Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies
Here, using slow diffusion methods at room temperature (RT), we obtained four isomorphous lanthanide glutarate chlorides, accommodating interstitial THF and water molecules, [Ln 2 (Glut) 2 Cl 2 (H 2 O) 8 ]·2H 2 O·THF, with Ln = La , Ce, Pr, Nd. They assemble as 3-dimensional (3D) lanthanide (Ln) coordination polymers with LnO 10 coordination polyhedra. Their topology was elucidated to be a 4-coordinated sql net. slowly dissolve in water liberating the entrapped THF molecules and reassemble as regular Ln-glutarate hydrates when the solution is deprived of THF and water by slow evaporation. The new products crystallize as [Ln 2 (Glut) 3 (H 2 O) 3 ]·5H 2 O, with Ln = La, Ce, Pr, and [Nd 2 (Glut) 3 (H 2 O) 2 ]·3.5H 2 O.