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Hoell, J. M.

Publications and source records attributed to Hoell, J. M..

18 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

Supporting Energy-Related Societal Applications Using NASA's Satellite and Modeling Data

Improvements to NASA Surface Meteorology and Solar Energy (SSE) web site are now being made through the Prediction of Worldwide Energy Resource (POWER) project under NASA Science Mission Directorate Applied Science Energy Management Program. The purpose of this project is to tailor NASA Science Mission results for energy sector applications and decision support systems. The current status of SSE and research towards upgrading estimates of total, direct and diffuse solar irradiance from NASA satellite measurements and analysis are discussed. Part of this work involves collaborating with partners such as the National Renewable Energy Laboratory (NREL) and the Natural Resources Canada (NRCan). Energy Management and POWER plans including historic, near-term and forecast datasets are also overviewed.

Stackhouse, Paul W., Jr.↗
NASA NTRS1985

Aircraft measurements of ammonia and nitric acid in the lower troposphere

The first simultaneous measurements of ammonia and nitric acid in the troposphere have been made from an aircraft using a tungsten oxide denuder system. Vertical profiles of NH3 and HNO3 taken over coastal Virginia and Maryland in March and September, 1983, at altitudes from 150 m to 3000 m, show mixing ratios that decrease with altitude. Ammonia profiles show substantial seasonal variation, while nitric acid profiles do not. Using the measured profiles and a one-dimensional photochemical model, lifetimes due to heterogeneous loss of one day for HNO3 and ten days for NH3 are calculated. In contrast, NH3 profiles up to 5300 m over the North Atlantic Ocean during August 1982 show mixing ratios that increase slightly with altitude. These data represent the first ammonia profiles measured over the ocean. It is suggested that the increase in NH3 with altitude is a result of an ammonia-rich continental air mass advected over the ocean, followed by the dissolution of NH3 in the marine boundary layer on water-covered sea salt particles.

Lebel, P. J.↗
NASA NTRS1984

An intercomparison of carbon monoxide, nitric oxide, and hydroxyl measurement techniques - Overview of results

Results from an intercomparison of methods to measure carbon monoxide (CO), nitric oxide (NO), and the hydroxyl radical (OH) are discussed. The intercomparison was conducted at Wallops Island, Virginia, in July 1983 and included a laser differential absorption and three grab sample/gas chromatograph methods for CO, a laser-induced fluorescence (LIF) and two chemiluminescence methods for NO, and two LIF methods and a radiocarbon tracer method for OH. The intercomparison was conducted as a field measurement program involving ambient measurements of CO (150-300 ppbv) and NO (10-180 pptv) from a common manifold with controlled injection of CO in incremental steps from 20 to 500 ppbv and NO in steps from 10 to 220 pptv. Only ambient measurements of OH were made. The agreement between the techniques was on the order of 14 percent for CO and 17 percent for NO. Hardware difficulties during the OH tests resulted in a data base with insufficient data and uncertanties too large to permit a meaningful intercomposition.

Hoell, J. M.↗
NASA NTRS1984

Assessment of Techniques for Measuring Tropospheric H Sub x O Sub y

In its continuing efforts to direct its applications programs towards relevant national needs, NASA is conducting the Tropospheric Chemistry Program, the long-range objective of which is to apply NASA's space technology to assess and predict human impact on the troposphere, particularly on the regional to global scale. One area of required research is instrumentation development, which is aimed at improving the capability to measure important trace gases and aerosols which are key species in the major atmospheric biogeochemical cycles. To focus on specific needs, the Instrumentation Worksphop for H(x)O(y) Tropospheric Species was conducted in August 1982. The workshop discussed current measurement needs and instrument capabilities for H(x)O(y) species, including OH, HO2, and H2O2. The workshop activities and conclusions are documented.

Hoell, J. M.↗
NASA NTRS1983

Tunable laser heterodyne spectrometer measurements of atmospheric species

It is pointed out that spectroscopic measurements conducted with the aid of tunable laser heterodyne spectrometers in the 3-30 micron range of the electromagnetic spectrum have the potential to measure the vertical profiles of tenuous gas molecules in the atmosphere with ultra high spectral resolution and great sensitivity. Programs related to the realization of this potential have been conducted for some time, and a Laser Heterodyne Spectrometer (LHS) experiment was developed. The present investigation has the objective to provide an overview of the LHS concept for measuring the vertical profiles of tenuous gas molecules in the upper atmosphere from space and airborne platforms, and to discuss the sensitivity ranges for this technique.

Allario, F.↗
NASA NTRS1982

Ammonia and the NOx budget of the troposphere

Liu et al. (1980) suggested that NOx transported from the stratosphere, as opposed to the anthropogenic source of NOx, may be the dominant source that controls the distribution of NOx in the global troposphere. These ideas require a reinvestigation, and, in particular, an assessment of the role of the oxidation of ammonia as a source of NOx. Attention is given to the results of an ammonia measurement program, in which the vertical distribution of ammonia in the troposphere and lower stratosphere could be studied with the aid of the Infrared Heterodyne Radiometer (IHR), a solar-viewing remote sensor. A one-dimensional photochemical model of the troposphere reported by Levine et al. (1980) was employed to study the chemical and physical processes that control the loss of ammonia in the troposphere. The results of the considered investigation suggest that the oxidation of ammonia may indeed be a significant source of NOx in the troposphere.

Levine, J. S.↗
NASA NTRS1981

Ozone air broadening coefficients in the 9-micron region

Air broadening coefficients and line strengths are reported for selected ozone lines in the 8.8 to 10 micron spectral region. These parameters were obtained from a least squares fit of the Voigt line shape to experimental ozone absorption spectra obtained with a tunable diode laser. Analysis of 11 lines in the nu 1 and 18 lines in the nu 3 band suggest a transition dependent coefficient, although no definitive relationship was identified. The average air broadening coefficient for the nu 1 and nu 3 ozone lines is 0.077 and 0.083 per cm/atm, respectively. The measured line strengths are typically 10% to a factor of 2 larger than those given in the AFGL compilation.

Hoell, J. M.↗
NASA NTRS1980

An experiment concept to measure stratospheric trace constituents by Laser Heterodyne Spectroscopy

The concept and techniques of a Laser Heterodyne Spectrometer experiment for measuring the vertical profiles of several stratospheric trace gases are discussed. The goal of the experiment is to develop a laser heterodyne receiver capable of measuring 2-4 gases simultaneously from Spacelab and, ultimately, from free-flying platforms. Sensitivity analyses are currently being performed for tenuous molecules such as ClO, ClONO2, NOCl, HO2, H2O2, and N2O5, although the capability exists for measuring more abundant gases, such as O3, HNO3, N2O, NO2, and CH4. Results indicate that O3 and ClO vertical profiles can be measured with an accuracy equal to or better than 95% and 80%, respectively, over the total profile. Laboratory measurements of the performance characteristics of the local oscillator and heterodyne detector are discussed with reference to 'excess-noise' and Doppler-shift effects.

Allario, F.↗
NASA NTRS1980

Remote infrared heterodyne radiometer measurements of atmospheric ammonia profiles

An infrared heterodyne radiometer has been used to study the seasonal variation of the vertical distribution of atmospheric ammonia. The ammonia profiles are inferred from high-resolution atmospheric solar transmittance measurements around the ammonia absorption feature at 927.32323 kaysers. The transmittance data are obtained from six IF channels with spectral resolutions ranging from .0067 to .033 kaysers. Results from this study show a marked decrease in the tropospheric ammonia level with a decrease at ground level from approximately 10 ppb in March 1979 to 1.3 ppb in August 1979.

Hoell, J. M.↗
NASA NTRS1980

The vertical distribution of tropospheric ammonia

A one-dimensional tropospheric photochemical model is used to simulate measured profiles of NH3 obtained with the Infrared Heterodyne Radiometer. The relative roles of homogeneous loss, heterogeneous loss, and vertical eddy transport are discussed in terms of selecting parameters which best fit the measurements. The best fit was obtained for a vertical eddy diffusion coefficient of 200,000/sq cm per sec or greater (corresponding to a characteristic vertical transport time in excess of about 35 days), and a characteristic heterogeneous loss time in excess of 10 days. The characteristic homogeneous chemical loss time was found to be about 40 days at the surface and decreased to about 180 days at 10 km, and not very sensitive to model chemical perturbations. Increased ground-level concentrations of NH3 to about 10 ppb, compared to background surface concentrations of about 1 ppb, were measured several weeks after application of ammonium nitrate fertilizer. This suggests that the volatilization of ammonium nitrate fertilizer is rapid, and an important source of NH3. Because of the characteristic times for the loss mechanisms, synoptic time-scale phenomena may play an important role in determining the tropospheric distribution of NH3 concentrations.

Levine, J. S.↗
NASA NTRS1979

Optical feedback effects on the performance of Pb/1-x/Sn/x/Se semiconductor lasers

The effects of optical feedback on the performance of Pb(1-x)Sn(x)Se semiconductor lasers are reported. Experimental results are presented to demonstrate that uncontrolled optical feedback can occur from optics external to the laser cavity and that these external optical elements can result in the formation of a composite cavity. This composite cavity can sustain a number of narrow closely spaced emission modes with the spectral characteristics of these modes dependent upon the parameters of the cavity. With weak feedback, the spectral width of the amplitude envelope of the new lasing modes resembles that of the original laser mode with no optical feedback. With strongly coupled feedback the envelope of the external cavity modes substantially broadens the apparent linewidth of the laser. It is shown that these effects can be eliminated, and, moreover, they offer the potential for obtaining spectrally narrow single-mode emission from Pb-salt lasers through the use of carefully designed external cavities.

Harward, C. N.↗
NASA NTRS1979

High resolution absorption coefficients for Freon-12

The ultra high resolution absorption coefficients of the Q-branch of Freon-12 obtained with tunable diode laser spectroscopy are presented. Continuous spectra are presented from 1155/cm to 1163/cm, and absolute wavelength calibration was obtained using SO2 spectra as a standard and a 5 cm Ge etalon for relative calibration between SO2 lines. The Freon-12 data obtained at a pressure of 0.05 torr showed a rich and highly structured spectra, but with the exception of three isolated features, collisional broadening reduces the spectra to a structureless continuum for nitrogen pressures greater than 20 torr. The spectra at 1161/cm continue to exhibit structure at atmospheric pressure.

Hoell, J. M.↗
NASA NTRS1979

Overview of the NASA tropospheric environmental quality remote sensing program

This paper will summarize the current NASA Tropospheric Environmental Quality Remote Sensing Program for studying the global and regional troposphere from space, airborne and ground-based platforms. As part of the program to develop remote sensors for utilization from space, NASA has developed a series of passive and active remote sensors which have undergone field test measurements from airborne and ground platforms. Recent measurements with active lidar and passive gas filter correlation and infrared heterodyne techniques will be summarized for measurements of atmospheric aerosols, CO, SO2, O3, and NH3. These measurements provide the data base required to assess the sensitivity of remote sensors for applications to urban and regional field measurement programs. Studies of Earth Observation Satellite Systems are currently being performed by the scientific community to assess the capability of satellite imagery to detect regions of elevated pollution in the troposphere. The status of NASA sponsored research efforts in interpreting satellite imagery for determining aerosol loadings over land and inland bodies of water will be presented, and comments on the potential of these measurements to supplement in situ and airborne remote sensors in detecting regional haze will be made.

Allario, F.↗
NASA NTRS1978

Infrared vibration-rotation spectra of the ClO radical using tunable diode laser spectroscopy

Tunable diode laser spectroscopy is used to measure the infrared vibration-rotation spectra of the ClO radical. The radical is generated in a flow system where a Cl2-He mixture passes through a microwave discharge to dissociate the Cl2. An O3-O2 mixture from an ozone generator is injected into the system downstream of the microwave discharge where O3 combines with Cl to form ClO. By adjusting the gas flow rates to yield an excess of Cl atoms, all the ozone is combined. ClO concentration is measured with UV absorption at 2577 and 2772 A and a deuterium lamp as a continuous source. Total cell pressure is 5.5 torr. The diode laser spectrometer is calibrated with ammonia lines as a reference where possible. The frequency of vibration-rotation lines is expressed as a function of rotational quantum number, fundamental vibrational frequency, and the rotational constants of the upper and lower vibrational states.

Rogowski, R. S.↗
NASA NTRS1974

Relative cross section and depolarization of NOCl

A standard photon counting technique and an argon-ion laser with 4545, 4579, 4727, 4765, 4880, 4965, 5017 and 5145-A lasing lines, providing a measurable Raman spectrum from NOCl, were used in the measurement of the Raman scattering cross section of NOCl at a Raman shift of 334.4 plus or minus 1.6/cm in relation to the N2 Raman cross section. A polarization analyzer and a quartz wedge were placed in front of the entrance slit of the double monochromator for depolarization measurements. Diagrams are plotted to show the scattering cross section and depolarization measurement results.

Hoell, J. M.↗