Automatic identification of chemical spectra - A goodness of fit measure derived from hypothesis testing
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Engineering topics
Publications and source records attributed to Grotch, S. L..
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In file-search techniques, the distribution of mismatches quantitatively measures the fit of a particular unknown against a given library. A simple theoretical method is developed to predict, a priori, this distribution. With this procedure, for any unknown code and library, the mean number of mismatches can be calculated exactly. For a given library and coding scheme, the mismatch distribution for most unknown codes closely follows a common curve which is easily calculated from statistical properties of the library. When this common curve is normalized to a constant mean, the observed matching behavior is well predicted. The theory should permit the user to more clearly assess the effects of errors on file search performance and suggest techniques by which recognition performance may be optimized.
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Computer program is developed to interpret spectral data in order to assist chemist in identifying low resolution mass spectra. Two versions of program, using approximately same amount of core are available. In both programs, core requirements are roughly proportional to maximum number of unknowns to be handled on each pass through tape.
Surveyor 5, 6, 7 missions alpha-scattering experiments, lunar rocks chemical composition compared with earth rocks and chondritic meteorites
Computer analyses of alpha scattering spectra from lunar site Surveyor probes
Data handling system to monitor detection of alpha particles energy scattered from top lunar surface layer