Engineering topics
Publications and source records attributed to Juvinall, G. L..
The advantages of lithium systems are described and a general summary of their application in present and future NASA programs is presented. Benefits of the lithium systems include an increased payload weight and an increased cost effectiveness to the customer. This also allows for more flexibility in the design of future space transportation systems.
Briefly outlined are the activities of the various research centers involved in the NASA program. Graphs are presented for: (1) the initial results on SOCl2 decomposition rate; (2) effect of rate on output of Li-SOCl2 cells; (3) comparison of high and low rate Li-SOCl2 cells; and (4) effect of temperature on output of Li-SOCl2 cells. Abusive test results and a description of secondary lithium cells are also presented.
Method of constructing nickel cadmium batteries prevents excessive gas buildup and allows hermetic sealing of battery for increased service life and reduced maintenance cost.
The use of negative-limited nickel-cadmium cells with adequate charge control is shown to provide an effective means for controlling internal pressure. Cycle test data show that negative-limited cells have somewhat higher ampere-hour degradation rates at higher operating temperatures. The most important advantages of these cells are: (1) lesser heat generation during operation; (2) longer separator life, as a result of operation at lower temperatures; (3) decreased stresses on cell seals due to lower operating pressures; and (4) significant weight savings.
The existing work on gravitational effects on electrochemical batteries is summarized, certain conclusions are drawn, and recommendations are made for future activities in this field. The effects of sustained high-G environments on cycle silver-zinc and nickel-cadmium cells have been evaluated over four complete cycles in the region of 10 to 75 G. Although no effects on high current discharge performances or on ampere-hour capacity were noted, severe zinc migration and sloughing of active material from the zinc electrode were observed. This latter effect constitutes real damage, and over a long period of time would result in loss of capacity. It is recommended that a zero-G battery experiment be implemented. Both an orbiting satellite and a sounding rocket approach are being considered.
Organometallic compounds of niobium and tantalum useful for film deposition
Nuclear magnetic resonance of phosphorus compounds, discussing signs of spin-spin couplings in dimethylphosphine and methylphosphine
Synthesis and formula determination of sigma bonded trimethyldichloroniobium and trimethyldichlorotantalum
Relative signs and magnitudes of proton nuclear magnetic resonance coupling constants in phosphorus compounds
Phosphorous-proton nuclear magnetic resonance coupling constants - sign determination