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Jucks, Kenneth W.

Publications and source records attributed to Jucks, Kenneth W..

Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS): Final Report of the ASCENDS Ad Hoc Science Definition Team

Improved remote sensing observations of atmospheric carbon dioxide (CO2) are critically needed to quantify, monitor, and understand the Earth's carbon cycle and its evolution in a changing climate. The processes governing ocean and terrestrial carbon uptake remain poorly understood,especially in dynamic regions with large carbon stocks and strong vulnerability to climate change,for example, the tropical land biosphere, the northern hemisphere high latitudes, and the Southern Ocean. Because the passive spectrometers used by GOSAT (Greenhouse gases Observing SATellite) and OCO-2 (Orbiting Carbon Observatory-2) require sunlit and cloud-free conditions,current observations over these regions remain infrequent and are subject to biases. These short comings limit our ability to understand and predict the processes controlling the carbon cycle on regional to global scales.In contrast, active CO2 remote-sensing techniques allow accurate measurements to be taken day and night, over ocean and land surfaces, in the presence of thin or scattered clouds, and at all times of year. Because of these benefits, the National Research Council recommended the National Aeronautics and Space Administration (NASA) Active Sensing of CO2 Emissions over Nights,Days, and Seasons (ASCENDS) mission in the 2007 report Earth Science and Applications from Space: National Imperatives for the Next Decade and Beyond. The ability of ASCENDS to collect low-bias observations in these key regions is expected to address important gaps in our knowledge of the contemporary carbon cycle.The ASCENDS ad hoc Science Definition Team (SDT), comprised of carbon cycle modeling and active remote sensing instrument teams throughout the United States (US), worked to develop the mission's requirements and advance its readiness from 2008 through 2018. Numerous scientific investigations were carried out to identify the benefit and feasibility of active CO2 remote sensing measurements for improving our understanding of CO2 sources and sinks. This report summarizes their findings and recommendations based on mission modeling studies, analysis of ancillary meteorological data products, development and demonstration of candidate technologies, anddesign studies of the ASCENDS mission concept.

Kawa, S. Randolph

SPARC Report on the Mystery of Carbon Tetrachloride

The Montreal Protocol (MP) controls the production and consumption of carbon tetrachloride (CCl4 or CTC) and other ozone-depleting substances (ODSs) for emissive uses. CCl4 is a major ODS, accounting for about 12% of the globally averaged inorganic chlorine and bromine in the stratosphere, compared to 14% for CFC-12 in 2012. In spite of the MP controls, there are large ongoing emissions of CCl4 into the atmosphere. Estimates of emissions from various techniques ought to yield similar numbers. However, the recent WMO/UNEP Scientific Assessment of Ozone Depletion estimated a 2007-2012 CCl4 bottom-up emission of 1-4 Gg/year (1-4 kilotonnes/year), based on country-by-country reports to UNEP, and a global top-down emissions estimate of 57 Gg/ year, based on atmospheric measurements. This 54 Gg/year difference has not been explained. In order to assess the current knowledge on global CCl4 sources and sinks, stakeholders from industrial, governmental, and the scientific communities came together at the “Solving the Mystery of Carbon Tetrachloride” workshop, which was held from 4-6 October 2015 at Empa in Dübendorf, Switzerland. During this workshop, several new findings were brought forward by the participants on CCl4 emissions and related science.

Ahmadzai, Husamuddin

Planning, Implementation, and Scientific Goals of the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) Field Missions

The Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) field mission based at Ellington Field, Texas, during August and September 2013 employed the most comprehensive airborne payload to date to investigate atmospheric composition over North America. The NASA ER-2, DC-8, and SPEC Inc. Learjet flew 57 science flights from the surface to 20 km. The ER-2 employed seven remote sensing instruments as a satellite surrogate and eight in situ instruments. The DC-8 employed 23 in situ and five remote sensing instruments for radiation, chemistry, and microphysics. The Learjet used 11 instruments to explore cloud microphysics. SEAC4RS launched numerous balloons, augmented Aerosol RObotic NETwork, and collaborated with many existing ground measurement sites. Flights investigating convection included close coordination of all three aircraft. Coordinated DC-8 and ER-2 flights investigated the optical properties of aerosols, the influence of aerosols on clouds, and the performance of new instruments for satellite measurements of clouds and aerosols. ER-2 sorties sampled stratospheric injections of water vapor and other chemicals by local and distant convection. DC-8 flights studied seasonally evolving chemistry in the Southeastern U.S., atmospheric chemistry with lower emissions of NOx and SO2 than in previous decades, isoprene chemistry under high and low NOx conditions at different locations, organic aerosols, air pollution near Houston and in petroleum fields, smoke from wildfires in western forests and from agricultural fires in the Mississippi Valley, and the ways in which the chemistry in the boundary layer and the upper troposphere were influenced by vertical transport in convective clouds.

Toon, Owen B.

Forward Modeling of Atmospheric Carbon Dioxide in GEOS-5: Uncertainties Related to Surface Fluxes and Sub-Grid Transport

Forward GEOS-5 AGCM simulations of CO2, with transport constrained by analyzed meteorology for 2009-2010, are examined. The CO2 distributions are evaluated using AIRS upper tropospheric CO2 and ACOS-GOSAT total column CO2 observations. Different combinations of surface C02 fluxes are used to generate ensembles of runs that span some uncertainty in surface emissions and uptake. The fluxes are specified in GEOS-5 from different inventories (fossil and biofuel), different data-constrained estimates of land biological emissions, and different data-constrained ocean-biology estimates. One set of fluxes is based on the established "Transcom" database and others are constructed using contemporary satellite observations to constrain land and ocean process models. Likewise, different approximations to sub-grid transport are employed, to construct an ensemble of CO2 distributions related to transport variability. This work is part of NASA's "Carbon Monitoring System Flux Pilot Project,"

Pawson, Steven

Early Validation Analyses of Atmospheric Profiles from EOS MLS on the Aura Satellite

We present results of early validation studies using retrieved atmospheric profiles from the Earth Observing System Microwave Limb Sounder (MLS) instrument on the Aura satellite. 'Global' results are presented for MLS measurements of atmospheric temperature, ozone, water vapor, hydrogen chloride, nitrous oxide, nitric acid, and carbon monoxide, with a focus on the January-March 2005 time period. These global comparisons are made using long-standing global satellites and meteorological datasets, as well as some measurements from more recently launched satellites. Comparisons of MLS data with measurements from the Ft. Sumner, NM, September 2004 balloon flights are also presented. Overall, good agreeement is obtained, often within 5% to 10%, but we point out certain issues to resolve and some larger systematic differences; some artifacts in the first publicly released MLS (version 1.5) dataset are noted.We comment briefly on future plans for validation and software improvements.

Atmospheric retrievals

Remote sensing of planetary properties and biosignatures on extrasolar terrestrial planets

The major goals of NASA's Terrestrial Planet Finder (TPF) and the European Space Agency's Darwin missions are to detect terrestrial-sized extrasolar planets directly and to seek spectroscopic evidence of habitable conditions and life. Here we recommend wavelength ranges and spectral features for these missions. We assess known spectroscopic molecular band features of Earth, Venus, and Mars in the context of putative extrasolar analogs. The preferred wavelength ranges are 7-25 microns in the mid-IR and 0.5 to approximately 1.1 microns in the visible to near-IR. Detection of O2 or its photolytic product O3 merits highest priority. Liquid H2O is not a bioindicator, but it is considered essential to life. Substantial CO2 indicates an atmosphere and oxidation state typical of a terrestrial planet. Abundant CH4 might require a biological source, yet abundant CH4 also can arise from a crust and upper mantle more reduced than that of Earth. The range of characteristics of extrasolar rocky planets might far exceed that of the Solar System. Planetary size and mass are very important indicators of habitability and can be estimated in the mid-IR and potentially also in the visible to near-IR. Additional spectroscopic features merit study, for example, features created by other biosignature compounds in the atmosphere or on the surface and features due to Rayleigh scattering. In summary, we find that both the mid-IR and the visible to near-IR wavelength ranges offer valuable information regarding biosignatures and planetary properties; therefore both merit serious scientific consideration for TPF and Darwin.

Planets

Measurement of HO2 And Other Trace Gases in The Stratosphere Using a High Resolution Far-Infrared Spectrometer

This report covers the time period 1 April 1999 to 31 March 2000. During this period we continued analyzing data from past flights, exploring issues such as radical partitioning, stratospheric transport, and stratosphere-troposphere exchange. With funding from Smithsonian we have also completed a preliminarY design for a compact, lightweight, next-generation Fourier-transform spectrometer.

Traub, Wesley A.

Ozone Production and Loss Rate Measurements in the Middle Stratosphere

The first simultaneous measurements of HO(x), NO(x), and Cl(x) radicals in the middle stratosphere show that NO(x) catalytic cycles dominate loss of ozone (O3) for altitudes between 24 and 38 km; Cl(x) catalytic cycles are measured to be less effective than previously expected; and there is no 'ozone deficit' in the photochemically dominated altitude range from 31 and 38 km, contrary to some previous theoretical studies.

Jucks, Kenneth W.

Measurement of HO2 and other trace gases in the stratosphere using a high resolution far-infrared spectrometer

This report covers the time period 1 January 1994 to 31 December 1994. During this reporting period we had our fourth Upper Atmosphere Research Satellite (UARS) correlative balloon flight; the data from this flight have been reduced and submitted to the UARS CDHF. We have spent most of the past year analyzing data from this and past flights. For example, using data from our September 1989 balloon flight we have demonstrated for the first time ever that the rates of production and loss of ozone are in balance in the upper stratosphere. As part of this analysis, we have completed the most detailed study to date of radical partitioning throughout the stratosphere. We have also produced the first measurement of HBr and HOBr mixing ratio profiles over a full diurnal cycle.

Traub, Wesley A.

Phase Determination from Mostly One-sided Interferograms

We show how to detect and correct for non-linear phase shifts in a mainly one-sided interferogram of an emission-line source. We simultaneously detect and correct for an out-of-phase emission background from the spectrometer. The method requires two auxiliary spectra, one of a strong continuum source, and one of an emission-line source with little or no continuum.

Johnson, David G.

Chemical change in the arctic vortex during AASE 2

We measured column abundances of HF, HCl, O3, HNO3, and H2O on the NASA DC-8 during the AASE II campaign, using thermal emission spectroscopy. We made multiple traversals of the Arctic vortex and surroundings. Using HF as a tracer, we remove the effects of subsidence from the measured column abundances; perturbations in the resulting column abundances are attributed to chemical processing. We find that by January 1992 the stratospheric column in the vortex had been chemically depleted by about (55+/-10)% in HCl and (35+/-10)% in O3, and enhanced by about (15+/-10)% in HNO3 and (0+/-10)% in H2O.

Traub, Wesley A.

Balloon measurements of stratospheric HCl and HF by far infrared emission spectroscopy

We have analyzed atmospheric thermal emission spectra obtained with the balloon-borne FIRS-2 far infrared Fourier transform spectrometer during balloon flights from Palestine, Texas on May 12-13, 1988 and from Fort Sumner, New Mexico on September 26-27, 1989 and on July 4-5, 1990. Seven and two pure rotational transition lines in 100-205 cm(exp -1) range are analyzed for deriving vertical profiles of stratospheric HCl and HF, respectively. We obtain both the daytime and nighttime average vertical profiles from 15 to 50 km. We compare these profiles with the ones obtained in June, 1983 with the first version of FIRS spectrometer during the Balloon Intercomparison Campaign (BIC-2). BIC-2 results were revised to be consistent with the present analysis which uses the latest spectral parameters. According to our comparison results no increase is recognized for HCl but about 3 percent per year increase for HF from 1983 to 1990, assuming a linear trend. These annual increase rates are smaller than those reported by other groups. Recently Rinsland et al. (1991) and Wallace and Livingston (1991) reported long term behavior of total HCl and HF observed on Kit Peak between 1977 and 1990. As Kit Peak is located near both balloon launching sites, Palestine and Fort Sumner, we think our results are favorably comparable with theirs. Comparison results with ours and ground-based measurements will be presented and discussed.

Shibasaki, Kazuo

Measurement of HO2 and other trace gases in the stratosphere using a high resolution far-infrared spectrometer

This report covers the time period 1 Jul. to 31 Dec. 1993. There were no balloon or airplane flights during this reporting period, instead we concentrated on analyzing our existing data. This was facilitated by a recently completed program of enhancements made in our data reduction software. We are using our data sets to examine the changes in stratospheric chemistry over a variety of time scales. Ongoing projects include investigating the diurnal variation of OH, HO2, and H2O2 and exploring their relationships with other simultaneously measured species; measuring long term trends in HF and HCl; and looking for changes caused by the June 1991 Pinatubo eruption. We are also continuing to analyze the large set of data collected during the AASE 2.

Traub, Wesley A.

Measurement of HO2 and other trace gases in the stratosphere using a high resolution far-infrared spectrometer at 28 km

This report covers the time period 1 January 1993 to 30 June 1993. During this reporting period we had our third Upper Atmosphere Research Satellite (UARS) correlative balloon flight and submitted the results from this flight to the Central Data Handling Facility (CDHF). We made a number of improvements in our data processing software in preparation for a new analysis of our old balloon data sets. Finally, we continue to analyze the data obtained during the second Airborne Arctic Stratospheric Expedition (AASE 2).

Traub, Wesley A.

Stratospheric spectroscopy with the far-infrared spectrometer (FIRS-2) - Overview and recent results

The Smithsonian Astrophysical Observatory's program of balloon-borne stratospheric spectroscopic measurements is described, including instrumentation, recent scientific results, and future plans. The design and operation of the FIRS-2 far-infrared spectrometer is discussed. The current status of our efforts to recover mixing-ratio profiles with about 1 percent precision is presented. Representative recent results are shown giving mixing-ratio profiles from 20 to 50 km, selected from the suite HOCl, HCl, HF, NO2, N2O, HNO3, OH, HO2, H2O2, H2O (and isotopes), O2 (and isotopes), O3 (and isotopes), and CO2 (and isotopes). The utility of O2 and CO2 spectral lines for information on view angle or temperature and pressure is discussed. Future plans are mentioned, including the use of FIRS-2 on a balloon platform for UARS correlative measurements, the use of FIRS-2 on the NASA DC-8 platform for polar measurements, and the potential benefits of a FIRS instrument on a Shuttle platform.

Traub, Wesley A.