Feedback Loop in Lightning Initiation Through Ice and Nitrogen Oxides
No abstract available
Peterson, Harold↗
Engineering topics
Hallett, John
Publications and source records attributed to Hallett, John.
Ice Particle Growth Under Conditions of the Upper Troposphere
Atmospheric conditions for growth of ice crystals (temperature and ice supersaturation) are often not well constrained and it is necessary to simulate such conditions in the laboratory to investigate such growth under well controlled conditions over many hours. The growth of ice crystals from the vapour in both prism and basal planes was observed at temperatures of -60 C and -70 C under ice supersaturation up to 100% (200% relative humidity) at pressures derived from the standard atmosphere in a static diffusion chamber. Crystals grew outward from a vertical glass filament, thickening in the basal plane by addition of macroscopic layers greater than 2 microns, leading to growth in the prism plane by passing of successive layers conveniently viewed by time lapse video.
Peterson, Harold S.↗
Ice Crystal Growth Rates Under Upper Troposphere Conditions
Atmospheric conditions for growth of ice crystals (temperature and ice supersaturation) are often not well constrained and it is necessary to simulate such conditions in the laboratory to investigate such growth under well controlled conditions over many hours. The growth of ice crystals from the vapour in both prism and basal planes was observed at temperatures of -60 C and -70 C under ice supersaturation up to 100% (200% relative humidity) at pressures derived from the standard atmosphere in a static diffusion chamber. Crystals grew outward from a vertical glass filament, thickening in the basal plane by addition of macroscopic layers greater than 2 m, leading to growth in the prism plane by passing of successive layers conveniently viewed by time lapse video.
Peterson, Harold S.↗
Ice Particle Growth Rates Under Upper Troposphere Conditions
Atmospheric conditions for growth of ice crystals (temperature and ice supersaturation) are often not well constrained and it is necessary to simulate such conditions in the laboratory to investigate such growth under well controlled conditions over many hours. The growth of ice crystals from the vapour in both prism and basal planes was observed at temperatures of -60 C and -70 C under ice supersaturation up to 100% (200% relative humidity) at pressures derived from the standard atmosphere in a static diffusion chamber. Crystals grew outward from a vertical glass filament, thickening in the basal plane by addition of macroscopic layers greater than 2 m, leading to growth in the prism plane by passing of successive layers conveniently viewed by time lapse video.
Peterson, Harold↗
Microphysics and Radiative Properties of Cirrus: Instrumentation and Analysis
Work under this grant has involved further development of a new aircraft instrument (the cloudscope) for real time characterization of atmospheric particulates together with field observations of such particulates, both in the form of ice and also as nuclei responsible for nucleation of both ice and water cloud particles. Part of the work involving assessment of the frequency of ice crystal shapes has been carried out in collaboration with the Meteorological Service of Canada; part of the work in a field program with the NCAR C-130. Part of the work has been interpreted in terms of laboratory simulation of ice crystal growth under a wide variety of conditions carried out under a grant from Physical Meteorology Program, National Science Foundation.
Hallett, John↗
Microphysics and Radiative Properties of Cirrus: Instrumentation and Analysis
This section summarizes the scientific questions which originated with participation in FIRE II in Coffeyville KA, evolved through participation in several field projects related to FIRE and culminated in participation in FIRE III in the Arctic in March / May 1998. It is noted that many of the ideas generated in FIRE II 1992 - 1995 and published under the grant involving the role of CCN in cirrus formation have been followed through in this grant and have also been central in the ideas for work under the SUCCESS project and the laboratory work currently supported by NSF.
Arnott, W. P.↗
Characterization of Aircraft Produced Soot and Contrails Near the Tropopause
Participation in the SUCCESS project primarily involved development and deployment of specific instruments for characterizing jet aircraft exhaust emissions as particulates and their subsequent evolution as contrail particles, either liquid or solid, as cirrus. Observations can be conveniently considered in two categories - close or distant from the aircraft. Thus close to the aircraft the exhaust is mixing through the engine turbulence with a much drier and colder environment and developing water/ ice supersaturation along the trail depending on circumstances (near field), whereas distant from the aircraft (far field) the exhaust has cooled essentially to ambient temperature, the turbulence has decayed and any particle growth or evaporation is controlled by the prevailing ambient conditions. Intermediate between these two regions the main aircraft vortices form (one on each side of the aircraft) which tend to inhibit mixing under some conditions, a region extending from a few aircraft lengths to sometimes a hundred times this distance. Our approach to the problem lay in experience gained in characterizing the smoke from hydrocarbon combustion in terms of its cloud forming properties and its potential influence on the radiation properties of the smoke and subsequent cloud from the viewpoint of reduction (absorbtion and scattering ) of solar radiation flux leading to significant global cooling (Hudson et al 1991; Hallett and Hudson 1991). Engine exhaust contains a much smaller proportion of the fuel carbon than is sometimes present in ordinary combustion (less than 0.01% compared with 10%) and influences condensation in quite different ways, to be characterized by the Cloud Condensation Nucleus, CCN - supersaturation spectrum. The transition to ice is to be related to the dilution of solution droplets to freeze by homogeneous nucleation at temperatures somewhat below -40C (Pueschel et al 1998). The subsequent growth of ice particles depends critically on temperature, supersaturation and to some extent pressure, as is demonstrated in an NSF funded project being carried out in parallel with the work reported here. As will be discussed below, nucleation processes themselves and also exhaust impurities also influence the growth of ice particles and may control some aspects of growth of ice in contrails. Instrumentation was designed to give insight into these questions and to be flown on the NASA DC- 8 as a platform. In addition a modest program was undertaken to investigate the properties of laboratory produced smoke produced under controlled conditions from the viewpoint of forming both CCN and CN. The composition of the smoke could inferred from a thermal characterization technique; larger particles were captured by formvar replicator for detailed analysis; ice particles were captured and evaporated in flight on a new instrument, the cloudscope, to give their mass, density and impurity content.
Hallett, John↗
The 5-6 December 1991 FIRE IFO 2 Jet Stream Cirrus Case Study: Possible Influences of Volcanic Aerosols
In presenting an overview of the cirrus clouds comprehensively studied by ground based and airborne sensors from Coffeyville, Kansas, during the 5-6 December 1992 First ISCCP Regional Experiment (FIRE) intensive field observation (IFO) case study period, evidence is provided that volcanic aerosols from the June 1991 Pinatubo eruptions may have significantly influenced the formation and maintenance of the cirrus. Following the local appearance of a spur of stratospheric volcanic debris from the subtropics, a series of jet streaks subsequently conditioned the troposphere through tropopause foldings with sulfur based particles that became effective cloud forming nuclei in cirrus clouds. Aerosol and ozone measurements suggest a complicated history of stratospheric-tropospheric exchanges embedded with the upper level flow, and cirrus cloud formation was noted to occur locally at the boundaries of stratospheric aerosol enriched layers that became humidified through diffusion, precipitation, or advective processes. Apparent cirrus cloud alterations include abnormally high ice crystal concentrations (up to approximately 600 L(exp. 1)), complex radial ice crystal types, and relatively large haze particles in cirrus uncinus cell heads at temperatures between -40 and -50 degrees C. Implications for volcanic-cirrus cloud climate effects and unusual (nonvolcanic) aerosol jet stream cirrus cloud formation are discussed.
Sassen, Kenneth↗
Part A: Cirrus ice crystal nucleation and growth. Part B: Automated analysis of aircraft ice particle data
Specific measurement of cirrus crystals by aircraft and temperature modified CN are used to specify measurements necessary to provide a basis for a conceptual model of cirrus particle formation. Key to this is the ability to measure the complete spectrum of particles at cirrus levels. The most difficult regions for such measurement is from a few to 100 microns, and uses a replicator. The details of the system to automate replicator data analysis are given, together with an example case study of the system provided from a cirrus cloud in FIRE 2, with particles detectable by replicator and FSSP, but not 2DC.
Arnott, William P.↗
Replicator for characterization of cirrus and polar stratospheric cloud particles
A formvar replicator for installation in an aircraft pod has been designed, built, and flight tested on the NASA DC-8. The system incorporates a deicing capability (which can be pressure activated) to enable climb out through icing situations prior to deployment. The system can be operated at preselected speeds such that data can be recorded over a period of one to ten hours on 200 ft of 16mm film. A x2 speed control can be used during flight. Capability exists for detection of chemical constituents by appropriate doping of the formvar solution. An article entitled 'Measurements of ice particles in tropical cirrus anvils: importance in radiation balance' is attached as appendix A.
Hallett, John↗
Nucleation and growth of crystals under cirrus and polar stratospheric cloud conditions
Laboratory studies examine phase changes of hygroscopic substances which occur as aerosol in stratosphere and troposphere (sodium chloride, ammonium sulfate, ammonium bisulfate, nitric acid, sulfuric acid), under controlled conditions, in samples volume 1 to 10(exp -4) ml. Crystallization of salts from supersaturated solutions is examined by slowly evaporating a solution drop on a substrate, under controlled relative humidity, until self nucleation occurs; controlled nucleation of ice in a mm capillary U-tube gives a measured ice crystallization velocity at known supercooling. Two states of crystallization occur for regions where hydrates exist. It is inferred that all of the materials readily exist as supersaturated/supercooled solutions; the degree of metastability appears to be slightly enhanced by inclusion of aircraft produced soot. The crystallization velocity is taken as a measure of viscosity. Results suggest an approach to a glass transition at high molality, supersaturation and/or supercooling within the range of atmospheric interest. It is hypothesized that surface reactions occur more readily on solidified particles - either crystalline or glass, whereas volume reactions are more important on droplets with sufficiently low viscosity and volume diffusivity. Implications are examined for optical properties of such particles in the atmosphere. In a separate experiment, crystal growth was examined in a modified thermal vapor diffusion chamber over the range of cirrus temperature (-30 to -70 C) and under controlled supersaturation and air pressure. The crystals grew at a velocity of 1-2 microns/s, thickness 60-70 micron, in the form of thin column crystals. Design criteria are given for a system to investigate particle growth down to -100 C, (PSC temperatures) where nitric acid particles can be grown under similar control and in the form of hydrate crystals.
Hallett, John↗
Replicator for characterization of cirrus and polar stratospheric cloud particles
A formvar replicator for installation in an aircraft pod has been designed, built, and flight tested on the NASA DC-8. The system incorporates a deicing capability (which can be pressure activated) to enable climb out through icing situations prior to deployment. The system can be operated at preselected speeds such that data can be recorded over a period of 1 to ten hours on 200 ft of 16mm film. A x2 speed control can be used during flight. Capability exists for detection of chemical constituents by appropriate doping of formvar solution.
Hallett, John↗
The 5-6 December 1991 FIRE IFO II jet stream cirrus case study: Possible influences of Volcanic Aerosols
In presenting an overview of the cirus clouds comprehensively studied by ground-based and airborne sensors from Coffeyville, Kansas, during the 5-6 December 1992 Project First ISCCP Region Experiment (FIRE) Intensive Fields Observation (IFO) II case study period, evidence is provided that volcanic aerosols friom the June 1991 Pinatubo eruptions may have significantly influenced the formation and maintenance of the cirrus. Following the local appearance of a spur of stratospheric volcanic debris from the subtropics, a series of jet streaks subsequently conditioned the troposphere through tropopause foldings with sulfur-based particles that became effective cloud-forming nuclei in cirrus clouds. Aerosol and ozone measurements suggest a complicated history of stratospheric-tropospheric exchanges embedded within the upper-level flow, and cirrus cloud formation was noted to occur locally at the boundaries of stratospheric aerosol-enriched layers that became humidified through diffusion, precipitation, or advective processes. Apparent cirrus cloud alterations include abnormally high ice crystal concentrations (up to approximately 600/L), complex radial ice crystal types, and relatively large haze particles in cirrus uncinus cell heads at temperatures between -40 and -50 C. Implications for volcanic-cirrus cloud climate effects and usual (nonvolcanic aerosol) jet stream cirrus cloud formation are discussed.
Sassen, Kenneth↗
Role of small ice crystals in radiative properties of cirrus: A case study, FIRE II, November 22, 1991
Aircraft observations of cirrus cloud were made near Coffeyville, Kansas, during November 1991 as part of the First ISCCP Regional Experiment II (FIRE II) project. Cloud ice particle spectra measurements were made using both a particle measuring system (PMS) 2DC probe and an ice particle replicator. Particles larger than 200 micrometers were column rosettes. The replicator shows the presence of large numbers of ice crystals smaller than 66 micrometers (two PMS size bins) that are not recorded by the PMS 2DC probe. Calculations based on the replicator data of the geometrical blocked area and absorption cross section of the cloud per unit volume show that small particles can contribute significantly to and sometimes dominate both the solar extinction and the infrared emission. Intercomparison is made of the ice particle size, area, and mass distributions determined by these different instruments. Power law relationships for area occluded by a crystal as a function of crystal maximum dimension were computed from the PMS 2DC data. The wavelength-dependent infrared absorption cross section per volume was computed using a simple model based on anomalous diffraction and area and mass dimensional relationships for the ice crystals.
Arnott, W. Patrick↗
Measurements of Ice Particles in Tropical Cirrus Anvils: Importance in Radiation Balance
Cirrus is important in the radiation balance of the global atmosphere, both at solar and thermal infrared (IR) wavelengths. In particular cirrus produced by deep convection over the oceans in the tropics may be critical in controlling processes whereby energy from warm tropical oceans is injected to different levels in the tropical atmosphere to subsequently influence not only tropical but mid latitude climate. Details of the cloud composition may differentiate between a net cooling or warming at these levels. The cloud composition may change depending on the input of nuclei from volcanic or other sources. Observations of cirrus during the FIRE-2 Project over Coffeyville, Kansas and by satellite demonstrate that cirrus, on occasion, is composed not only of larger particles with significant fall velocity (few hundred micrometers, 0.5 m/s) but much more numerous small particles, size 10-20 micrometers, with small fall velocity (cm/s), which may sometimes dominate the radiation field. This is consistent with emissivity measurements. In the thermal IR, ice absorption is strong, so that ice particles only 10 micrometers thick are opaque, at some wavelengths; on the other hand at other wavelengths and in the visible, ice is only moderately to weakly absorbing. It follows that for strongly absorbing wavelengths the average projected area of the ice particles is the important parameter, in weakly absorbing regions it is the volume (mass) of ice which is important. The shape of particles and also their internal structure may also have significant effect on their radiative properties. In order to access the role of cirrus in the radiation budget it is necessary to measure the distribution of ice particles sizes, shapes and concentrations in the regions of interest. A casual observation of any cirrus cloud shows that there is variability down to a scale of at least a few 100 m; this is confirmed by radar and lidar remote sensing. Thus aircraft measurements designed to give insight into the spatial distribution of radiation properties of ice crystals must be capable of examination of concentration, size and shape over a distance ideally of 100 m or less and to detect particles down to a size below which radiative effects are no longer significant.
Foster, Theodore↗
The 5-6 December 1991 FIRE IFO 2 jet stream cirrus case study: The influence of volcanic aerosols
In presenting an overview of the cirrus clouds comprehensively studied by ground-based and airborne sensors from Coffeyville, KS, during the 5-6 Dec. 1992 Project FIRE (First International Satellite Cloud Climatology Project Regional Experiment) IFO II case study period, evidence is provided that volcanic aerosols from the June 1991 Pinatubo eruptions significantly influenced the formation and maintenance of the cirrus. Following the local appearance of a spur of stratospheric volcanic debris from the subtropics, a series of jet streaks subsequently conditioned the troposphere through tropopause foldings with sulfur-based particles that became effective cirrus cloud-forming nuclei. Aerosol and ozone measurements suggest a complicated history of stratospheric-tropospheric exchanges embedded within the upper level flow, and cirrus cloud formation was noted to occur locally at the boundaries of stratospheric aerosol-enriched layers that became humidified through diffusion, precipitation, or advective processes. Apparent cirrus cloud alterations include abnormally high ice crystal concentrations (up to approximately 600 l(sup -1), small but complex radial ice crystal types, and relatively large haze particles in cirrus uncinus cell heads at temperatures between -40 to -50 C. Implications for volcanic-cirrus cloud climate effects, and usual (non-volcanic aerosol) jet stream cirrus cloud formation are discussed.
Sassen, Kenneth↗
Importance of aggregation and small ice crystals in cirrus clouds, based on observations and an ice particle growth model
The 1 November 1986 FIRE I case study was used to test an ice particle growth model which predicts bimodal size spectra in cirrus clouds. The model was developed from an analytically based model which predicts the height evolution of monomodal ice particle size spectra from the measured ice water content (IWC). Size spectra from the monomodal model are represented by a gamma distribution, N(D) = N(sub o)D(exp nu)exp(-lambda D), where D = ice particle maximum dimension. The slope parameter, lambda, and the parameter N(sub o) are predicted from the IWC through the growth processes of vapor diffusion and aggregation. The model formulation is analytical, computationally efficient, and well suited for incorporation into larger models. The monomodal model has been validated against two other cirrus cloud case studies. From the monomodal size spectra, the size distributions which determine concentrations of ice particles less than about 150 mu m are predicted.
Mitchell, David L.↗
Are tropical cirrus brighter than mid-latitude cirrus?
Recent measurements during FIRE II, in the tropics and elsewhere, support an emerging hypothesis about the role of stratospheric mixing in determining the microphysical and radiative properties of cirrus clouds. This is only a working hypothesis, and may change as new measurements become available. This report reviews the conditions under which certain types of ice crystals form.
Mitchell, David L.↗