Can interstellar H2S be formed via gas-phase reactions? - Calculations concerning the rates of the ternary and radiative association reactions between HS(+) and H2
Explore the source record for details and available documents.
Herbst, Eric↗
Engineering topics
Herbst, Eric
Publications and source records attributed to Herbst, Eric.
The laboratory millimeter- and submillimeter-wave spectrum of the first two excited torsional states of (C-13)H3OH
The rotational-torsional spectrum of (C-13)H3OH is presented in both the symmetric and degenerate substates of the first two excited torsional states. Of the new transitions reported, 122 lines are from the v(t) = 1 torsional state and 110 lines are from the v(t) = 2 torsional state, and all are confined to the rotational quantum number J = 8 or less. The data are combined with previously reported millimeter and submillimeter data for the v(t) = 0 torsional state and 44 previously measured excited torsional state lines to form a global data set of 596 transitions, which is analyzed and fitted using an extended internal axis method. The fit results in an overall rms deviation of 1.98 MHz. The spectral constants generated by the fit are used to predict an additional 123 lines of (C-13)H3OH in the v(t) = 1,2 excited torsional states with frequencies up to 612 GHz and rotational quantum number J = 11 or less.
Anderson, Todd↗
Identification of interstellar methanol lines
The extended internal axis method Hamiltonian of Herbst et al. (1984) was used to study the rotational spectrum of methanol out to high values of the rotational quantum number J. Laboratory data for 783 lines of (C-12)H3OH from the lowest three torsional levels out to a rotational quantum number of J = 22 were fitted to an rms deviation of 4.40 MHz. For (C-13)H3OH, 455 lines out to J = 22 were fitted to an rms of 2.28 MHz.
Sutton, E. C.↗
The laboratory millimeter- and submillimeter-wave spectrum of CH3OD
The millimeter-wave and submillimeter-wave spectrum of CH3OD, a deuterated isotope of methanol known to be present in the interstellar medium, has been studied in the laboratory. Like all isotopes of methanol, CH3OD possesses a complex dense spectrum because of the phenomenon of internal rotation, sometimes referred to as torsional motion. Approximately 300 lines in the frequency range 130-700 GHz have been assigned. These lines involve transitions between rotational states with rotational quantum number J of not greater than 9 in both the A and the E substates of the lowest torsional state (v sub t = 0). The present data and previous data at lower frequencies (longer wavelengths) have been combined and analyzed by a procedure called the 'internal axis method'. The analysis yields spectral constants for CH3OD which, in turn, have been used to predict the frequencies of a number of other transitions of this species not measured in the laboratory.
Anderson, Todd↗
A detailed investigation of proposed gas-phase syntheses of ammonia in dense interstellar clouds
The initial reactions of the Herbst and Klemperer (1973) and the Dalgarno (1974) schemes (I and II, respectively) for the gas-phase synthesis of ammonia in dense interstellar clouds were investigated. The rate of the slightly endothermic reaction between N(+) and H2 to yield NH(+) and H (scheme I) under interstellar conditions was reinvestigated under thermal and nonthermal conditions based on laboratory data. It was found that the relative importance of this reaction in synthesizing ammonia is determined by how the laboratory data at low temperature are interpreted. On the other hand, the exothermic reaction between N and H3(+) to form NH2(+) + H (scheme II) was calculated to possess significant activation energy and, therefore, to have a negligible rate coefficient under interstellar conditions. Consequently, this reaction cannot take place appreciably in interstellar clouds.
Herbst, Eric↗
The laboratory millimeter- and submillimeter-wave spectrum of C-13 methanol
A comprehensive millimeter- and submillimeter-wave study of the rotational spectrum of (C-13)H3OH is presented. Approximately 300 new transitions of this species were measured at frequencies up to 650 GHz, and the transitions were analyzed along with previously measured spectra using the internal axis method of Herbst et al. (1984). The resulting spectral constants allow prediction of an additional large number of transitions which should allow astronomers to identify many strong rotational lines of C-13 methanol throughout much of the submillimeter region.
Anderson, Todd↗
C-type transitions in methyl formate
Based on previously determined spectral constants for methyl formate in its ground torsional degenerate substate, the frequencies and intensities of forbidden c-type transitions in this molecule, which is represented by a large number of lines in OMC-1, are calculated along with other 'forbidden' transitions labeled x-type. The stronger c-type transitions below 300 GHz with angular momentum quantum number of 30 or less and with upper state rotational energy of 350/cm or less are included in a list of spectral frequencies presented in this paper. Because the c-type transitions borrow intensity from the b-type transitions, the intensities of strongly affected b-type spectra are recalculated and presented.
Plummer, Grant M.↗
Ion-molecule calculation of the abundance ratio of CCD to CCH in dense interstellar clouds
Laboratory measurements and calculations have been performed to determine the abundance ratio of the deuterated ethynyl radical (CCD) to the normal radical (CCH) which can be achieved in dense interstellar clouds via isotopic fractionation in the C2H2(+) (HD)=C2HD(+)(H2) system of reactions. According to this limited treatment, the CCD/CCH abundance ratio which can be attained is in the range 0.02-0.03 for the Orion molecular cloud and 0.0l-0.02 for TMC-1. These ranges of numbers are in reasonable agreement with the observed values in Orion and TMC-1. However, the analysis of the CCD/CCH abundance ratio is complicated via the presence of competing fractionation mechanisms, especially in the low-temperature source TMC-1.
Herbst, Eric↗