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Hwang, C.

Publications and source records attributed to Hwang, C..

At least 37 records · Page 2

Electrolytes with Improved Safety Developed for High Specific Energy Li-Ion Cells with Si-Based Anodes

A number of electrolyte formulations that have improved safety characteristics have been developed for use with high capacity silicon-based anodes. To improve the compatibility with Si-based anodes, a number of technical approaches have been employed, including: (1) the use of mono-fluoroethylene carbonate (FEC) in conjunction with, or in lieu of, ethylene carbonate (EC), (2) the use of high proportions of fluorinated co-solvents, (3) the use of vinylene carbonate (VC) to stabilize the Si/C electrode, and (4) the use of lithium bis(oxalato)borate (LiBOB) to improve the compatibility of the electrolyte when Si/C electrodes are used in conjunction with high voltage cathodes. Candidate electrolytes were studied in Li/Si-C and Si-C/ Li(MnNiCo)O2 (NMC) coin cells, as well as in larger Si-C/NMC three-electrode cells equipped with lithium reference electrodes. In summary, many electrolytes that contain triphenyl phosphate (TPP), which is used as a flame retardant additive up to concentrations of 15 volume percent, and possess FEC as a co-solvent have been demonstrated to outperform the all-carbonate baseline electrolytes when evaluated in Si-C/ Li(MnNiCo)O2 cells.

Silicon-Based Anode↗

Improved Wide Operating Temperature Range of LiNiCoAiO2-based Li-ion Cells with Methyl Propionate-based Electrolytes

Demonstration of wide operating temperature range Li-ion electrolytes Methyl propionate-based wide operating temperature range electrolytes were demonstrated to provide dramatic improvement of the low temperature capability of Quallion prototype Li-ion cells (MCMB-LiNiCoAlO2). Some formulations were observed to deliver over 60% of the room temperature capacity using a 5C rate at - 40oC !! Represents over a 4-fold improvement over the baseline electrolyte system. Demonstrated operational capability of a number of systems over a wide temperature range (-40 to +70 C) Demonstrated reasonably good long term cycle life performance at high temperature (i.e., at +40deg and +50 C) A number of formulations containing electrolytes additives (i.e., FEC, VC, LiBOB, and lithium oxalate) have been shown to have enhanced lithium kinetics at low temperature and promising high temperature resilience. Demonstrated good performance in larger capacity (12 Ah) Quallion Li-ion cells with methyl propionate-based electrolytes. Current efforts focused upon performing life studies and the impact upon low temperature capability.

Li-ion electrolytes↗

Electrolytes with Improved Safety Characteristics for High Voltage, High Specific Energy Li-ion Cells

(1) NASA is actively pursuing the development of advanced electrochemical energy storage and conversion devices for future lunar and Mars missions; (2) The Exploration Technology Development Program, Energy Storage Project is sponsoring the development of advanced Li-ion batteries and PEM fuel cell and regenerative fuel cell systems for the Altair Lunar Lander, Extravehicular Activities (EVA), and rovers and as the primary energy storage system for Lunar Surface Systems; (3) At JPL, in collaboration with NASA-GRC, NASA-JSC and industry, we are actively developing advanced Li-ion batteries with improved specific energy, energy density and safety. One effort is focused upon developing Li-ion battery electrolyte with enhanced safety characteristics (i.e., low flammability); and (4) A number of commercial applications also require Li-ion batteries with enhanced safety, especially for automotive applications.

improved safety↗

The Evaluation of Triphenyl Phosphate as a Flame Retardant Additive to Improve the Safety of Lithium-Ion Battery Electrolytes

With the intent of improving the safety characteristics of lithium ion cells, electrolytes containing flame retardant additives have been investigated. A number of triphenyl phosphate-containing electrolytes were evaluated in both coin cells and experimental three electrode lithium-ion cells (containing reference electrodes). A number of chemistries were investigated, including MCMB carbon/LiNi(0.8)Co(0.2)O2 (NCO), graphite/LiNi(0.8)Co(0.15)Al(0.05)O2 (NCA), Li/Li(Li(0.17)Ni(0.25)Mn(0.58))O2, Li/LiNiMnCoO2 (NMC) and graphite/LiNiMnCoO2 (NMC), to study the effect that different electrolyte compositions have upon performance. A wide range of TPP-containing electrolytes were demonstrated to have good compatibility with the C/NCO, C/NCA, and Li/NMC systems, however, poor performance was initially observed with the high voltage C/NMC system. This necessitated the development of improved electrolytes with stabilizing additives, leading to formulations containing lithium bis(oxalato)borate (LiBOB) that displayed substantially improved performance.

rechargable batteries↗

The Evaluation of Triphenyl Phosphate as a Flame Retardant Additive to Improve the Safety of Lithium-Ion Battery Electrolytes

NASA is actively pursuing the development of advanced electrochemical energy storage and conversion devices for future lunar and Mars missions. The Exploration Technology Development Program, Energy Storage Project is sponsoring the development of advanced Li-ion batteries and PEM fuel cell and regenerative fuel cell systems for the Altair Lunar Lander, Extravehicular Activities (EVA), and rovers and as the primary energy storage system for Lunar Surface Systems. At JPL, in collaboration with NASA-GRC, NASA-JSC and industry, we are actively developing advanced Li-ion batteries with improved specific energy, energy density and safety. One effort is focused upon developing Li-ion battery electrolyte with enhanced safety characteristics (i.e., low flammability). A number of commercial applications also require Li-ion batteries with enhanced safety, especially for automotive applications.

Li-ion batteries↗

Standard user data services for spacecraft applications

The Consultative Committee for Space Data Systems is an international organization of national space agencies that is branching out to provide new standards to enhanced reuse of spacecraft equiptment and software. These Spacecraft Onboard Interface (SOIF) standards will be based on the well-known Internet protocols. this paper will review the SOIF standards by looking at the services that are being proposed for SOIF.

space interfaces avionics interfaces standard inte↗

COTS-based OO-component approach for software inter-operability and reuse (software systems engineering methodology)

The purpose of this research and study paper is to provide a summary description and results of rapid development accomplishments at NASA/JPL in the area of advanced distributed computing technology using a Commercial-Off--The-Shelf (COTS)-based object oriented component approach to open inter-operable software development and software reuse.

object-oriented components distributed computing a↗

Estimating regional evapotranspiration from remotely sensed data by surface energy balance models

Spatial and temporal variations of surface radiative temperatures of the burned and unburned areas of the Konza tallgrass prairie were studied. The role of management practices, topographic conditions and the uncertainties associated with in situ or airborne surface temperature measurements were assessed. Evaluation of diurnal and seasonal spectral characteristics of the burned and unburned areas of the prairie was also made. This was accomplished based on the analysis of measured spectral reflectance of the grass canopies under field conditions, and modelling their spectral behavior using a one dimensional radiative transfer model.

Asrar, Ghassem↗

Galileo

The Galileo consists of two main parts: a Jupiter orbiter and a probe. After a 1000 day journey, the Galileo will assume orbit around the giant planet, an orbit which will last for 200 days, in the hopes of astronomers. The orbit will carry the Galileo past its four Jovian satellites--Io, Europa, Ganymede, and Callisto - a combined total of 11 times. This will enable scientists to study the atmosphere of not only the largest planet in the solar system, but its large moons as well. Sometime in August of 1988, the Galileo will approach Jupiter and begin its important activities. Fifty-six days away from planetary encounter, the Galileo will release the probe which will continue the trip to Jupiter and enter the atmosphere. As it descends through the atmosphere, the probe will unfurl a parachute to slow its speed as it broadcasts information back to the waiting orbiter, which will in turn relay it back to the waiting scientists on Earth. The probe's descent time is expected to be approximately 15 min before Jupiter's pressure and heat overwhelm the probe's protection. However, scientists are hopeful that the probe will survive longer than 15 min, possibly up to 60 min.

Hwang, C.↗

Adaptive flutter suppression, analysis and test

Methods of adaptive control have been applied to suppress a potentially violent flutter condition of a half-span model of a lightweight figher aircraft. This marked the confluence of several technologies with active flutter suppression, digital control and adaptive control theory the primary contributors. The control algorithm was required to adapt both to slowly varying changes, corresponding to changes in the flight condition or fuel loading and to rapid changes, corresponding to a store release or the transition from a stable to an unstable flight condition. The development of the adaptive control methods was followed by a simulation and checkout of the complete system and a wind tunnel demonstration. As part of the test, a store was released from the model wing tip, transforming the model abruptly from a stable configuration to a violent flutter condition. The adaptive algorithm recognized the unstable nature of the resulting configuration and implemented a stabilizing control law in a fraction of a second. The algorithm was also shown to provide system stability over a range of wind tunnel Mach numbers and dynamic pressures.

Johnson, E. H.↗

Wind tunnel test of a fighter aircraft wing/store flutter suppression system: An international effort

A 30% scale, half span model of a lightweight fighter aircraft with an active wing/store flutter suppression system was tested in the NASA Langley Research Center sixteen foot transonic dynamics tunnel. The test featured a store configuration that was intentionally designed to exhibit a violent flutter condition. In addition to Northrop organized control laws, three European countries also contributed control laws to stabilize this condition. After the control laws were mechanized by Northrop, they were tested at the Langley facility. The model was tested up to 170% of the open loop flutter dynamic pressure in a number of cases, with the indication that a substantially greater improvement was achievable. Some special features of the test model are discussed and the design and implementation of the control laws as well as the test monitoring techniques and results are presented.

Hwang, C.↗

Demonstration of aircraft wing/store flutter suppression systems

A wind tunnel test program was conducted to demonstrate the active wing/store flutter suppression systems on a lightweight fighter aircraft. The program, completed in mid-1978, included the design, analysis, fabrication, and testing of a scale model. The tests were conducted at the NASA Langley 16-ft Transonic Dynamics Tunnel. Three store configurations were selected for testing. Two of these configurations were deliberately designed to exhibit low flutter speeds with rapid reductions in damping at the incipient flutter condition. After initial tunnel entries, which showed the need for certain improvements in the model and the control system design, substantial increases in the flutter speeds were achieved using both leading- and trailing-edge control surfaces, separately. For the most critical configuration, a demonstrated improvement of 18% and a projected improvement of 29% in the dynamic pressure were achieved.

Hwang, C.↗

Some observations on the mechanism of aircraft wing rock

A scale model of the Northrop F-5A was tested in NASA Ames Research Center Eleven-Foot Transonic Tunnel to simulate the wing rock oscillations in a transonic maneuver. For this purpose, a flexible model support device was designed and fabricated, which allowed the model to oscillate in roll at the scaled wing rock frequency. Two tunnel entries were performed to acquire the pressure (steady state and fluctuating) and response data when the model was held fixed and when it was excited by flow to oscillate in roll. Based on these data, a limit cycle mechanism was identified, which supplied energy to the aircraft model and caused the Dutch roll type oscillations, commonly called wing rock. The major origin of the fluctuating pressures that contributed to the limit cycle was traced to the wing surface leading edge stall and the subsequent lift recovery. For typical wing rock oscillations, the energy balance between the pressure work input and the energy consumed by the model's aerodynamic and mechanical damping was formulated and numerical data presented.

Hwang, C.↗