Search NASASearch

Engineering topics

Johnson, H.

Publications and source records attributed to Johnson, H..

AVIRIS User's Guide

This paper serves as a brief overview of the AVIRIS instrument (Airborne Visible/Infrared Imaging Spectrometer) and its role in the field of imaging spectrometry. Mission planning and flight operations are discussed, and recommendations are given regarding the deployment of ground truth experiments.

AVIRIS

Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) Onboard Calibration System

The AVIRIS instrument uses an onboard calibration system to provide auxiliary calibration data. The system consists of tungsten halogen cycle lamp imaged onto a fiber bundle through an eight position filter wheel. The fiber bundle illuminates the back side of the foreoptics shutter during a pre-run and post-run calibration sequence. The filter wheel contains 2 neutral density filters, 5 spectral filters and blocked position.

spectrometer

Improvements to the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) Calibration System

As a continuing effort to increase the calibration accuracy of the AVIRIS data a number of recent improvements have been implemented and are in the process of being tested during the 1994 flight season. These include the following innovations: A direct observation of a laboratory radiance standard is now used to double check the wide field-of-view calibration via an integrating sphere source. Launch site field calibration of the AVIRIS sensor is now being planned to augment the laboratory and inflight calibration. Modification to a dry air conditioning unit has been made to enable ground calibration at flight operating temperatures. One hundred lines of dark imagery has been added to the end of each flight line to assist in the analysis and removal of residual coherent noise. The intensity of the onboard calibration lamp has been modified to improve response in the blue end of the spectrum. Novel spectral filters have been installed in the onboard calibration source.

Airborne Visible/Infrared Imaging Spectrometer Cal

QSAR for cholinesterase inhibition by organophosphorus esters and CNDO/2 calculations for organophosphorus ester hydrolysis

Quantitative structure-activity relationships were derived for acetyl- and butyrylcholinesterase inhibition by various organophosphorus esters. Bimolecular inhibition rate constants correlate well with hydrophobic substituent constants, and with the presence or absence of catonic groups on the inhibitor, but not with steric substituent constants. CNDO/2 calculations were performed on a separate set of organophosphorus esters, RR'P(O)X, where R and R' are alkyl and/or alkoxy groups and X is fluorine, chlorine or a phenoxy group. For each subset with the same X, the CNDO-derived net atomic charge at the central phosphorus atom in the ester correlates well with the alkaline hydrolysis rate constant. For the whole set of esters with different X, two equations were derived that relate either charge and leaving group steric bulk, or orbital energy and bond order to the hydrogen hydrolysis rate constant.

Johnson, H.

QSAR for cholinesterase inhibition by organophosphorus esters and CNDO/2 calculations for organophosphorus ester hydrolysis

Quantitative structure-activity relationships were derived for acetyl- and butyrylcholinesterase inhibition by various organophosphorus esters. Bimolecular inhibition rate constants correlate well with hydrophobic substituent constants, and with the presence or absence of cationic groups on the inhibitor, but not with steric substituent constants. CNDO/2 calculations were performed on a separate set of organophosphorus esters, RR-primeP(O)X, where R and R-prime are alkyl and/or alkoxy groups and X is fluorine, chlorine or a phenoxy group. For each subset with the same X, the CNDO-derived net atomic charge at the central phosphorus atom in the ester correlates well with the alkaline hydrolysis rate constant. For the whole set of esters with different X, two equations were derived that relate either charge and leaving group steric bulk, or orbital energy and bond order to the hydrolysis rate constant.

Johnson, H.

Structure-activity correlations for organophosphorus ester anticholinesterases. Part 2: CNDO/2 calculations applied to ester hydrolysis rates

Quantitative structure-activity relationships are presented for the hydrolysis of organophosphorus esters, RR'P(O)X, where R and R' are alkyl and/or alkoxy groups and X is fluorine, chlorine or a phenoxy group. CNDO/2 calculations provide values for molecular parameters that correlate with alkaline hydrolysis rates. For each subset of esters with the same leaving group, X, the CNDO-derived net atomic charge at the central phosphorus atom correlates well with the alkaline hydrolysis rate constants. For the whole set of esters with different leaving groups, equations are derived that relate charge, orbital energy and bond order to the hydrolysis rate constants.

Johnson, H.

Material development for thermionic fuel-cladding systems.

Fuel-cladding systems capable of maintaining stable dimension and electron emission characteristics at high temperatures under irradiation are essential to the successful operation of nuclear thermionic power sources. Studies regarding two possible systems, involving tungsten clad uranium carbide and uranium oxide, are considered. Out-of-pile developmental efforts and the in-pile evaluation results for the two systems are described. Prototypical emitters have been tested for 8000 hours for the carbide system and 4000 hours for the oxide system.

Yang, L.