. Six rotational transitions in the 2Pi(1/2) ladder and four in the 2Pi(3/2), each split by lambda doubling, were observed. The twenty millimeter-wave lines were simultaneously fit by a standard Hamiltonian with five free parameters: the fine-structure constant, the rotational constant, the centrifugal distortion constant, and two lambda-doubling constants.

Gottlieb, C. A.↗

NASA NTRS1986

The rotational spectrum of the C3H radical

The rotational spectrum of the recently discovered C3H radical in both fine-structure ladders of its electronic ground state (X2Pi) with lambda doubling and hyperfine structure has been determined to high accuracy, and the strongest transitions at frequencies less than 376 GHz are tabulated. Recently published spectroscopic constants derived from astronomical and laboratory data (Gottlieb et al., 1985) allowed calculation of the spectrum to a radial velocity of 0.4 km/s at frequencies less than 200 GHz, the uncertainties above being somewhat larger. The hyperfine constants of the sequence of four hydrocarbon radicals CH, C2H, C3H, and C4H are briefly described.

Gottlieb, C. A.↗

NASA NTRS1985

Laboratory detection of the C3H radical

Millimeter-wave lines of the C3H radical, including six of the lines observed in space, were detected in a laboratory glow discharge through a flowing mixture of C2H2, He, and CO. Each of the 10 rotational transitions measured, five between 98 and 185 GHz in the 2Pi1/2 ladder and five between 80 and 194 GHz in the 2Pi3/2 ladder, is split by lambda-type doubling, and all but three possess resolved hyperfine structure. The excellent agreement between the fine-structure, rotation, lambda-doubling, and hyperfine constants derived from the laboratory data and from the astronomical observations conclusively confirms the identifications in IRC +10216 and TMC-1 by Thaddeus and colleagues (1985). An accurate set of spectroscopic constants, which allow calculation of the entire radio spectrum of C3H to a radial velocity of 0.1 km/s, was derived from a simulataneous fit to the laboratory frequencies and to the well-resolved hfs observed in the narrow-line astronomical source TMC-1.

Gottlieb, C. A.↗

NASA NTRS1983

Laboratory detection of the C3N an C4H free radicals

The millimeter-wave spectra of the linear carbon chain free radicals C3N and C4H, first identified in IRC + 10216 and hitherto observed only in a few astronomical sources, have been detected with a Zeeman-modulated spectrometer in laboratory glow discharges through low pressure flowing mixtures of N2 + HC3N and He + HCCH, respectively. Four successive rotational transitions between 168 and 198 GHz have been measured for C3N, and five rotational transitions between 143 and 200 GHz for C4H; each is a well-resolved spin doublet owing to the unpaired electron present in both species. Precise values for the rotational, centrifugal distortion, and spin doubling constants have been obtained, which, with hyperfine constants derived from observations of the lower rotational transitions in the astronomical source TMC 1, allow all the rotational transitions of C3N and C4H at frequencies less than 300 GHz to be calculated to an absolute accuracy exceeding 1 ppm.

Gottlieb, C. A.↗

NASA NTRS1983

Laboratory and astronomical measurement of the millimeter wave spectrum of the ethynyl radical CCH

The N = 0 yields 1 and 1 yields 2 rotational transitions of CCH at 87 and 174 GHz, respectively, have been detected in a laboratory glow discharge in a mixture of He and C2H2. The spectroscopic constants of CCH derived from measurements of the hfs of the transitions agree well with those derived from astronomical observations, confirming the astronomical detection of CCH. As the CCH lines in the Orion Nebula are narrower than the laboratory lines but less certain in rest frequency owing to uncertainty in the radial velocity, the most accurate values for the spectroscopic constants of CCH are obtained from a simultaneous fit of both the laboratory and astronomical data. For the rotation, centrifugal distortion, spin-rotation, and hyperfine constants, respectively, the values found are within 0.006 of 43674.534 MHz, within 0.0008 of 0.1071 MHz, within 0.004 of -62.606 MHz, b = within 0.019 MHz of 40.426, and c is within 0.026 of 12.254 MHz.

Gottlieb, C. A.↗

NASA NTRS1980

Molecular line observations of AFGL sources

HCN and (with three exceptions) CH emission lines have been detected from 14 molecular clouds associated with AFGL sources and/or Sharpless regions. Eleven are molecular cloud-H II region complexes. The remaining three appear to be similar (perhaps younger) objects; they are strong in the far infrared, but have no visible H II regions. Enhancement of the lower satellite transition of CH is seen in most cases. CH was also detected in association with the Herbig B8-A2e star V380 Ori. This emission was the most intense of all the CH detections. An effort was made to find a maser transition for a carbon-bearing molecule in late-type stars. A search was made for rotational transitions in the HCN bending mode (first overtone at 89.1 GHz) and stretching mode (fundamental at 88.0 GHz) as well as the CH ground state lambda-doublet in carbon stars.

Dinger, A. S. C.↗

NASA NTRS1977

Detection of interstellar ethyl cyanide

Twenty-four millimeter-wave emission lines of ethyl cyanide (CH3CH2CN) have been detected in the Orion Nebula (OMC-1) and seven in Sgr B2. To derive precise radial velocities from the astronomical data, a laboratory measurement of the rotational spectrum of ethyl cyanide has been made at frequencies above 41 GHz. In OMC-1, the rotational temperature of ethyl cyanide is 90 K (in good agreement with other molecules), the local-standard-of-rest radial velocity is 4.5 + or - 1.0 km/s (versus 8.5 km/s for most molecules), and the column density is 1.8 by 10 to the 14th power per sq cm (a surprisingly high figure for a complicated molecule). The high abundance of ethyl cyanide in the Orion Nebula suggests that ethane and perhaps larger saturated hydrocarbons may be common constituents of molecular clouds and have escaped detection only because they are nonpolar or only weakly polar.

Johnson, D. R.↗