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Jacobsen, S. B.

Publications and source records attributed to Jacobsen, S. B..

Magnesium and Silicon Isotopes in HASP Glasses from Apollo 16 Lunar Soil 61241

The high-Al (>28 wt %), silica-poor (<45 wt %) (HASP) feldspathic glasses of Apollo 16 are widely regarded as the evaporative residues of impacts in the lunar regolith [1-3]. By virtue of their small size, apparent homogeneity, and high inferred formation temperatures, the HASP glasses appear to be good samples in which to study fractionation processes that may accompany open system evaporation. Calculations suggest that HASP glasses with present-day Al2O3 concentrations of up to 40 wt% may have lost 19 wt% of their original masses, calculated as the oxides of iron and silicon, via evaporation [4]. We report Mg and Si isotope abundances in 10 HASP glasses and 2 impact-glass spherules from a 64-105 m grain-size fraction taken from Apollo 16 soil sample 61241.

Herzog, G. F.

Magnetic Fe, Si, Al-Rich Impact Spherules from the P-T Boundary Layer at Graphite Peak, Antarctica

The geological boundary between Triassic and Permian strata coincides with the greatest life extinction in the Earth's history. Although the cause of the extinction is still the subject of intense debates, recent discoveries in the P-T boundary layer of shocked quartz grains, fullerenes with the extraterrestrial noble gases, Fe metal nuggets, and chondritic meteorite fragments all point to a powerful collision of Earth with a celestial body in the late Permian. Here we report the discovery of magnetic Fe, Si, Al-rich impact spherules which accompany the chondritic meteorite fragments in some samples from the P-T boundary layer at Graphite Peak, Antarctica.

Petaev, M. I.

Core-Formation Models and Extinct Nuclides

Zr and W isotope data are consistent with the Earth's core forming in a single event subsequent to about 113 Ma after the formation of the solar system. With continuous models of core formation the process can start early. Additional information is contained in the original extended abstract.

Jacobsen, S. B.

Integrated chronostratigraphy of Proterozoic-Cambrian boundary beds in the western Anabar region, northern Siberia

Carbonate-rich sedimentary rocks of the western Anabar region, northern Siberia, preserve an exceptional record of evolutionary and biogeochemical events near the Proterozoic/Cambrian boundary. Sedimentologically, the boundary succession can be divided into three sequences representing successive episodes of late transgressive to early highstand deposition; four parasequences are recognized in the sequence corresponding lithostratigraphically to the Manykal Formation. Small shelly fossils are abundant and include many taxa that also occur in standard sections of southeastern Siberia. Despite this coincidence of faunal elements, biostratigraphic correlations between the two regions have been controversial because numerous species that first appear at or immediately above the basal Tommotian boundary in southeastern sections have first appearances scattered through more than thirty metres of section in the western Anabar. Carbon- and Sr-isotopic data on petrographically and geochemically screened samples collected at one- to two-metre intervals in a section along the Kotuikan River, favour correlation of the Staraya Reckha Formation and most of the overlying Manykai Formation with sub-Tommotian carbonates in southeastern Siberia. In contrast, isotopic data suggest that the uppermost Manykai Formation and the basal 26 m of the unconformably overlying Medvezhya Formation may have no equivalent in the southeast; they appear to provide a sedimentary and palaeontological record of an evolutionarily significant time interval represented in southeastern Siberia only by the sub-Tommotian unconformity. Correlations with radiometrically dated horizons in the Olenek and Kharaulakh regions of northern Siberia suggest that this interval lasted approximately three to six million years, during which essentially all 'basal Tommotian' small shelly fossils evolved.

Non-NASA Center

REE chemistry and Sm-Nd systematics of late Archean weathering profiles in the Fortescue Group, Western Australia

Two weathering profiles, each consisting of an upper, sericite-rich zone and a lower, chlorite-rich zone, are preserved between flows of the Mt. Roe Basalt in the Fortescue Group, Hamersley Basin, Western Australia. REE concentrations in samples from these two profiles, which originally developed ca 2,760 Ma, show large variations depending on stratigraphic position. LREE abundances and (La/Yb)N are greatest at depths of 3-6 m below the paleosurface of the Mt. Roe #1 profile and are somewhat lower in samples above this level. The LREEs reach concentrations 6-9 times greater than in the underlying basalt, and thus appear to have been mobilized downward in the paleosol and concentrated in its middle part. LREE concentrations in the #2 profile show a similar distribution but with a sharp increase in all REE concentrations within 50 cm of the paleosurface. The distinction between the REE profiles in the two paleosols may be related to the difference in the overlying material. The #1 paleosol is overlain by a few meters of sediments and then by basalt, whereas the #2 paleosol is directly overlain by basalt. The LREEs appear to have been mobilized both during chemical weathering of the parental basalt and during later lower-greenschist-facies metamorphism and metasomatism of the paleosols. Remobilization of the REEs during the regional metamorphism of the Fortescue Group is confirmed by a whole-rock Sm-Nd reference isochron of Mt. Roe #1 samples with an age of 2,151 +/- 360 Ma. Variable initial 143Nd/144Nd values of unweathered basalt samples which may represent the paleosol protolith prevents a confident determination of the magnitude of LREE mobility. Both the initial mobilization of the REEs during weathering and the metasomatic remobilization appear to have taken place under redox conditions where Ce was present dominantly as Ce3+, because Ce anomalies are not developed within the sericite zone samples regardless of concentration. Europium anomalies in the paleoweathering profile are somewhat variable and were probably modified by mobilization of Eu2+ at metamorphic conditions. In all samples, the HREEs appear to have been relatively immobile and correlate with Al, Ti, Cr, V, Zr, and Nb. Sm-Nd systematics and REE patterns of four unweathered basalt samples indicate derivation of the Mt. Roe Basalts from a heterogeneous and enriched source having epsilon Nd between -4.0 and -7.4. Initial 143Nd/144Nd values of these basalts are even lower than those reported by NELSON et al. (1992) for Fortescue Group basalts and indicate a substantial crustal component in the generation of Mt. Roe Basalts.

NASA Discipline Exobiology

Nd-142/Nd-144 in bulk planetary reservoirs, the problem of incomplete mixing of interstellar components and significance of very high precision Nd-145/Nd-144 measurements

Apart from the challenge of very high precision Nd-142/Nd-144 ratio measurement, accurate applications of the coupled Sm-(146,147)-Nd-(142,143) systematics in planetary differentiation studies require very precise knowledge of the present-day (post-Sm-146 decay) Nd-142/Nd-144 ratios of bulk planetary objects (BP). The coupled systematics yield model ages for the time of formation of Sm/Nd-fractionated reservoirs by differentiation of Sm/Nd-unfractionated bulk planetary reservoirs. Estimates of (Nd-142/Nd-144)(sub BP) and (Nd-143/Nd-144)(sub BP) therefore provide the critical baseline relative to which these model ages are referenced. In the Sm-147-Nd-143 systematics, Nd-143/Nd-144 variations are mostly large; therefore, small variations in initial Nd-143/Nd-144 ratios generally can be ignored. However, in the case of Sm-146-Nd-142, the range of Nd-142/Nd-144 divergence for differentiated planetary reservoirs is much smaller. Consequently Sm-(146,147)-Nd-(142,143) model ages are sensitive to small variations in bulk planetary Nd-142/Nd-144 (both present-day and initial). One major unanswered question is whether or not Nd shelf standards (CIT Nd beta/Ames metal, La Jolla, NASA-JSC/Ames metal) have Nd-142/Nd-144 identical to the bulk Earth or otherwise might record some degree of radiogenic evolution in an early-fractionated reservoir. Our discussions of earth Earth differentiation based on Nd-142/Nd-144 in Isua and Acasta samples have employed a working assumption: (Nd-142/Nd-144)(sub Nd beta) = (Nd-142/Nd-144)(sub Bulk Earth). This requires experimental justification and is apparently contradicted by chondrite Nd-142/Nd-144 measurements, which have been interpreted to indicate: (Nd-142/Nd-144)(sub JSC/Ames metal) = ((Nd-142/Nd-144)(sub CHUR) = 35 plus or minus 8 ppm). At present, interpretations of the early Earth and Moon hinge largely on this issue. Because Ba in bulk chondrite samples exhibit similar magnitude nuclear anomalies, attributable to incomplete mixing of interstellar components, a critical question is whether or not nuclear effects are also present in Nd-142/Nd-144, both in bulk chondrites and between planetary objects.

Harper, C. L., Jr.

Constraints on the differentiation of the Earth from the coupled Sm-146,147-Nd-142,143 systematics

The coupled Sm-Nd systematics are a powerful (albeit analytically challenging) tool for investigating the geodynamic history of the Earth. We have previously reported evidence for a 33 ppm difference of an Isua sample relative to our terrestrial standard. Interpretation yields a formation age range for the depleted mantle (DM) source reservoir of 4.45-4.55 Ga. This is consistent with an epoch of LREE-enriched melt extraction from the mantle (proto-crust formation), soon after magma ocean freeze-up following the putative Moon forming giant impact.

Jacobsen, S. B.

A Nd and Sr isotopic study of the Trinity peridotite Implications for mantle evolution

Field evidence is reported which indicates that the Trinity peridotite in Northern California was partially melted during its rise as part of the upwelling convecting mantle at a spreading center. A Sm-Nd mineral isochron for a plagioclase Iherzolite yielded an age of about 427 Ma which is significantly higher than that expected for depleted mantle during this period. The age is interpreted as the time of crystallization of trapped melt in the plagioclase Iherzolite P-T field, and probably represents the time when the massif was incorporated as a part of the oceanic lithosphere. The Sm-Nd model age of the plagioclase Iherzolite total rock is 3.4 AE. This suggests that the peridotite was derived from a mantle that was depleted early in earth history. Although most available data indicate that the depleted upper mantle has been relatively well stirred through time, the Trinity data suggest that very ancient Nd isotropic values are preserved and chemical and physical heterogeneities are sometimes preserved in the depleted source of midocean ridge basalts as well as the oceanic lithosphere which they intrude.

Jacobsen, S. B.

Sm-Nd isotopic evolution of chondrites and achondrites. II

The chondrite data obtained as a result of an investigation of Sm-147-Nd-143 and Sm-146-Nd142 isotope systematics in five chondrites and the Moama and Andra dos Reis (ADOR) achondrites are consistent with previously reported reference values for the chondritic uniform reservoir (CHUR) of 0.511847 and 0.1967. The Nd-143/Nd-144 and Sm-147/Nd-144 values of the bulk chondrites analyzed suggest that the CHUR evolution is known to within 0.5 epsilon-units and 0.15 percent of the CHUR values for the entire history of the solar system. The Sm-146-Nd-142 systematics of ADOR and Moama support the hypothesis that Sm-146 was present in the early solar system, suggesting a high Sm-146/Sm-144 ratio that cannot be explained as a late injection forma supernova, and must instead be due to galactic nucleosynthesis.

Jacobsen, S. B.

Sm-Nd isotopic evolution of chondrites

The Nd-143/Nd-144 and Sm-147/Nd-144 ratios measured in 5 chondrites and the Juvinas achondrite correlated with the variation of 4.2% in Sm-147/Nd-144. Most of the spread in the range of these ratios results from small heterogeneities in the chondrites and does not reflect the large-scale volumetric averages. A new set of self-consistent reference values were selected for the 'chrondritic uniform reservoir' (CHUR); the new Sm-147/Nd-144 value is 1.6% higher than the previous value assigned to CHUR using the Juvinas data of Lugmair (1975). The new CHUR curve indicates significant changes in model ages for lunar rocks and in the interpretation of early lunar chronology.

Jacobsen, S. B.

The mean age of mantle and crustal reservoirs

An analysis of two transport models for trace elements in mantle and crust evolution and related to the observed abundance patterns. In model I, continents are derived by melt extraction over the earth history from undepleted mantle, and the residue forms a depleted mantle which is the current source of mid-ocean ridge basalts. In model II, new additions to continents are derived from a mantle reservoir 2, which becomes more depleted by repeated extraction of melts. The isotopic composition and concentrations of trace elements are shown to reduce to simple mathematical expressions which permit calculations of basic evolutionary parameters. The mean age of the crust mass and isotopic data for the continental crust and the mantle are discussed, concluding with a consideration of their difference in compositions of newly derived crust.

Jacobsen, S. B.