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Hohenberg, C. M.

Publications and source records attributed to Hohenberg, C. M..

At least 55 records · Page 3

I-Xe studies of individual Allende chondrules

Nine Allende chondrules and a sample of oxidized Allende matrix material are subjected to iodine-xenon studies, and the model compositions derived are compared with those of the Bjurbole chondrules. Chondrule 6 yields a well-defined isochron, with an apparent age that is later than Bjurbole whole rock. Elemental abundances suggest that all the chondrules except 6 may be pyroxene- or mesostasis-rich. The oxidized matrix sample gives a well defined isochron with an initial I-129/I-127 ratio higher than any plateaus seen in the chondrules, suggesting that the matrix predates the chondrules.

Swindle, T. D.↗

Cosmogenic neon from precompaction irradiation of Kapoeta and Murchison

Neon from hand-picked Murchison and Kapoeta grains, selected on the basis of the presence or absence of solar flare particle tracks, was analyzed in order to delineate the precompaction history of this material. The irradiated grains showed large enrichments of cosmogenic neon relative to the unirradiated grains. Galactic cosmic ray (GCR) exposure ages for the unirradiated grains yield the nominal values reported for the recent exposure history of these meteorites. Apparent minimum precompaction galactic exposure ages of 28 m.y. and 56 m.y. would have been obtained for Murchison and Kapoeta, respectively, if the cosmogenic effects in the irradiated grains were due to GCR irradiation. Since this seems unreasonably long, the cosmogenic neon in the irradiated grains may be due to spallation by solar cosmic rays. This, however, would require a more active early sun. The isotopic composition of the cosmogenic neon in these grains suggests a harder energy spectrum than is characteristic of present solar flares. Lack of apparent solar wind effects may require some kind of shielding, such as nebular gas.

Caffee, M. W.↗

Troctolite 76535 - A study in the preservation of early isotopic records

The lunar rock considered in the present investigation is a coarse-grained troctolite granulite containing about 58(vol)% plagioclase, 37% olivine, 4% pyroxene, and less than 1% accessory phases with a texture which indicates formation as a cumulate at depths between 10 and 30 km followed by an extended period of slow cooling. A description is presented of noble gas studies of separated minerals from 76535. The quantity of fission xenon from the in situ decay of Pu-244 provides further evidence for different, mineral-specific, isotopic closure times. The presented data shows that 76535 loses its surface-correlated xenon component upon disaggregation. No other xenon component is lost. The presence of solar gases in 76535 would seem to argue in favor of the external acquisition of the parentless extinct isotope effects and consequently favor 'thermal diffusion' and 'adsorption' over local redistribution models.

Caffee, M.↗

I-Xe ages of individual Bjurbole chondrules

Initial iodine isotopic compositions have been obtained for 10 individual chondrules from the meteorite Bjurbole, with a total range in well determined values of 6.5%, which would correspond to an age difference of 1.6 m.y. These results can be interpreted as distinct formation ages, metamorphic ages, or isotopic inhomogeneities in the early solar system, and can serve to constrain models for chondrule formation. Two of the chondrules show evidence of either isotopic inhomogeneities or disturbances of their I-Xe systems.

Caffee, M. W.↗

Shock disturbance of the I-Xe system

Three separate samples of the meteorite Bjurbole were artificially shocked at pressures of 70 kb, 200 kb, and 400 kb. Analysis of xenon released in stepwise heating shows that the I-Xe system of the 400 kb sample is substantially altered by the shock loading, and it is no longer possible to infer an age or trapped xenon composition for that sample. The 200-kb and 70-kb samples display isotopic structures progressively less altered demonstrating the gradations in shock disturbance likely to be found in natural systems. Interpretations of the I-Xe and Ar-40-Ar-39 systems for several naturally shocked meteorites are also presented. New data for Arapahoe do not confirm the previously reported age and trapped xenon composition, demonstrating instead that its I-Xe structure has been strongly disturbed by shock.

Caffee, M. W.↗

Xenon spallation systematics in Angra dos Reis

Literature Xe data for the Angra dos Reis meteorite have been resolved into constituent spallation, fission and trapped components. The spallation Xe compositions vary over a range wider than observed in any other samples, including lunar samples. These variations are due to the mixing of spallation Xe from Ba and rare earth element targets. It is possible to infer the Ba and rare earth spallation Xe compositions. Angra dos Reis spallation Xe compositions are systematically different from those observed in lunar samples, possibly because of differences in the irradiation conditions (geometry and shielding). Thus the Angra dos Reis data appear to be superior to lunar data for predicting spallation Xe compositions in other meteorites.

Hohenberg, C. M.↗

I-Xe dating - Intercomparisons of neutron irradiations and reproducibility of the Bjurbole standard

Previously unpublished data from the stepwise heating analysis of the Valecitos 1 (V1) Bjurbole standard are presented together with the results of an isotopic dilution measurement of a KI monitor included in the V1 irradiation package. The results of these analyses are compared with the values observed in other irradiations. Apparent I-Xe 'formation' ages are reproducible for three different samples of Bjurbole, suggesting isotopic homogeneity for initial iodine in the bulk material. The systematics of neutron capture in Xe-135 (produced from U-235 neutron fission) are examined and verified in irradiated BCR-1.

Hohenberg, C. M.↗

High sensitivity pulse-counting mass spectrometer system for noble gas analysis

A pulse-counting mass spectrometer is described which is comprised of a new ion source of cylindrical geometry, with exceptional optical properties (the Baur source), a dual focal plane externally adjustable collector slits, and a 17-stage Allen-type electron multiplier, all housed in a metal 21 cm radius, 90 deg magnetic sector flight tube. Mass discrimination of the instrument is less than 1 per mil per mass unit; the optical transmission is more than 90%; the source sensitivity (Faraday collection) is 4 ma/torr at 250 micron emission; and the abundance sensitivity is 30,000.

Hohenberg, C. M.↗

A post-Viking view of Martian geologic evolution

The geologic evolution of Mars is reviewed on the basis of data obtained by the Viking and previous missions. Current knowledge of the mean density and moment of inertia factor of Mars are surveyed and the constraints these data place on the structure and composition of the interior are discussed. Inferences drawn about Martian surface composition and mineralogy from lava modeling studies, in situ analyses, remote sensing observations, flow morphometry and investigations of weathering under Martian conditions are presented, and data on the topography, gravity field and structural features are considered in relation to the structure and deformational history of the crust. The temporal and spatial distribution of volcanic units are considered as a constraint on the thermal evolution of the planet, and other constraints on Martian thermal history, such as magnetic field data, are reviewed. Finally, the volatile inventory of Mars is discussed based on elemental and isotopic atmospheric abundance data and geological constraints on H2O and CO2 abundances.

Arvidson, R. E.↗

Fission xenon in troctolite 76535

Xenon released in stepwise heating of troctolite 76535 shows remarkable similarity to that from the gas-rich breccias. The low temperature fractions are highly enriched in fissiogenic xenon from Pu-244. Although the quantity of fission xenon is not inconsistent with reported age data, release patterns demonstrate that this component is not due to in situ decay. However, in contrast with the gas-rich breccias, the parentless radionuclear component in 76535 is not accompanied by solar wind xenon. Mechanisms for the emplacement of this component in 76535 cannot, therefore, involve exposure on the lunar surface but most likely involve adsorption along intergranular boundaries or thermally driven redistribution. The fact that xenon released from a gas-poor igneous cumulate can mimic that from gas-rich breccias, except for the presence of solar wind xenon in the latter, suggests that direct exposure to space is not required for the incorporation of these weakly bound, surface-correlated, parentless radionuclear components in lunar samples.

Hohenberg, C. M.↗

Noble gas component organization in 14301

A study is conducted of the organization of noble gases in the Apollo 14 breccia 14301, giving particular attention to xenon from the extinct radionuclides I-129 and Pu-244. An essential ingredient of this work is the intercomparison between noble gases released in single-stage melts of grain size fractions and those released in stepwise extractions. This approach resolves 'functional' noble gas components, which are organized by siting, into the specific genetic contributions on the basis of the 'activation energies' for diffusive loss. The procedure makes it possible to resolve various genetic components on the basis of the chemical and structural differences in their specific locations. Consequently, distinctions can be made among components acquired by different processes and among components which have undergone different regolith histories.

Bernatowicz, T. J.↗

Predicted versus observed cosmic-ray-produced noble gases in lunar samples - Improved Kr production ratios

New sets of cross sections for the production of krypton isotopes from targets of Rb, Sr, Y, and Zr have been constructed primarily on the bases of experimental excitation functions for Kr production from Y. These cross sections were used to calculate galactic-cosmic-ray and solar-proton production rates for Kr isotopes in the moon. The paper reports spallation Kr data obtained from ilmenite separates of rocks 10017 and 10047. Production rates and isotopic ratios for cosmogenic Kr observed in ten well-documented lunar samples and in ilmenite separates and bulk samples from several lunar rocks with long but unknown irradiation histories were compared with predicted rates and ratios. The agreements were generally quite good.

Regnier, S.↗

Xenon component organization in 14301

Xe in 14301 is a superposition of in situ spallation and presumably also fission Xe, of trapped solar wind, and of trapped fission Xe and Xe-129 redistributed after origin elsewhere on the moon. Some and probably most of the trapped fission originates from Pu-244. All of the components of various origins are released independently in stepwise heating, indicating that they were acquired by different means and remain in different sites within the sample. This applies to the excess fission and to the excess Xe-129, which fail to correlate quantitatively with each other; they must thus have been trapped by different mechanisms or at different times. In spite of their independent behavior in stepwise heating, the various trapped components contribute in constant proportion to the total Xe contents of the various size fractions. This quantitative correlation between excess Xe and solar wind Xe indicates that the same circumstances control the acquisition of both. The variation of the ratio of excess to solar wind Xe among different breccias thus can be ascribed more confidently to compositional variation in total Xe available for trapping rather than to the details of the trapping process.

Bernatowicz, T. J.↗

Excess fission xenon at Apollo 16

Results are reported of stepwise heating analyses of Xe and Kr in four Apollo 16 low-grade breccias: 60019, 60225, 60275, and 67455. All four samples contain significant amounts of solar wind gases and at least three contain excess fission Xe. This observation indicates that the excess fission Xe effect is global rather than local, i.e., results from moon-wide redistribution of fission Xe rather than local redistribution in KREEP-rich Apollo 14 material. It is suggested that the excess fission Xe phenomenon represents a temporal variation in the amount of fission Xe available for redistribution, that it is prominent in samples from both highland sites simply because they are older than mare sites, and that samples from these sites had experienced at least some of their surface exposure at an early epoch.

Bernatowicz, T. J.↗

Comparisons between observed and predicted cosmogenic noble gases in lunar samples

Comparisons are made between cosmogenic production rates and isotopic ratios predicted on the basis of nuclear systematics with those observed in well-documented lunar samples. Although some significant differences are found, the agreement in general is surprisingly good. The predicted production rates for Ar-38 and Xe-126 agree reasonably well with observation but the predicted rate for Ne-21 appears to be too high; in most cases the predicted rate for Kr-83 agrees to within 50%, although some larger differences are apparent. There are some prominent cases in which predicted isotopic compositons differ from observation: Kr-78/Kr-83 trends in the wrong sense with the Zr/Sr ratio; Xe-124/Xe-126 is too large by about 13%; Xe-128/Xe-126 is too small by about 6%; Xe-130/Xe-126 is too low by 30-40%.

Hohenberg, C. M.↗

The regolith history of 14307

Noble gas and trace element analyses of matrix and a clast from breccia 14307 are reported. This sample was exposed to a large neutron fluence, as seen by an elevated Sm-150/Sm-149 ratio and by noble gases, particularly Xe-136 from neutron fission of U-235. Strong constraints on the exposure history result from combined consideration of Sm-150, Xe-136, and spallation noble gases. Both clast and matrix were irradiated for about 1 AE under substantial shielding beginning at least 2 AE ago, probably more than 3 AE ago. The manifestations of soil exposure seen in the matrix - solar wind gases, glass formation, etc. - thus must have been acquired in an ancient epoch. The matrix has had a longer exposure to cosmic rays than the clast, presumably during its prebrecciation history as a soil. Brecciation probably occurred more than 1 AE ago, perhaps more than 3 AE ago, but at least 0.4 AE after the formation of the matrix constituents.

Bernatowicz, T.↗