Engineering topics

Huss, Gary R.

Publications and source records attributed to Huss, Gary R..

16 records

DOE OSTI2022

Oxygen isotopes of anhydrous primary minerals show kinship between asteroid Ryugu and comet 81P/Wild2

The extraterrestrial materials returned from asteroid (162173) Ryugu consist predominantly of low-temperature aqueously formed secondary minerals and are chemically and mineralogically similar to CI (Ivuna-type) carbonaceous chondrites. Here, we show that high-temperature anhydrous primary minerals in Ryugu and CI chondrites exhibit a bimodal distribution of oxygen isotopic compositions: 16 O-rich (associated with refractory inclusions) and 16 O-poor (associated with chondrules). Both the 16 O-rich and 16 O-poor minerals probably formed in the inner solar protoplanetary disk and were subsequently transported outward. The abundance ratios of the 16 O-rich to 16 O-poor minerals in Ryugu and CI chondrites are higher than in other carbonaceous chondrite groups but are similar to that of comet 81P/Wild2, suggesting that Ryugu and CI chondrites accreted in the outer Solar System closer to the accretion region of comets.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2022

Contribution of Ryugu-like material to Earth’s volatile inventory by Cu and Zn isotopic analysis

We report initial analyses showed that asteroid Ryugu’s composition is close to CI (Ivuna-like) carbonaceous chondrites (CCs) – the chemically most primitive meteorites, characterized by near-solar abundances for most elements. However, some isotopic signatures (for example, Ti, Cr) overlap with other CC groups, so the details of the link between Ryugu and the CI chondrites are not yet fully clear. Here we show that Ryugu and CI chondrites have the same zinc and copper isotopic composition. As the various chondrite groups have very distinct Zn and Cu isotopic signatures, our results point at a common genetic heritage between Ryugu and CI chondrites, ruling out any affinity with other CC groups. Since Ryugu’s pristine samples match the solar elemental composition for many elements, their Zn and Cu isotopic compositions likely represent the best estimates of the solar composition. Earth’s mass-independent Zn isotopic composition is intermediate between Ryugu/CC and non-carbonaceous chondrites (NCs), suggesting a contribution of Ryugu-like material to Earth’s budgets of Zn and other moderately volatile elements.

58 GEOSCIENCES↗

NASA NTRS2005

Microbeam Investigations of Presolar and Early Solar System Materials

This grant provided three years of funding for my Cosmochemistry research program at Arizona State University. This research resulted in 11 peer-reviewed papers in six Journals and 35 abstracts to 11 Conferences and Workshops (see list below). My original proposal listed three main areas of research: 1) Studies of presolar grains; 2) Studies of short-lived radionuclides and; 3) Investigations of nebular processes and the origin of chondritic components.

Huss, Gary R.↗

NASA NTRS2003

Microbeam Investigations of Presolar and Early Solar System Materials

This grant provided three years of funding to initiate an independent research program in Cosmochemistry at Arizona State University. Because the new equipment that was installed at ASU took longer than expected to get running, the project was extended for a fourth year with no additional funding. By the time the funds were expended, we had set up an entirely new ion microprobe laboratory at ASU, and we have been fully operational for over two years. This laboratory was funded in almost equal parts by NASA, NSF, and ASU. Papers describing the first results from this new laboratory are being published now, and the results have been making an impact on the Cosmochemistry community. While this laboratory was being built, I continued my research program in collaboration with G. J. Wasserburg at Caltech. As equipment became available, I gradually shifted my research to ASU. Over the lifetime of this grant, my research program resulted in 12 papers and 13 abstracts on topics ranging from presolar grains (2 papers, 3 abstracts), short-lived radionuclides (6 papers, 6 abstracts), chemical compositions of chondritic materials (3 papers, 3 abstracts), silicon isotopic fractionation (1 abstract), and the oxygen composition of the Sun (1 paper). The most important results of this period were the discovery of presolar hibonite in a meteorite residue, the measurement of 26A1 in CAIs from enstatite chondrites, and the measurements of 10Be in type A CAIs from CV chondrites. All of these results have had a significant impact on research in Cosmochemstry.

Huss, Gary R.↗

NASA NTRS2002

Sulfur Isotope Composition of Putative Primary Troilite in Chondrules

Sulfur isotope compositions of putative primary troilites in chondrules from Bishunpur were measured by ion probe. These primary troilites have the same S isotope compositions as matrix troilites and thus appear to be isotopically unfractionated. Additional information is contained in the original extended abstract.

Tachibana, Shogo↗

NASA NTRS2002

Isotopic Study of Silicon Carbide in Semarkona

We have measured Si and C isotopes for individual SiC grains from Semarkona. Our results are compared with those of previous studies on SiC from Murchison and Orgueil. Metamorphism and grain-size distribution can affect these comparisons. Additional information is contained in the original extended abstract.

Smith, Julie B.↗

NASA NTRS2001

Presolar Grains as Tracers of Nebular Processes

This grant provided two years of funding to investigate the abundances of presolar diamond, SiC, and graphite in primitive chondritic meteorites. The original proposal was for a three-year study, but two years of funding were awarded. The proposed work plan for the first year included preparation of acid residues for two meteorites and noble-gas measurements on those residues and residues of two other meteorites that had been previously prepared. The meteorites to be measured were Acfer 003, Adrar 214, RC075, and Axtell. In the second year, the plan called for measuring Renazzo and Murchison, and beginning chemical processing on another set of meteorites, including Murray, which were to be measured in the third year. All of the meteorites listed above have been measured and the results were presented in three abstracts. The project is continuing under follow-on grants and one of two planned major papers is almost ready for submission.

Huss, Gary R.↗

NASA NTRS1994

Noble gases in presolar diamonds I: Three distinct components and their implications for diamond origins

High-purity separates of presolar diamond were prepared from 14 primitive chondrites from 7 compositional groups. Their noble gases were measured using stepped pyrolysis. Three distinct noble gas components are present in diamonds, HL, P3, and P6, each of which is found to consist of five noble gases. P3, released between 200 C and 900 C, has a 'planetary' elemental abundance pattern and roughly 'normal' isotopic ratios. HL, consisting of isotopically anomalous Xe-HL and Kr-H, Ar with high Ar-38/Ar-36, and most of the gas making up Ne-A2 and He-A, is released between 1100 C and 1600 C. HL has 'planetary' elemental ratios, except that it has much more He and Ne than other known 'planetary' components. HL gases are carried in the bulk diamonds, not in some trace phase. P6 has a slightly higher median release temperature than HL and is not cleanly separated from HL by stepped pyrolysis. Our data suggest that P6 has roughly 'normal' isotopic compositions and 'planetary' elemental ratios. Both P3 and P6 seem to be isotopically distinct from P1, the dominant 'planetary' noble-gas component in primitive chondrites. Release characteristics suggest that HL and P6 are sited in different carriers within the diamond fractions, while P3 may be sited near the surfaces of the diamonds. We find no evidence of separability of Xe-H and Xe-L or other isotopic variations in the HL component. However, because approximately 10(exp 10) diamonds are required to measure a Xe composition, a lack of isotopic variability does not constrain diamonds to come from a single source. In fact, the high abundance of diamonds in primitive chondrites and the presence of at least three distinct noble-gas components strongly suggest that diamonds originated in many sources. Relative abundances of noble-gas components in diamonds correlate with degree of thermal processing, indicating that all meteorites sampled essentially the same mixture of diamonds. That mixture was probably inherited from the Sun's parent molecular cloud.

Huss, Gary R.↗

NASA NTRS1994

Noble gases in presolar diamonds II: Component abundances reflect thermal processing

Using the isotopic compositions derived in Huss and Lewis, 1994a, abundances of the P3, HL, and P6 noble-gas components were determined for 15 diamonds separates from primitive chondrites of 8 chondrite classes. Within a meteorite class, the relative abundances of these components correlate with the petrologic subtype of the host meteorite, indicating that metamorphism is primarily responsible for the variations. Relative abundances of P3, HL, and P6 among diamond samples can be understood in terms of thermal processing of a single mixture of diamonds like those now found in CI and CM2 chondrites. With relatively gentle heating, primitive diamonds first lose their low-temperature P3 gases and a 'labile' fraction of the HL component. Mass loss associated with release of these components produces an increase in the HL and P6 content of the remaining diamond relative to unprocessed diamond. Higher temperatures initiate destruction of the main HL carrier, while the HL content of the surviving diamonds remains essentially constant. At the same time, the P6 carrier begins to preferentially lose light noble gases. Meteorites that have experienced metamorphic temperatures greater than or = 650 C have lost essentially all of their presolar diamond through chemical reactions with surrounding minerals. The P3 abundance seems to be a function only of the maximum temperature experienced by the diamonds and thus is independent of the nature of the surrounding environment. If all classes inherited the same mixture of primitive diamonds, then P3 abundances would tie together the metamorphic scales in different meteorite classes. However, if the P3 abundance indicates a higher temperature than do other thermometers applicable to the host meteorite, then the P3 abundance may contain information about heating prior to accretion. Diamonds in the least metamorphosed EH, CV, and CO chondrites seem to carry a record of pre-accretionary thermal processing.

Huss, Gary R.↗

NASA NTRS1994

Oxygen isotopes in circumstellar Al203 grains from meteorites and stellar nucleosynthesis

We have found a approximately 3 micrometer Al2O3 grain (B39) in the Bishunpur LL3.1 chondrite that is enriched in 0-17 by a factor of approximately 6.8 (0-16/0-17 = 385 +/- 9) and depleted in 0-18 by almost 60% (0-16/0-18 = 853 +/- 30) relative to solar system oxygen and has an initial Al-26/Al-27 = 1.7 +/- 0.2 x 10 (exp 3), approximately 34 times greater than the initial solar system value. The isotopic compositions of B39 and two other Al2O3 grains previously reported from the Orgueil and Murchison meteorites show that these grains formed directly from the ejecta of low-mass AGB stars with C/O less than 1. A simple theoretical analysis is presented showing that the oxygen systematics of the grains are a natural consequence of main-sequence evolution followed by first dredge-up Al-26 is the result of third dredge-up. Circumstellar Al2O3 grains provide very precise isotopic data for stellar ejecta that complement spectroscopic observations of oxygen-rich stars. Isotopic differences indicate that the Al2O3 grains come from separate stars of different mass and intital oxygen composition that originated in molecular clouds different from the one in which the solar system formed.

Huss, Gary R.↗

NASA NTRS1993

Do SiC grains in Orgueil differ from those in Murchison?

Studies of individual presolar SiC grains have shown that most are enriched in Si-29, Si-30, and C-13, and depleted in N-15, compared to solar-system abundances and that many have large excesses of Mg-26, most plausibly from in situ decay of Al-26. Stone et al., observed that Si from a family of platy SiC grains define a linear array on a 3-isotope plot that does not pass through normal solar-system Si. In contrast, Si-isotope data from over 100 3-4 micron SiC grains from Murchison from an elongate ellipse enclosing the Stone et al. linear array but also including 'normal' solar-system Si. To investigate whether this difference in Si isotopes indicates different populations of SiC in the two meteorites and to improve the characterization of Orgueil SiC, we used the PANURGE ion microprobe to measure Si, C, N, and Mg isotopes and Al and Na concentrations in a suite of 2-5 micron SiC grains from a new sample of Orgueil.

Huss, Gary R.↗

NASA NTRS1991

Meteorite mass distributions and differences between Antarctic and non-Antarctic meteorites

Meteorite mass distributions provide important insight into real and apparent differences between Antarctic and non-Antarctic meteorites. Antarctic meteorites are typically smaller than non-Antarctic meteorites and represent a different portion of the mass distribution of infalling meteorites. This results from the different methods employed to acquire the collections and from the much smaller effective collecting area for Antarctic meteorites. Comparisons of the proportions and mass distributions of H and L chondrites for different ice fields suggest that previously reported high H to L ratio among Antarctic meteorites compared to witnessed falls results from an unrecognized H5 shower fall that covered the Allan Hills Main and Near Western ice fields in the relatively recent past. The probable presence of unrecognized shower falls among the Antarctic meteorites means that population statistics, even corrected for presently recognized pairing, cannot be used to support the suggestion by Dennison et al. (1986) of a temporal variation in the mixture of meteorites arriving on earth.

Huss, Gary R.↗

NASA NTRS1990

Ubiquitous interstellar diamond and SiC in primitive chondrites - Abundances reflect metamorphism

It is shown here that interstellar diamond and SiC were incorporated into all groups of chondrite meteorites. Abundances rapidly go to zero with increasing metamorphic grade, suggesting that metamorphic destruction is responsible for the apparent absence of these grains in most chondrites. In unmetamorphosed chondrites, abundances normalized to matrix content are similar for different classes. Diamond samples from chondrites of different classes have remarkably similar noble-gas constants and isotropic compositions, although constituent diamonds may have come from many sources. SiC seems to be more diverse, partly because grains are large enough to measure individually, but average characteristics seem to be similar from meteorite to meteorite. These observations suggest that various classes of chondritic meteorites sample the same solar system-wide reservoir of interstellar grains.

Huss, Gary R.↗

NASA NTRS1990

Meteorite infall as a function of mass - Implications for the accumulation of meteorites on Antarctic ice

Antarctic meteorites are considerably smaller, on average, than those recovered elsewhere in the world, and seem to represent a different portion of the mass distribution of infalling meteorites. When an infall rate appropriate to the size of Antarctic meteorites is used (1000 meteorites 10 grams or larger/sq km/1 million years), it is found that direct infall can produce the meteorite accumulations found on eight ice fields in the Allan Hills region in times ranging from a few thousand to nearly 200,000 years, with all but the Allan Hills Main and Near Western ice fields requiring less than 30,000 years. Meteorites incorporated into the ice over time are concentrated on the surface when the ice flows into a local area of rapid ablation. The calculated accumulation times, which can be considered the average age of the exposed ice, agree well with terrestrial ages for the meteorites and measured ages of exposed ice. Since vertical concentration of meteorites through removal of ice by ablation is sufficient to explain the observed meteorite accumulations, there is no need to invoke mechanisms to bring meteorites from large areas to the relatively small blue-ice patches where they are found. Once a meteorite is on a bare ice surface, freeze-thaw cycling and wind break down the meteorite and remove it from the ice. The weathering lifetime of a 100-gram meteorite on Antarctic ice is on the order of 10,000 + or - 5,000 years.

Huss, Gary R.↗

NASA NTRS1988

The role of presolar dust in the formation of the solar system

The characteristics of presolar dust are discussed and evidence is provided to support the possibility that presolar dust was the primary building material for the meteorites and terrestrial planets. The material in the sun's parent molecular cloud is divided into eight reservoirs. The results show that presolar dust and objects made from processed dust make up the vast majority of the material in primitive chondrites. The present theory is able to account for the chemical and oxygen isotopic variations between meteorite classes, the formation of chondrules, the accretion of chondrites, and parent body metamorphism.

Huss, Gary R.↗

NASA NTRS1987

On the presolar origin of the 'normal planetary' noble gas component in meteorites

Several components of planetary noble gases, including CCFXe (Xe-X), s-process Kr and Xe, and Ne-E, are now thought to have had a presolar origin. It is proposed that the 'normal planetary' noble gas component, which contains most of the planetary Ar, Kr, and Xe, is also presolar. This component was trapped in carbonaceous mantles as the mantles formed on grain surfaces in the molecular cloud. The presolar dust grains and their carbonaceous mantles were then incorporated into primitive meteorites. This model naturally explains: (1) the affinity of 'normal planetary' noble gases for carbonaceous material in primitive chondrites; (2) the near absence of He and Ne in the 'normal planetary' component; (3) the elemental fractionation patterns of the 'exotic' and 'normal planetary' components; (4) the similarity of the isotopic compositions of 'normal planetary' and trapped solar Ar, Kr, and Xe; (5) the high noble gas content of the 'normal planetary' gas carrier; (6) several aspects of the chemistry of the 'normal planetary' gas carrier; (7) the correlation of planetary noble gases with the fine-grained material in primitive chondrites; and (8) the widespread occurrence of the planetary fractionation pattern throughout the solar system.

Huss, Gary R.↗