Frit Recommendation For Sludge Batch 9 Coupled Operation With The Salt Waste Processing Facility
Prior to the processing of Sludge Batch 9 (SB9) with Frit 803 at the Defense Waste Processing Facility (DWPF), assessments and experimental glass work were completed to support SB9 coupled processing with streams from the Actinide Removal Process (ARP) and Modular Caustic Side Solvent Extraction Unit (MCU). This previous work did not address coupled processing with streams from the Salt Waste Processing Facility (SWPF) because the Product Composition Control System (PCCS) models limited the TiO2 concentration in glass to 2 weight percent (wt.%). These high activity streams from SWPF include monosodium titanate (MST) and sludge solids from the Sludge Solids Receipt Tank (SSRT) as well as Cscontaining strip effluent (SE). The SWPF streams are expected to reach TiO2 concentrations in glass greater than 2 wt.% based on an MST strike of 0.4 g MST/L of salt solution. Therefore, revisions to the models contained in PCCS were completed to allow the evaluation of glasses containing greater than 2 wt.% TiO2, but less than 6 wt.%. Since the initial SB9 qualification for ARP-MCU coupled operation, additional Tank 40 analyses have been completed, which served as the basis for an updated projection of the SB9 blend composition in Tank 40. This projection will be used to support SB9 coupled operation with SWPF in 2019. Savannah River Remediation (SRR) has requested that the Savannah River National Laboratory (SRNL) select a second frit to optimize SB9 coupled operation with SWPF. The selected frit would provide operational flexibility by allowing an acceptable waste loading (WL) to be targeted while maintaining an operating window of at least ± 4 percentage points around this target. The objective of this study was to select a second frit based on a paper-study utilizing Measurement Acceptance Region (MAR) assessments with DWPF PCCS. To support these assessments, SRNL developed a new method for rigorous and directed optimization of frit compositions, which allowed for rapid screening and an assessment of a large array of candidate frits, and the ability to simultaneously satisfy the following single and double MST strike operating scenarios.