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Jaworske, Donald A.

Publications and source records attributed to Jaworske, Donald A..

65 records · Page 4

Atomic Oxygen Durability of Second Surface Silver Microsheet Glass Concentrators

Second surface silver microsheet glass concentrators are being developed for potential use in future solar dynamic space power systems. Traditional concentrators are aluminum honeycomb sandwich composites with either aluminum or graphite epoxy face sheets, where a reflective aluminum layer is deposited onto an organic leveling layer on the face sheet. To protect the underlying layers, a SiO2 layer is applied on top of the aluminum reflective layer. These concentrators may be vulnerable to atomic oxygen degradation due to possible atomic oxygen attack of the organic layers at defect sites in the protective and reflective coatings. A second surface microsheet glass concentrator would be inherently more atomic oxygen durable than these first surface concentrators. In addition, a second surface microsheet glass concentrator design provides a smooth optical surface and allows for silver to be used as a reflective layer, which would improve the reflectivity of the concentrator and the performance of the system. A potential threat to the performance of second surface microsheet glass concentrators is atomic oxygen attack of the underlying silver at seams and edges or at micrometeoroid and debris (MMD) impacts sites. Second surface silver microsheet glass concentrator samples were fabricated and tested for atomic oxygen durability. The samples were iteratively exposed to an atomic oxygen environment in a plasma asher. Samples were evaluated for potential degradation at fabrication seams, simulated MMD impact sites, and edges. Optical microscopy was used to evaluate atomic oxygen degradation. Reflectance was obtained for an impacted sample prior to and after atomic oxygen exposure. After an initial atomic oxygen exposure to an effective fluence of approx. 1 x 10(exp 21) atoms/cm(exp 2), oxidation of the silver at defect sites and edges was observed. Exposure to an additional approx. 1 x 10(exp 21) atoms/cm(exp 2) caused no observed increase in oxidation. Oxidation at an impact site caused negligible changes in reflectance. In all cases oxidation was found to be confined to the vicinity of the seams, impact sites, edges or defect sites. Asher to in-space atomic oxygen correlation issues will be addressed.

deGroh, Kim K.↗

Alignment and Initial Operation of an Advanced Solar Simulator

A solar simulator utilizing nine 30 kW xenon arc lamps was built to provide radiant power for testing a solar dynamic space power system in a thermal vacuum environment. The advanced solar simulator meets requirements specific to the solar dynamic system, including: (1) a subtense angle of 1 deg, (2) the ability to vary solar simulator intensity up to 1.7 kW/sq m, (3) a beam diameter of 4.8 m, and (4) uniformity of illumination on the order of +/- 10 percent. The flexibility of the solar simulator design allows for other potential uses of the facility. This paper presents a description of the facility, the alignment procedures used to deliver radiant power to the solar dynamic system, and a summary of the performance of the as-built solar simulator.

Jaworske, Donald A.↗

Emittance characterization of thermal control paints, coatings and surfaces using a calorimetric technique

Thermal control surfaces are used in every spacecraft thermal management system to dissipate heat through radiant heat transfer. This paper describes the thermal performance of several thermal control paints, coatings, and surfaces, as characterized by a calorimetric vacuum emissometer. The emissometer is designed to measure the functional emittance of a surface based on heat transfer from an underlying substrate to the surface and from the surface or near surface to a surrounding cold wall. Emittance measurements were made between 200 and 350 K. Polished aluminum, used here as a standard, was found to have a total hemispherical emittance of 0.06, as expected. A velvet black paint, also used here as a standard, was found to have an emittance of 0.94 at room temperature. Other surfaces of interest included a polyurethane-based black paint designated Z-306, a highly polished 316L stainless steel, and an atomic oxygen beam-textured carbon-carbon composite.

Jaworske, Donald A.↗

Measurement Of Thermal Conductivity Of Molten LiF

Report discusses experimental study of thermal conductivity of molten lithium fluoride. Study motivated by consideration of material for use as energy-storage medium in solar power systems.

Jaworske, Donald A.↗

Determination of atomic oxygen fluence using spectrophotometric analysis of infrared transparent witness coupons for long duration exposure tests

Atomic oxygen degradation is one of several major threats to the durability of spaceborne systems in low Earth orbit. Ground-based simulations are conducted to learn how to minimize the adverse effects of atomic oxygen exposure. Assessing the fluence of atomic oxygen in test chambers such as a plasma asher over long periods of time is necessary for accurate determination of atomic oxygen exposure. Currently, an atomic oxygen susceptible organic material such as Kapton is placed next to samples as a witness coupon and its mass loss is monitored and used to determine the effective atomic oxygen fluence. However, degradation of the Kapton witness coupons occurs so rapidly in plasma ashers that for any long term test many witness coupons must be used sequentially in order to keep track of the fluence. This necessitates opening vacuum to substitute fresh coupons. A passive dosimetry technique was sought to monitor atomic oxygen exposure over longer periods without the need to open the plasma asher to the atmosphere. This paper investigates the use of spectrophotometric analysis of durable IR transparent witness coupons to measure atomic oxygen exposure for longer duration testing. The method considered would be conductive to making in situ measurements of atomic oxygen fluence.

Podojil, Gregg M.↗

Void control in the crystallization of lithium fluoride

The effect of tungsten-coated graphite fibers on the radiant heat transfer characteristics of salt-fiber composites was studied by measuring the onset of melting as a function of applied furnace power. As the fiber concentration was increased from 0 to 5.40 percent fiber by weight, the furnace temperature required to melt the lithium fluoride also increased. Upon cooling, each of the crystalline salt-fiber composites were cut open with a diamond saw to expose the void. Optical photographs of the voids revealed a trend in void location and size, with the largest void, and the least change in the outer dimension of the boule upon cooling, occurring in the sample with the most fiber.

Jaworske, Donald A.↗

Hot filament technique for measuring the thermal conductivity of molten lithium fluoride

Molten salts, such as lithium fluoride, are attractive candidates for thermal energy storage in solar dynamic space power systems because of their high latent heat of fusion. However, these same salts have poor thermal conductivities which inhibit the transfer of heat into the solid phase and out of the liquid phase. One concept for improving the thermal conductivity of the thermal energy storage system is to add a conductive filler material to the molten salt. High thermal conductivity pitch-based graphite fibers are being considered for this application. Although there is some information available on the thermal conductivity of lithium fluoride solid, there is very little information on lithium fluoride liquid, and no information on molten salt graphite fiber composites. This paper describes a hot filament technique for determining the thermal conductivity of molten salts. The hot filament technique was used to find the thermal conductivity of molten lithium fluoride at 930 C, and the thermal conductivity values ranged from 1.2 to 1.6 W/mK. These values are comparable to the slightly larger value of 5.0 W/mK for lithium fluoride solid. In addition, two molten salt graphite fiber composites were characterized with the hot filament technique and these results are also presented.

Jaworske, Donald A.↗

Measurements of print-through in graphite fiber epoxy composites

High-reflectance accurate-contour mirrors are needed for solar dynamic space power systems. Graphite fiber epoxy composites are attractive candidates for such applications owing to their high modulus, near-zero coefficient of thermal expansion, and low mass. However, mirrors prepared from graphite fiber epoxy composite substrates often exhibit print-through, a distortion of the surface, which causes a loss in solar specular reflectance. Efforts to develop mirror substrates without print-through distortion require a means of quantifying print-through. Methods have been developed to quantify the degree of print-through in graphite fiber epoxy composite specimens using surface profilometry.

Jaworske, Donald A.↗

Halogenation Enhances Carbon-Fiber/Epoxy Composites

Interlaminar shear strength increased by inexpensive treatment. New surface treatment for carbon fibers enhances interlaminar shear strength, ILSS, without altering tensile strength significantly. Exposure of polyacrylonitrile-based T-300, or equivalent, fibers to bromine vapor at room temperature improves ILSS of epoxy composites made from these fibers by 30 percent. Enhanced ILSS obtained from halogenation of carbon fibers beneficial in many aerospace and terrestrial applications.

Jaworske, Donald A.↗

Improving the interlaminar shear strength of carbon fiber-epoxy composites through carbon fiber bromination

The use of bromine to improve the interlaminar shear strength of PAN-based carbon fibers was investigated. Composite test specimens fabicated from brominated T-300 fibers and a MY720 matrix exhibited on average a 30% improvement in ILSS over their pristine counterparts. Mass, electrical resistivity, density, contact angle, and scanning Auger microscopy results suggested a mechanism in which the bromine was covalently bonded to the surface of the fiber, and this resulted in an increased van der Waal's adhesion between fiber and matrix.

Jaworske, Donald A.↗

Mechanical and electrical properties of graphite fiber-epoxy composites made from pristine and bromine intercalated fibers

The mechanical and electrical properties of pristine and bromine intercalated graphite fiber-epoxy composites were compared. The two types of composite were similar in terms of tensile modulus, tensile strength, and Poisson's Ratio. However, the interlaminar shear strength of the brominated composite was 18 percent greater than its pristine counterpart. Only slight differences were observed in flexural properties. A five-fold decrease was observed in the electrical resistivity of the brominated composite parallel to the axis of the fibers, resulting in a unidirectional resistivity of about 90 microOmega/cm. Transverse resistivity was unaffected. Both types of composite were subjected to a simulated lightning strike of 10 KJ (at a peak current of 150 kA), and the composite with the intercalated graphite exhibited less damage.

Jaworske, Donald A.↗