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J I Simon

Publications and source records attributed to J I Simon.

36 records · Page 2

A Mars 2020 Perseverance SuperCam Perspective on the Igneous Nature of the Máaz Formation at Jezero Crater, Mars

The Mars2020 Perseverance rover landed in Jezero crater in February 2020,and first encountered the Máaz formation (or Crater floor-fractured rough(Cf-fr) unit previously mapped based on orbital data[1]).In this study, we use data from the SuperCam instrument(SCAM) to show that the Máaz formation has an igneous origin. SuperCam is a remote-sensing instrument onboard Perseverance, and investigates the texture, mineralogy, and chemistry of rocks and soils, as well as atmospheric features [2,3]. SuperCam comprises the Remote Micro Imager (RMI) to provide high-resolution images, laser-induced breakdown spectroscopy (LIBS)to investigate the major and minor element chemistry of materials, Raman, and passive visible-near infrared (VISIR) spectroscopy to analyze the mineralogy of targets, and time-resolved luminescence spectroscopy (TRLS)to measure organic fluorescence and inorganic luminescence. In addition, the microphone (MIC) can constrain the rock hardness through measurements of the shockwave of LIBS shots. In this study, we use LIBS-based major-oxide compositions (MOC),quantified using the calibration in [2].

Mars 2020↗

Oxygen Isotopic Composition of Refractory Inclusions from the Miller Range (MIL) 090019 Carbonaceous Chondrite

Introduction: Primitive meteorites contain Calcium-Aluminum-rich Inclusions (CAIs)that preserve the records of the earliest times in the Solar System. CAIs record O isotopic variations with time and/or location from solar (16O-rich) to planetary (16O-poor) compositions [e.g., 1, 2].However, CAIs were also affected by parent body processing to varying degrees. The goal of this work was to identify the processes that resulted in the fine-scale spatial variations in oxygen isotopic compositions within the most ancient Solar System solids. We report oxygen isotopic composition of CAIs from MIL 090019 CO3.1 carbonaceous chondrite. MIL 090019 contains a high abundance of CAIs showing mineralogical as well as textural variations [3]. Methods: We analyzed 10 CAIs with different mineralogical assemblages, classified as corundum-bearing, grossite-bearing, hibonite-bearing, melilite-bearing, anorthite-bearing inclusions and amoeboid olivine aggregates(AOA’s). The mineralogical and petrological characterization of CAIs was performed using the JOEL Hyperprobe 8530 electron microprobe at NASA JSC. Oxygen isotopic imaging of the CAIs was done using the Cameca NanoSIMS 50L ion microprobe at NASA JSC. We followed the analytical protocol described in [4]. O-isotopic maps of the CAI were acquired by rastering a ~3 pA primary Cs+beam at 16 keVover an area of 20 ×20μm2over a period of ~7 hours. Negative secondary ions of 16O−, 17O−, 18O−, 28Si−, 24Mg16O−, 27Al16O−, and 40Ca16O−were simultaneously acquired using electron multiplier detectors at a mass resolving power sufficient to resolve the 16OH−interference from the 17O−peak, where the contribution of 16OH−was <0.1%.An electron flood gun was used to mitigate sample charging during the analyses. We used San Carlos olivine and Madagascar hibonite as isotopic standards to correct for the instrumental mass fractionation. The O-isotopic ratios were corrected for the quasi simultaneous arrival (QSA) effect and the detector dead time. All reported errors are 1 sigma. Results: The MIL 090019 carbonaceous chondrite hosts refractory inclusions varying in their mineralogies and textures[2, 3]. We found the oxygen isotopic compositions of mineral phases in MIL 090019 CAIs show large variations with Δ17O values varying from -27 to 0‰. A corundum-bearing inclusion records isotopic variations with corundum, melilite, perovskite, and anorthite showing Δ17Ovalues of -20 ±2.5, -10.2 ± 6.5, -10.7 ± 1.3,and -1.2 ± 3.2‰ respectively. A grossite-hibonite-bearing inclusion also records O-isotopic heterogeneity, where grossite, hibonite, Mg-rich spinel, and melilite show -3.7 ± 2.7, -22.9 ± 2.5, -21.4 ± 2.6, and -17.3 ± 2.8‰ respectively, whereas perovskite grains record a heterogenous isotopic composition ranging from -22.6 to -13.9‰. A hibonite-bearing inclusion shows average Δ17Ο values of -17.6 ± 5.3 ‰ and -15.1 ± 4.8 ‰ for hibonite and spinel respectively. The two perovskite grains also show relatively 16O-poor composition (Δ17Ο = -11.8 ± 6.4 ‰ and -8.6 ± 5.2 ‰). Anorthite has ~0.1 wt% Na2O and ~0.52 wt% FeO and a Δ17Ο value of -7.2 ± 5.0 ‰, whereas diopside records a Δ17Ο value of -3.5 ± 5.0 ‰. A hibonite-spinel-rich inclusion contains spinel and hibonite that are16O-rich (Δ17Οvalues -21.3 ± 2.8‰ and -19.4 ± 3.0‰, respectively). Melilite shows heterogenous oxygen isotopic composition, with an inner 16O-rich region and an outer 16O-poor region separated by a sharp boundary, with a bulk Δ17Ο= -16.2 ± 2.1‰, whereas two perovskite grains are relatively 16O-poor (Δ17Ο= -13.2 ± 3.7‰ and -7.1 ± 3.4‰).A spinel-rich inclusion contains perovskite grains with Δ17Οranging from -27.0 to -22.8 ‰and spinel with average Δ17Οvalue of -21.4 ± 2.8 ‰. In a melilite and spinel-rich CAI, perovskite, spinel, diopside, melilite, and Al-Ti-rich pyroxene record Δ17Ο values of-26.9 ± 4.6‰, -22.4 ± 4.3‰,-23.4 ± 4.9, -19.3 ± 3.4, and -19.0 ± 4.3 ‰ respectively. Olivine and spinel components of 2 AOA’s record a 16O-rich composition with Δ17O~-23‰. Discussion: The coexistence of 16O-rich and 16O-poor minerals within CAIs has been attributed to differing degrees of O isotopic exchange, reflecting a wide range of O diffusion rates[5]. However, the O isotopic heterogeneity observed in these CAIs cannot be explained by oxygen diffusion in nebular or parent body settings alone. The isotopic imaging of CAIs from the MIL 090019 meteorite shows variations in the O isotopic composition recorded in their mineral components, suggesting that these CAIs record the oxygen isotopic heterogeneity in the nebular gas from which they condensed. The coexistence of 16O-rich and 16O-poor mineral components in the CAI-forming region suggests that the gas in this region was not well-mixed and consisted of distinct 16O-rich and 16O-poor gaseous reservoirs.

P Mane↗

The NASA Facility for Astromaterials Research at the Johnson Space Center – A National Laboratory for Planetary Research

The Astromaterials Research and Exploration Science (ARES) Division at the NASA Johnson Space Center houses a unique combination of laboratories, instruments, infrastructure, technical ex-pertise, and other assets for conducting broad-based world-class planetary research. These facilities have been accessed for decades by hundreds of external scientists, including faculty, post-docs, students, and interns, most at no cost and on a collaborative basis. With funding through NASA’s Planetary Science Enabling Facilities (PSEF) program, we have estab-lished the NASA Facility for Astromaterials Research (NFAR) to expand access to and enhance these labora-tories for a diverse and inclusive external user base, thus maximizing the science return from research funded by R&A programs in NASA’s Planetary Sci-ence Division (PSD). NFAR enables cutting edge planetary sample analyses, making new scientific dis-coveries possible, in addition to training the next-generation of planetary scientists. NFAR laboratories are co-located with JSC Curation that houses all NASA-controlled astromaterials collections, thus ena-bling direct access to both research and curation exper-tise, to facilitate specialized sample handling and anal-ysis of allocated samples (from JSC and other sample collections) to PIs, particularly those affiliated with institutions that historically have limited or no access to in-house analytical or experimental facilities.

J Filiberto↗

Trace Elemental Abundances in Calcium-Aluminum-Rich Inclusions in CV Chondrites

Introduction: Calcium-aluminum-rich inclusions (CAIs), are the first formed solids that define the age of the Solar System [1,2]. CAIs are thought to have condensed from nebular gas [3,4] within the first <1 Ma of Solar System formation [5,6]. CAIs have experienced numerous early Solar System processes including condensation, evaporation, melting, recrystallization, and aqueous alteration [e.g., 7]. The chemical, mineralogical, and textural diversity among CAIs results from a range of chemical and physical processes recorded during nebular and parent body epoch. This study aims to explore the mineralogical, textural, and chemical compositions of CAIs including the trace elemental abundances in CAI phases to determine the early Solar System processes recorded in them. Samples and Analytical Methods: We analyzed one CAI each from CV3 chondrites Northwest Africa (NWA) 5508 designated as ‘Saguaro’, and Northwest Africa (NWA) 12772 designated as ‘Hoopoe’. Back-scatter electron (BSE) images were collected using a Phenom XL scanning electron microscope (SEM) at the Lunar and Planetary Institute (LPI) and the JEOL JXA-8530F electron probe microanalyzer (EPMA) at Johnson Space Center (JSC)-NASA. Additionally, energy dispersive X-ray spectrometry (EDS) elemental maps of select areas for these samples were collected using a 15.0kV beam energy and a 40µA emission current. Using the EPMA, wavelength-dispersive X-ray spectroscopy (WDS) quantitative data were collected. In-situ trace element measurements for both CAIs were determined at JSC-NASA using a Photon Machines 193nm laser ablation system and a Thermo-Scientific Element-XR inductively coupled plasma mass spectrometer (ICP-MS). Analyses consisted of 30s ablations at 10Hz, spot sizes of 20-25µm, and a fluence of 6.0 J/cm2 for anorthite and melilite, and a 3.5 J/cm2 fluence for all other phases. NIST612 was used to correct for instrument drift, while BHVO-2g was used as a primary calibration standard. BCR-2g and in-house mineral standards were regularly measured as unknowns to ensure accuracy. Results: Saguaro is a coarse-grained CAI, ~11 x 6 mm in dimensions. Saguaro contains spinel, Al-rich pyroxene, anorthite, Mg-rich melilite, and minor perovskite in its interior and is therefore classified as a Type B CAI. Individual melilite grains shows normal compositional zoning with an Ak content ranging from ~24 to 54 with no apparent trend from the core to the edge of the CAI. The spinel appears euhedral and occurs both as clusters and as spinel palisades [8]. Two rim sequences surround most of the sample: the inner rim being a Wark-Lovering (WL) rim (~10-35 µm) containing pyroxene, spinel, and melilite (or anorthite), and the outer rim is a finer-grained, thicker (~100 µm), accretionary rim (Fig. 1). The mineral phases in Saguaro record an overall flat REE pattern with an average negative Eu anomaly in pyroxene, and an average positive Eu anomaly in anorthite and melilite respectively. Anorthite, melilite, and pyroxene have a minor depletion in Tm (Fig. 2). The Hoopoe CAI is a compact, coarse-grained ~6 × 4 mm in size. The major mineralogy includes hibonite, spinel, melilite, anorthite, and perovskite. Therefore, it is classified as a compact transitional type A and B. (?)zoning was observed in some hibonites. Individual melilite grains show both reverse and normal zoning, where the Ak content ranges from ~6- to 28. Melilite shows two distinct textures. One texture consisted of smooth melilite that appeared homogenous, while the second appeared to consist of many fine fractures. The spinel also often appears clustered. The WL-rim sequence surrounding Hoopoe is ~25 µm thick and composed of spinel, perovskite, hibonite, and melilite/anorthite. It is then partially surrounded by an outer accretionary rim (~75µm). Like before, refractory metal nuggets appeared concentrated near the WL rims. Other metal assemblages rich in Fe and Ni were also observed. All major mineral phases in Hoopoe display relatively flat REE patterns, except for varying Eu and Tm between phases (Fig. 2). There is a prominent negative Eu anomaly in perovskite and an average positive Eu anomaly in spinel, anorthite, and hibonite respectively (Fig. 2, 3). The mixed phases along the rim of the CAI also display a negative Eu anomaly, and all phases the CAI were depleted in Pb. Discussion: The CV3 CAIs analyzed in this study were classified based on their mineralogy and textures into Type A versus Type B CAIs [10]. Hibonite appears to be pseudomorphically replacing the spinel, (i.e., is hibonite in composition, but appears in the shape of spinel). Spinel palisades. The presence of spinel palisades present in Saguaro are consistent with the melting and recrystallization experienced by this CAI. Trace elemental analyses. Saguaro and Hoopoe display similar trace element patterns to each other, with both appearing generally flat, with anomalies in Eu, and Tm. Melilite and anorthite display positive Eu anomalies in both CAIs, in addition to the hibonite in Hoopoe (Fig. 2). The phases that are depleted in Eu are pyroxene and perovskite in both Saguaro and Hoopoe, respectively (Fig. 3). Given that Eu is volatile in reducing environments [11], this could possibly indicate reducing conditions at the time anorthite and melilite crystallized, with the gas they formed from containing Eu. As these CAIs continued to form, this gas as a result would become depleted in Eu. This also could be supported by the propensity of anorthite and melilite to take up Eu from its surroundings and incorporate it into their structure [12]. In addition, analyzing the assemblage of the phases in the Saguaro, melilite and anorthite (Eu enriched) often surround the pyroxene (Eu depleted) as they are crystallized. This intergrowth of phases and the proximity of the phases would support that the Eu is being incorporated into some phases, preventing it from incorporating into other. Trace elemental analyses of the CAI rims will be evaluated in more detail, as they are complicated by the transient signal being composed of a mixture of mineral phases. Broadly, however, the patterns in the rims of both CAIs are comparable to each other, and for Hoopoe, to the mixed phase patterns in the core (Fig. 3). Other studies have found that CAI rims can be depleted in Ce and Yb [13], however we did not observe these anomalies in the two CAIs discussed here. Given their similarity, the trace elemental analyses of the mixed interior (i.e. core) and rim phases could be interpreted as forming from similar, if not the same, reservoirs. The REE abundance between the rim and core of Hoopoe are also similar, indicating they may have formed from a gas of the same or similar composition. Acknowledgments: We thank the ASU Center for Meteorite Studies for loaning the samples used in this work and Tabb Prissel for his assistance with the analysis. Mouti Al-Hashimi thanks Sam Crossley and Cyrena Goodrich for their help with the LPI SEM training. This work was supported by the LPI Summer Intern Program in Planetary Science and the LPI Cooperative Agreement. References: [1] Connelly J.N. (2012) Science, 338, 651-655. [2] MacPherson G. J. (2014) Treatise on Geochem., 2, 139-179. [3] Grossman L. (1972) GCA, 36, 597-619. [4] Ebel, D.S. (2006) Meteorites and the Early Solar System II (D. S. Lauretta & H. Y. McSween, Eds.) 253-277. [5] MacPherson G. J. (2012) Earth Planet. Sci. Lett., 331-332, 43-54. [6] MacPherson G.J. (2017) GCA, 201, 65-82. [7] Krot A.N. (1995) Meteoritics & Planet. Sci., 30, 748-775. [8] Wark and Lovering (1982) GCA, 46, 2595-2607. [9] Palme H. and Jones A. (2003) Treatise on Geochemistry (H. D. Holland and K. K. Turekian Eds.), 1, 41-61. [10] Grossman L. (1980) Ann. Rev. Earth Planet. Sci., 8, 559-608. [11] Floss C. et al. (1996) GCA, 60, 1975-1997. [12] Mason B. and Martin P. M. (1974) Earth Planet. Sci. Lett., 22, 141-144. [13] Wark B. and Boynton W. V. (2001) Meteoritics & Planet. Sci., 36, 1135-1166.

X Mouti↗

Provenance of Sediments in the Jezero Delta From Perseverance Rover and Orbital Observations.

The Perseverance rover is exploring an ancient delta in Jezero crater to search for potential biosignatures and collect samples for return to Earth by Mars Sample Return [1]. Understanding the source (provenance) of the sediments and how it changes in the delta stratigraphy will be important for developing hypotheses for the origin and transport history of potential biosignatures, will help constrain the evolution of the delta and watershed through time, and will enable us to identify the origin of detrital grains from outside Jezero in sandstones and conglomerate samples collected by Perseverance. In this study, we constrain the provenance of delta sediments by studying the distribution of primary mafic minerals detected using spectroscopy at rover and orbital scales.

B Horgan↗

Early History of the Solar System Revealed By Calcium-48 Heterogeneity in Calcium-Aluminium-Rich Inclusions

Introduction: Calcium-aluminum-rich inclusions (CAIs) are the earliest formed solids in the solar system. Although the mineralogy of CAIs is consistent with condensation from a solar composition gas, textural, elemental and isotopic signatures point to CAIs having more complicated thermal histories rather than simply being primary condensates. Untangling the condensation record in these refractory inclusions and the associated physicochemical environment, can provide insights into temporal and/or spatial reservoirs in the protoplanetary disk where solids were forming.

R M G Armytage↗

Tracing Nebular Reservoirs and Processes Via In-situ Trace Element Analyses of Chondrule Rims in Allende

Introduction: Layered rims of dust-sized material surround some chondrules and other early formed nebular particles, such as calcium aluminum inclusions in chondritic meteorites. Most chondrules (~85%) in the Allende meteorite (CV3) are un-rimmed and in direct contact with the host material or matrix. For the 15% of rimmed particles, rim thickness is correlated to the underlying particle size, arguing for pre-parent body formation of rimmed particles as they traversed distinct (cooler and/or dustier) nebular environments. Nebular rim formation involves accretion of unequilibrated dust to chondrule surfaces, recording evidence for the formation of at least two separate particle populations (chondrules and dust) that interacted in the nebula, and therefore potentially record distinct nebular reservoirs.

J B Setera↗

Pristine Pyroxene-Bearing Boulders Analyzed By Supercam in the Jezero Western Fan, Mars

During its exploration of the upper surface of the Jezero western fan, the Mars 2020 Perseverance rover encountered a population of boulders that likely represents a late-stage deposit from high-energy floods. These boulders can be divided into two groups based on their inferred mineralogy: olivine-rich and pyroxene-bearing. The first group, the most abundant one, is described in ref.[2]. Here, we present the analyses performed by the SuperCam instrument on the pyroxene-bearing boulders and show that they are among the most pristine rocks encountered so far in the mission. We also draw a comparison with the Boston Knob outcrop, located on the fan front, which may be a buried and stratigraphically lower equivalent of the pyroxene-bearing boulders of the upper fan.

Mars 2020↗

Field Geologic Mapping of Sample Sites From the Ground and the Air With Perseverance Rover and Ingenuity Helicopter

One of the primary mission goals for Perseverance is to determine the geologic context of sample sites. Rover-based (in situ) or field geologic context mapping (GXM) based on Perseverance rover and Ingenuity helicopter observations provides a nearly continuous record of geologic context and exposed surface structure over a 120 m-wide corridor along the traverse of Perseverance and the flight path of Ingenuity. Field geologic mapping along the traverse and flight path and outcrop-scale mapping at sample sites provides a spatial dimension to ground truth geologic, stratigraphic, and modern environmental context for samples at scales relevant to sample interpretation. Here we provide an abbreviated overview of field mapping as it relates to documenting the architecture of the Jezero fan and geologic context of several examples of sample locations.

Mars 2020↗

Chemistry and Mineralogy of the Margin Unit, Jezero Crater, Mars, Observed By M2020 / Supercam

The Margin Unit of Jezero crater, Mars, was identified from orbit as one of the most carbonate-rich regions of the planet [e.g., 1,2]. Its presence, along with the adjacent fluvial delta [e.g., 3] made Jezero crater the most compelling landing site for the Mars 2020 mission. Investigation of Jezero’s Margin-Unit carbonates provides a unique opportunity to address the formation of carbonates in sedimentary deposits, possibly under a CO 2 -rich martian atmosphere. Here we report on chemistry and mineralogy of 55 targets observed by the multi-technique SuperCam instrument during Perseverance’s crater-margin campaign.

Mars 2020↗

Viscosity and Flow Properties of the Seitah Olivine-Rich Lithology

One of the most surprising findings of the Perseverance rover was the discovery of olivine cumulate in the Séítah region [1]. The rover landed and traversed to the Séítah region and collected measurements at three workspaces: Bastide, Brac and Issole (Fig 1). Here we use the SuperCam VISIR and LIBS to investigate the properties of the lithology insitu and determine two things: 1) the olivine-clay-carbonate regional lithology is low in Al3+, which allows us to eliminate the possibility of clays which are high in Al3+, 2) the viscosity of the Séítah formation is extremely low, which is a reasonable explanation for the Séítah unit to both cumulate and thin-layered (Fig 1b).

Mars 2020↗

Astrobiological Potential of Rocks Acquired By the Perseverance Rover at the Front of the Western Sediment Fan in Jezero Crater, Mars.

Major objectives of the Perseverance rover mission include identifying past habitable environments, collecting rocks that are likely to preserve biosignatures and using the rover’s instruments to look for potential biosignatures in these rocks. The recognition of the > 3.5 billion-year old habitable environments in Jezero crater, Mars (Fig. 1); promised that the mission could achieve these objectives. The western sedimentary fan deposit, the hydrated minerals therein and the carbonate minerals at the margin of this fan were identified as particularly compelling areas in which to search for the signs of past life and collect the oldest aqueously deposited rocks from another planet.

Mars 2020↗

The Scientific Significance of Potential Samples From the Jezero Crater Rim

The Mars 2020 Perseverance rover has been exploring Jezero crater, Mars to characterize the geology,assess the potential for rocks to represent ancient habitable environments and/or preserve biosignatures, and collect a suite of scientifically compelling samples for return to Earth (Farleyet al.,2020).Thus far, Perseverance has collected samples that represent the diversity of igneous materials encountered on the crater floor and a suite of aqueously deposited sedimentary rocks from the fanand margin units(Simon et al., 2023; Bosak et al., 2024). When the rover ascendsthe crater rimit will encounter rocktypesthat are not included in the current sample cache. These include rocks fromthe Noachian whose mineralogical, geochemical, and geochronological recordswould greatly expand our understanding of early Mars. Some of the exposures are understood to come from subsurface aquifers that may represent the most ancient potentially habitablesubsurfaceenvironmentson Mars(Ehlmann et al., 2024). Samples ofthese rocks will add uniquescientific value tothe sample cache and to the Mars sample returnprogramby addressing outstanding questions in Mars science including potential habitability and how the climate and the interior of the planet evolved through time.

Mars 2020↗