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Hill, Gerald F.

Publications and source records attributed to Hill, Gerald F..

Carbon monoxide and methane in the North American Arctic and Subarctic troposphere - July-August 1988

Enhanced concentrations of CH4 in the unpolluted atmospheric mixed layer over both Arctic and subarctic tundra landscapes are documented here using data from the NASA Arctic Boundary Layer Expedition (ABLE 3A). The CH4 concentration gradients were determined mainly by interactions of biogenic emission from wet tundra and turbulent mixing proceses. The gradient were most frequently associated with intrusion of upper tropospheric or stratospheric air into the midtroposphere, emissions from forest and tundra fires, and long-range transport of enhanced concentration of these gases from unidentified sources. Summertime haze layers exhibited midtropospheric enhancements of CH4 similar to those measured in winter Arctic events. The observations confirm the importance of Arctic and Subarctic wetland environments as a regional source of global atmospheric CH4.

Harriss, Robert C.↗

Airborne flux measurements of trace species in an Arctic boundary layer

In situ airborne flux values for O3, CO, an CH4 over selected wetlands of Alaska are reported, and airborne CH4 flux measurements are presented for the first time. The source/sink distribution over the Yukon-Kuskokwim Delta (YKD) is qualitatively correlated with surface vegetation type. The CH4 source strength over the YKD ranged from 25 to 85 mg/sq m/d. A spatially averaged, seasonally adjusted source strength of 51 mg/sq m/d was established for the YKD. Indirect CH4 flux estimates obtained over the Alaskan North Slope indicate a much lower source strength. The global CH4 emission from tundra are estimated to be 44 Tg/a at an upper limit. Airborne CO flux measurements over the YKD indicate low negative flux values over the coastal areas, while some positive fluxes were observed in the inland sparsely forested regions. An inspection of the cospectrum of CO with vertical velocity for sample runs in coastal areas indicate the possibility of in situ photochemical destruction/production of CO.

Ritter, John A.↗

Venturi air-jet vacuum ejectors for high-volume atmospheric sampling on aircraft platforms

Documentation of the installation and use of venturi air-jet vacuum ejectors for high-volume atmospheric sampling on aircraft platforms is presented. Information on the types of venturis that are useful for meeting the pumping requirements of atmospheric-sampling experiments is also presented. A description of the configuration and installation of the venturi system vacuum line is included with details on the modifications that were made to adapt a venturi to the NASA Electra aircraft at GSFC, Wallops Flight Facility. Flight test results are given for several venturis with emphasis on applications to the Differential Absorption Carbon Monoxide Measurement (DACOM) system at LaRC. This is a source document for atmospheric scientists interested in using the venturi systems installed on the NASA Electra or adapting the technology to other aircraft.

Hill, Gerald F.↗

Venturi Air-Jet Vacuum Ejector For Sampling Air

Venturi air-jet vacuum ejector pump light in weight, requires no electrical power, does not contribute heat to aircraft, and provides high pumping speeds at moderate suctions. High-pressure motive gas required for this type of pump bled from compressor of aircraft engine with negligible effect on performance of engine. Used as source of vacuum for differential-absorption CO-measurement (DACOM), modified to achieve in situ measurements of CO at frequency response of 10 Hz. Provides improvement in spatial resolution and potentially leads to capability to measure turbulent flux of CO by use of eddy-correlation technique.

Hill, Gerald F.↗

Airborne flux measurements and budget estimates of trace species over the Amazon Basin during the GTE/ABLE 2B expedition

In situ airborne measurements of turbulent heat, moisture, momentum, ozone, and carbon monoxide fluxes in a convective boundary layer were obtained over a tropical rain forest between 1100 and 1630 LT on May 4, 1987. The aircraft flight path was chosen so as to fly over the tower site at the Ducke Forest Reserve near Manaus, Amazonas, Brazil. Both turbulence statistics and mean quantities were used to study the budgets of heat, water vapor, ozone, and carbon monoxide. The ozone budget study shows an accumulation rate in the boundary layer of 0.3 + or - 0.2 ppbv/h. The surface resistance to ozone during this flight was determined to be 0.06 + or - 0.03 s/cm, while the aerodynamic resistance was 0.14-0.17 s/cm. Results from the CO budget analysis show a midday accumulation rate of 0.6 + or - 0.3 ppbv/h in the Amazonian boundary layer. The evidence suggests production of CO in the PBL. A source of CO may exist below the lowest flight level (about 150 m), although it was not possible to determine what part of the flux at flight level was due to chemical production and what part may be due to surface emission.

Ritter, John A.↗

Operational overview of NASA GTE/CITE 1 airborne instrument intercomparisons - Carbon monoxide, nitric oxide, and hydroxyl instrumentation

An overview of the airborne intercomparisons of CO, NO, and OH instrumentation is presented in this first paper of the series on the NASA Global Tropospheric Experiment/Chemical Instrumentation Test and Evaluation (GTE/CITE 1). This paper provides the reader with background information about several important characteristics of the project. These include the overall objectives and approach, the measurements taken, the intercomparison protocol, aircraft platform, profiles of each aircraft flight, and the participants. A synopsis of the overall results of the CO, NO, and OH instrument intercomparisons is also included. Companion papers discuss the detailed results of the CO and NO intercomparison tests as well as pertinent scientific findings.

Beck, Sherwin M.↗

Airborne intercomparisons of carbon monoxide measurement techniques

Results from an airborne intercomparison of techniques to measure tropospheric levels of carbon monoxide (CO) are discussed. The intercomparison was conducted as part of the National Aeronautics and Space Administration's Global Tropospheric Experiment and included a laser differential absorption method and two grab sample/gas chromatograph methods. Measurements were obtained during approximately 90 flight hours, during which the CO mixing ratios ranged from about 60 to 140 ppbv. The level of agreement observed for the ensemble of measurements was well within the overall accuracy stated for each instrument. The correlation observed between the measurements from the respective pairs of instruments ranged from 0.85 to 0.98, with no evidence for the presence of either a constant or proportional bias between any of the instruments.

Hoell, James M., Jr.↗

Fast-response, high-precision carbon monoxide sensor using a tunable diode laser absorption technique

A tunable diode laser instrument, denoted as DACOM (Differential Absorption CO Measurement), has been developed to meet the fast-response, high-precision CO measurement needs of the GTE (Global Tropospheric Experiment) program. Under the GTE program, DACOM participated in the three field missions of CITE 1 (Chemical Instrumentation Test and Evaluation 1), a project involving the intercomparison of trace gas measurement techniques. DACOM performance, including analyses of measurement error sources, is discussed for the ground-based mission at Wallops Island, VA (summer 1983), and two missions on the NASA CV-990 (fall 1983 and spring 1984). Examples of fast-response (about 1 s), high-precision (+ or - 1 part per billion by volume, + or - 1.5 percent of reading) airborne data are included to illustrate the capability of this instrument.

Sachse, Glen W.↗

Vertical profiles of ozone, carbon monoxide, and dew-point temperature obtained during GTE/CITE 1, October-November 1983

A set of 14 pairs of vertical profiles of ozone and carbon monoxide, obtained with fast-response instrumentation, is presented. Most of these profiles, which were measured in the remote troposphere, also have supporting fast-response dew-point temperature profiles. The data suggest that the continental boundary layer is a source of tropospheric ozone, even in October and November, when photochemical activity should be rather small. In general, the small-scale vertical variability between CO and O3 is in phase. At low latitudes this relationship defines levels in the atmosphere where midlatitude air is being transported to lower latitudes, since lower dew-point temperatures accompany these higher CO and O3 concentrations. A set of profiles which is suggestive of interhemispheric transport is also presented. Independent meteorological analyses support these interpretations.

Fishman, Jack↗

Carbon monoxide measurements over the eastern Pacific during GTE/CITE 1

As part of the Global Tropospheric Experiment's Chemical Instrumentation Test and Evaluation (GTE/CITE 1) intercomparison, carbon monoxide (CO) measurements were made from the NASA CV-990 aircraft during the fall of 1983 and again in the spring of 1984. The experimental measurements for CO obtained during those flight series over the eastern and mid-Pacific are presented here. Data were acquired from 10 to 20 deg N latitude over the mid-Pacific and from 30 to 37 deg N latitude over the eastern Pacific off the coast of California. A seasonal variation of approximately 34 parts per billion by volume was measured over the altitudes and latitudes sampled, and a small latitudinal variation was also noted. The data are discussed in terms of the meteorological context in which they were collected.

Condon, Estelle P.↗