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Julien, Howard L.

Publications and source records attributed to Julien, Howard L..

Pyrovalve Blowby Tests

The NASA White Sands Test Facility (WSTF) was requested to perform pyrovalve blowby tests in support of the Mars Observer Propulsion and Corrective Actions Test Program. Fifty-three tests were conducted in an attempt to characterize the blowby of commercial pyrovalves. Those pyrovalves used on NASA spacecraft are well represented, and the test data reported provide a basis for evaluating the performance of similar valves in other propulsion systems. The three test series conducted are subsequently described. All testing was done in the same test facility, with periodic changes that enhanced the test methodology.

Saulsberry, Regor

Isentropic Compression of Multicomponent Mixtures of Fuels and Inert Gases

In selected aerospace applications of the fuels hydrazine and monomethythydrazine, there occur conditions which can result in the isentropic compression of a multicomponent mixture of fuel and inert gas. One such example is when a driver gas such as helium comes out of solution and mixes with the fuel vapor, which is being compressed. A second example is when product gas from an energetic device mixes with the fuel vapor which is being compressed. Thermodynamic analysis has shown that under isentropic compression, the fuels hydrazine and monomethylhydrazine must be treated as real fluids using appropriate equations of state. The appropriate equations of state are the Peng-Robinson equation of state for hydrazine and the Redlich-Kwong-Soave equation of state for monomethylhydrazine. The addition of an inert gas of variable quantity and input temperature and pressure to the fuel compounds the problem for safety design or analysis. This work provides the appropriate thermodynamic analysis of isentropic compression of the two examples cited. In addition to an entropy balance describing the change of state, an enthalpy balance is required. The presence of multicomponents in the system requires that appropriate mixing rules are identified and applied to the analysis. This analysis is not currently available.

Barragan, Michelle

WSTF Pyrovalve Test Program Status: 2000

Extensive propulsion and pyrotechnic testing has been in progress at NASA/JSC White Sands Test Facility (WSTF) since 1995, starting with the Mars Observer Propulsion and Pyrotechnics Corrective Action Test Program (MOCATP). The MOCATP has been concluded, but extensive pyrovalve testing plus research and development continues at WSTF. Our capability to accurately characterize pyrovalve combustion product blow-by into propellant systems, evaluate hydrazine and monomethylhydrazine (MMH) thermal decomposition initiated by blow-by, and characterize valve actuation operation, continues to be used and refined. Data from this and several low blow-by pyrovalves manufactured by Conax and other corporations continues to be evaluated as a potential corrective measure for blow-by induced propellant explosions. Additionally, new measurement techniques are being developed, advanced pyrovalve development is under-way, and nondestructive examination (NDE) methods are being developed to help ensure pyrovalve safety. Starting in 2000 these data are being formatted into a pyrovalve application and testing handbook. Near-term testing includes evaluation of 3/8-in. Conax pyrovalves and other commercially available valves; development of advanced pyrovalve subcomponent technology; investigation of NDE techniques to evaluate pyrovalve ram seals and real-time measurement of housing deformation; and investigation of pyrotechnically induced explosive hydrazine decomposition both through testing and modeling. Evaluation of 3/8-in. Conax valves is to include operational margin testing to be accomplished at the NASA Langley Research Center.

Saulsberry, Regor L.

A Multiphase Equation of State for Hydrazine and Monomethylhydrazine

The objective of this work was to obtain a validated equation of state for hydrazine and monomethylhydrazine (MMH) and use this equation to calculate thermodynamic properties. The approach was based on using both reliable critical property values and a value of the acentric factor in the Soave Redlich Kwong and the Peng Robinson model equations of state. These equations were validated by comparing calculated molar volumes for phase equilibrium with published experimental values and comparing calculated vapor pressures with published experimental values over the temperature range appropriate for the corresponding state equations. The equation of state giving the best results was used to calculate enthalpy and entropy departure functions and fugacity values. Additional thermodynamic property calculations were performed to produce partial Mollier diagrams and thermodynamic properties containing internal energy, enthalpy, and entropy values for hydrazine and MMH. The analyses of systems in which either adiabatic or near-adiabatic compression of liquid or vapor hydrazine or low velocity detonations occur require a validated equation of state for representing occurring molar volumes and for energy calculations. Other calculations for thermodynamic properties of hydrazine are available, but the values are for a strict ideal gas state. This work characterized destructive events using hydrazine by calculating for isentropic compression temperatures. The final temperatures were calculated and compared using the ideal and real gas fluid equations of state.

Barragan, Michelle

Mars Observer Propulsion and Pyrotechnics Corrective Actions Test Program Status-1999

An extensive propulsion and pyrotechnic test program has been in progress at the NASA White Sands Test Facility since 1995. This program created the capabilities to: accurately measure and characterize pyrovalve combustion product blow-by into propellant systems; characterize valve operation using a Velocity Interferometer System for Any Reflector (VISAR); and evaluate hydrazine and monomethylhydrazine thermal decomposition initiated by blow-by. These capabilities were further utilized and refined this year. Low blow-by pyrovalves manufactured by Conax Florida Corporation continued to be evaluated as a potential corrective measure for blow-by induced propellant explosions. Development and testing of various advanced pyrovalves and investigation of explosion mechanisms also continued. Current and near-term testing includes: evaluation of 3/8 in. Conax pyrovalves and other commercially available valves; development and testing of advanced pyrovalve subcomponent technologies including a zero blow-by pyrovalve ram, composite overwrapped ram cylinder, and a zero particulate generating poppet; investigation of non-destructive evaluation techniques to evaluate pyrovalve ram seals; and testing and modeling of pyrotechnically induced explosive hydrazine decomposition. Evaluation of 3/8 in. Conax valves will include operational margin testing to be accomplished at NASA Langley Research Center. The test program also seeks to compile and format significant amounts of data from this and other pyrovalve test programs to generate a pyrovalve applications handbook. The handbook will facilitate formation of standards that ensure safe spacecraft applications. Current data and future plans are discussed, and community interaction is encouraged.

Saulsberry, Regor

Influence of test configuration on the combustion characteristics of polymers as ignition sources

The experimental evaluation of polymers as ignition sources for metals was accomplished at the NASA White Sands Test Facility (WSTF) using a standard promoted combustion test. These tests involve the transient burning of materials in high-pressure oxygen environments. They have provided data from which design decisions can be made; data include video recordings of ignition and non-ignition for specific combinations of metals and polymers. Other tests provide the measured compositions of combustion products for polymers at select burn times and an empirical basis for estimating burn rates. With the current test configuration, the detailed analysis of test results requires modeling a three-dimensional, transient convection process involving fluid motion, thermal conduction and convection, the diffusion of chemical species, and the erosion of sample surface. At the high pressure extremes, it even requires the analysis of turbulent, transient convection where the physics of the problem are not well known and the computation requirements are not practical at this time. An alternative test configuration that can be analyzed with a relatively-simple convection model was developed during the summer period. The principal change constitutes replacing a large-diameter polymer disk at the end of the metal test rod with coaxial polymer cylinders that have a diameter nearer to that of the metal rod. The experimental objective is to assess the importance of test geometries on the promotion of metal ignition by testing with different lengths of the polymer and, with an extended effort, to analyze the surface combustion in the redesigned promoted combustion tests through analytical modeling of the process. The analysis shall use the results of cone-calorimeter tests of the polymer material to model primary chemical reactions and, with proper design of the promoted combustion test, modeling of the convection process could be conveniently limited to a quasi-steady boundary layer analysis where the economical solution of parabolic equations is involved. The products for the summer period are: (1) a conceptual-level redesign of the test apparatus, and (2) the development and use of an approximate integral boundary layer analysis to demonstrate the influence of geometry changes prior to testing. A computer code STAN5, an accurate numerical boundary layer model whose earlier versions were developed for the NASA Lewis Research Center by the Fellow, also was installed and validated on the WSTF and New Mexico State University computer systems as a starting point in the development of a more detailed fluid mechanics and combustion model.

Julien, Howard L.