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Holt, R. Glynn

Publications and source records attributed to Holt, R. Glynn.

Sonoluminescence in Space: The Critical Role of Buoyancy in Stability and Emission Mechanisms

Sonoluminescence is the term used to describe the emission of light from a violently collapsing bubble. Sonoluminescence ("light from sound") is the result of extremely nonlinear pulsations of gas/vapor bubbles in liquids when subject to sufficiently high amplitude acoustic pressures. In a single collapse, a bubble's volume can be compressed more than a thousand-fold in the span of less than a microsecond. Even the simplest consideration of the thermodynamics yields pressures on the order of 10,000 ATM, and temperatures of at least 10,000K. On the face of things, it is not surprising that light should be emitted from such an extreme process. Since 1990 (the year that Gaitan discovered light from a single bubble) there has been a tremendous amount of experimental and theoretical research in stable, single-bubble sonoluminescence (SBSL), yet there remain at least four unexplained phenomena associated with SBSL in 1g: the light emission mechanism itself, the existence of anisotropies in the emitted light, the disappearance of the bubble at some critical acoustic pressure, and the appearance of quasiperiodic and chaotic oscillations in the flash timing. Gravity, in the context of the buoyant force, is implicated in all four of these. We are developing KC-135 experiments probing the effect of gravity on single bubble sonoluminescence. By determining the stability boundaries experimentally in microgravity, and measuring not only light emission but mechanical bubble response, we will be able to directly test the predictions of existing theories.

Thomas, Charles R.

Dynamics of Aqueous Foam Drops

We develop a model for the nonlinear oscillations of spherical drops composed of aqueous foam. Beginning with a simple mixture law, and utilizing a mass-conserving bubble-in-cell scheme, we obtain a Rayleigh-Plesset-like equation for the dynamics of bubbles in a foam mixture. The dispersion relation for sound waves in a bubbly liquid is then coupled with a normal modes expansion to derive expressions for the frequencies of eigenmodal oscillations. These eigenmodal (breathing plus higher-order shape modes) frequencies are elicited as a function of the void fraction of the foam. A Mathieu-like equation is obtained for the dynamics of the higher-order shape modes and their parametric coupling to the breathing mode. The proposed model is used to explain recently obtained experimental data.

Akhatov, Iskander

Rheology of Foam Near the Order-Disorder Transition

The first part of our research results are summarized in the recent journal publication: J. Gregory McDaniel and R. Glynn Holt, 'Measurement of aqueous foam rheology by acoustic levitation', Phys. Rev. E 61, 2204 (2000). This aspect of the work was a combination of experiment and analysis. We built a levitation system capable of acoustically levitating small samples of aqueous foam of arbitrary gas and liquid volume fractions. We then modulated the acoustic field to induce normal mode oscillations of the foam samples. The observables from the experiment were frequency and mode number. For dry (roughly > 70% gas by volume) foams and small deformations, we developed an effective medium, normal-modes analysis which took the frequency and mode number from experiment, and gave us the shear elastic modulus of the foam as a function of Poisson's ratio. The second part of our results may be found in a soon-to-be submitted manuscript 'Dynamics of aqueous foam drops', I.Sh. Akhatov, J.G. McDaniel and R.G. Holt, describing our modeling in the wet foam limit by considering the acoustic problem. This aspect of the research is purely theoretical. Beginning from a mass-conserving mixture law, the fully nonlinear equations of motion for a wet (roughly < 10% gas by volume) foam drop of initially spherical shape were derived. The frequencies for normal mode oscillations were derived in the linear inviscid limit. The nonlinear equations were numerically solved to elicit the motion of a foam drop under acoustic excitation. The role of the time-varying void fraction in breathing-mode oscillations is of particular interest. As of the end of the current (NAG#3-2121) grant, this work was not yet concluded. We continue to work on this aspect in order to extend the analysis to cover the transition regime of gas volume fractions, as well as to compare to experiments in the wet regime.

Holt, R. Glynn

Measurement of Aqueous Foam Rheology by Acoustic Levitation

An experimental technique is demonstrated for acoustically levitating aqueous foam drops and exciting their spheroidal modes. This allows fundamental studies of foam-drop dynamics that provide an alternative means of estimating the viscoelastic properties of the foam. One unique advantage of the technique is the lack of interactions between the foam and container surfaces, which must be accounted for in other techniques. Results are presented in which a foam drop with gas volume fraction phi = 0.77 is levitated at 30 kHz and excited into its first quadrupole resonance at 63 +/- 3 Hz. By modeling the drop as an elastic sphere, the shear modulus of the foam was estimated at 75 +/- 3 Pa.

McDaniel, J. Gregory

Sonoluminescence in Space: The Critical Role of Buoyancy in Stability and Emission Mechanisms

Sonoluminescence is the term used to describe the emission of light from a violently collapsing bubble. Sonoluminescence ("light from sound") is the result of extremely nonlinear pulsations of gas/vapor bubbles in liquids when subject to sufficiently high amplitude acoustic pressures. In a single collapse, a bubble's volume can be compressed more than a thousand-fold in the span of less than a microsecond. Even the simplest consideration of the thermodynamics yields pressures on the order of 10,000 ATM. and temperatures of at least 10,000 K. On the face of things, it is not surprising that light should be emitted from such an extreme process. Since 1990 (the year that Gaitan discovered light from a single bubble) there has been a tremendous amount of experimental and theoretical research in stable, single-bubble sonoluminescence. Yet there remain four fundamental mysteries associated with this phenomenon: 1) the light emission mechanism itself; 2) the mechanism for anomalous mass flux stability; 3) the disappearance of the bubble at some critical acoustic pressure; and 4) the appearance of quasiperiodic and chaotic oscillations in the flash timing. Gravity, in the context of the buoyant force, is implicated in all four of these unexplained phenomena. We are developing microgravity experiments probing the effect of gravity on single bubble sonoluminescence. By determining the stability boundaries experimentally in microgravity, and measuring not only light emission but mechanical bubble response, we will be able to directly test the unambiguous predictions of existing theories. By exploiting the microgravity environment we will gain new knowledge impossible to obtain in earth-based labs which will enable explanations for the above mysteries. We will also be in a position to make new discoveries about bubbles which emit light.

Holt, R. Glynn

Rheology of Foam Near the Order-Disorder Phase Transition

Foams are extremely important in a variety of industrial applications. Foams are widely used in fire-fighting applications, and are especially effective in fighting flammable liquid fires. In fact the Fire Suppression System aboard the Space Shuttle utilizes cylinders of Halon foam, which, when fired, force a rapidly expanding foam into the convoluted spaces behind instrument panels. Foams are critical in the process of enhanced oil recovery, due to their surface-active and highly viscous nature. They are also used as drilling fluids in underpressurized geologic formations. They are used as transport agents, and as trapping agents. They are also used as separation agents, where ore refinement is accomplished by froth flotation of the typically lighter and hydrophobic contaminants. The goal of the proposed investigation is the determination of the mechanical and rheological properties of foams, utilizing the microgravity environment to explore foam rheology for foams which cannot exist, or only exist for a short time, in 1g.

Holt, R. Glynn

Experiment 5: Science and Technology of Surface Controlled Oscillations: Report on USML-2 Results

Minuscule amounts (e.g., 1 part in 10,000) of a surface-active material in a liquid can drastically affect the surface behavior of the liquid, influencing how the material flows and mixes with other liquid and solid materials. In many respects, the science of surfactants has been empirical, with trial and error dominating over the ability to predict how surfactant type and concentration influence surface behavior. A program for the modeling of surfactant behavior has been established at Yale. This program combines experimental work performed both on the ground and in space, and theoretical and numerical modeling. By levitating a drop of liquid in air, away from solid container surfaces, and by manipulating the drop with acoustic radiation forces, we have been able to establish idealized conditions for surface behavior studies. The primary experiments involve the study of the free oscillations of initially deformed drops. In STS-73, the USML-2 mission of the Space Shuttle, we performed the following measurements: 1) the oscillation of a spherical drop in its quadrupole mode; 2) the oscillation of a drop about a deformed (oblate) shape; 3) the slow static squeezing of the drop from spherical to nearly flat; and 4) the superoscillations of drops when the radiation forces maintaining the drop in a flattened state are suddenly reduced. Analytic and numerical studies have enabled us to understand the physics of these oscillations and to extract material properties such as the dynamic surface tension and the surface viscosities (shear and dilatational). The relation to ground-based studies is essential, because the knowledge and understanding gleaned from our space studies enable us to interpret ground-based data.

Apfel, Robert E.

Drops in Space: Super Oscillations and Surfactant Studies

An unprecedented microgravity observation of maximal shape oscillations of a surfactant-bearing water drop the size of a ping pong ball was observed during a mission of Space Shuttle Columbia as part of the second United States Microgravity Laboratory-USML-2 (STS-73, October 20-November 5, 1995). The observation was precipitated by the action of an intense sound field which produced a deforming force on the drop. When this deforming force was suddenly reduced, the drop executed nearly free and axisymmetric oscillations for several cycles, demonstrating a remarkable amplitude of nonlinear motion. Whether arising from the discussion of modes of oscillation of the atomic nucleus, or the explosion of stars, or how rain forms, the complex processes influencing the motion, fission, and coalescence of drops have fascinated scientists for centuries. Therefore, the axisymmetric oscillations of a maximally deformed liquid drop are noteworthy, not only for their scientific value but also for their aesthetic character. Scientists from Yale University, the Jet Propulsion Laboratory (JPL) and Vanderbilt University conducted liquid drop experiments in microgravity using the acoustic positioning/manipulation environment of the Drop Physics Module (DPM). The Yale/JPL group's objectives were to study the rheological properties of liquid drop surfaces on which are adsorbed surfactant molecules, and to infer surface properties such as surface tension, Gibb's elasticity, and surface dilatational viscosity by using a theory which relies on spherical symmetry to solve the momentum and mass transport equations.

Apfel, Robert E.

The Onset of Resonance-Controlled Instability in Spherical Bubble Oscillations

Single bubble dynamics are investigated using acoustic techniques for isolation and manipulation. The goal of the investigations is to understand the dynamic origin of the various phenomena that bubbles exhibit: light emission, enhanced mass transport, chaotic and quasiperiodic oscillations, and translations. Once understood, acoustically manipulated bubbles can serve as platforms for materials effects on free surfaces, using surfactants to alter surface rheology and observing how that affects both dynamics and also mass transport. The effects of gravity on the problem will be shown to be significant. The first set of observations from 1g experimentation are presented. These observations are of the onset conditions for instability of the spherical shape of the bubble. For the size range 55-90 microns in diameter we observe instability governed by resonant mode coupling, which is significantly affected by the buoyant force and its effects.

Holt, R. Glynn

Faraday Wave Turbulence on a Spherical Liquid Shell

Millimeter-radius liquid shells are acoustically levitated in an ultrasonic field. Capillary waves are observed on the shells. At low energies (minimal acoustic amplitude, thick shell) a resonance is observed between the symmetric and antisymmetric thin film oscillation modes. At high energies (high acoustic pressure, thin shell) the shell becomes fully covered with high-amplitude waves. Temporal spectra of scattered light from the shell in this regime exhibit a power-law decay indicative of turbulence.

Holt, R. Glynn

Surface-Controlled Drop Oscillations in Space

Large liquid drops were deformed by an acoustic standing wave in a resonant air chanber called the Drop Physics Module, which was carried on Space Shuttle Columbia as part of the second United States Microgravity Laboratory mission. When this deforming force was suddenly reduced, the drops executed free oscillations about a perfect sherical equilibrium. Results are presented for pure water and aqueous solutions of soluble surfactants. [PACS: 43.25.U, 47.55Dz, 68.10.Cr, 83.10.-y].

microgravity drop oscillations drop physics module

The Onset of Resonance-Controlled Instability in Spherical Bubble Oscillations

Single bubble dynamics are investigated using acoustic techniques for isolation and manipulation. The goal of the investigations is to understand the dynamic origin of the various phenomena that bubbles exhibit: light emission, enhanced mass transport, chaotic and quasiperiodic oscillations and translations. Once understood, acoustically manipulated bubbles can serve as platforms for materials effects on free surfaces, using surfactants to alter surface rheology and observing how that affects both dynamics and also mass transport. The effects of gravity on the problem will be shown to be significant. The first set of observations from 1g experimentation are presented. These observations are of the onset conditions for instability of the spherical shape of the bubble. For the size range 55 - 90 microns in diameter we observe instability governed by resonant mode coupling, which is significantly affected by the buoyant force and its effects.

bubbles

Searching for the Second Harmonic

To mathematically model the oscillations of a spherical bubble, either the time-dependent volume V(t) or the radius R(t) can be used as the dependent variable. A recent exchange between the advocates of the volume approach and the radius approach concerns in apparent discrepancy in the predicted nonlinear acoustic emissions from a bubble subject to a time-periodic external pressure field. This letter attempts to resolve the discrepancy via an examination of the arguments offered by both sides. In addition, some general comments on nonlinear harmonic and subharmonic emissions from acoustically forced bubble oscillations are presented.

Holt, R. Glynn

Surface characterization through shape oscillations of drops in microgravity and 1-g

The goal of these experiments is to determine the rheological properties of liquid drops of single or multiple components in the presence or absence of surface active materials by exciting drops into their quadrupole resonance and observing their free decay. The resulting data coupled with appropriate theory should give a better description of the physics of the underlying phenomena, providing a better foundation than earlier empirical results could. The space environment makes an idealized geometry available (spherical drops) so that theory and experiment can be properly compared, and allows a 'clean' environment, by which is meant an environment in which no solid surfaces come in contact with the drops during the test period. Moreover, by considering the oscillations of intentionally deformed drops in microgravity, a baseline is established for interpreting surface characterization experiments done on the ground by other groups and ours. Experiments performed on the United States Microgravity Laboratory Laboratory (USML-1) demonstrated that shape oscillation experiments could be performed over a wide parameter range, and with a variety of surfactant materials. Results, however, were compromised by an unexpected, slow drop tumbling, some problems with droplet injection, and the presence of bubbles in the drop samples. Nevertheless, initial data suggests that the space environment will be useful in providing baseline data that can serve to validate theory and permit quantitative materials characterization at 1-g.

Apfel, Robert E.