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Kaifu, Norio

Publications and source records attributed to Kaifu, Norio.

Observations of molecular envelopes of late-type stars: CRL 618, CRL 2688, CRL 3068, and CIT 6

The HC3N, HC5N, HC7N, CCH, C4H, SiS, and HNC molecules were observed in the circumstellar envelopes of CRL 618, CRL 2688, CIT 6, and CRL 3068 with the Nobeyama 45 m radio telescope. The observed relative abundances of the cyanopolyynes, CCH, and C4H in these late-type stars are similar to those for IRC +10216. However, it was found that the abundance of HNC increased with the physical evolutionary stage of the stars. In CRL 2688, it is also found that HNC is more concentrated in the inner region than SiS. The production mechanism of HNC is discussed by considering ultraviolet radiation from the central stars. The HC3N J = 4-3 transition was observed to have a P Cygni line profile in CRL 618.

Fukasaku, Sadafumi↗

Detection of a new carbon-chain molecule, CCO

A new carbon-chain molecule, CCO 3Sigma(-), has been detected in the cold dark molecular cloud TMC-1. The excitation temperature and the column density of CCO are, respectively, about 6 K and about 6 x 10 to the 11th/sq cm. This column density corresponds to a fractional abundance relative to H2 of about 6 x 10 to the -11th. This value is two orders of magnitude less than the abundance of the related carbon-chain molecule CCS, and about half that of C3O. The formation mechanism for CCO is discussed.

Ohishi, Masatoshi↗

Chemical abundances in cold, dark interstellar clouds

Current tabulations are presented of the entire range of known interstellar molecules, giving attention to that subset which has been identified in the cold, dark interstellar clouds out of which the sun has been suggested to have formed. The molecular abundances of two such clouds, Taurus Molecular Cloud 1 and Lynd's 134N, exhibit prepossessing chemical differences despite considerable physical similarities. This discrepancy may be accounted for by the two clouds' differing evolutionary stages. Two novel classes of interstellar molecules are noted: sulfur-terminated carbon chains and silicon-terminated ones.

Irvine, William M.↗

Observations of cumulene carbenes, H2CCCC and H2CCC, in TMC-1

Attention is given to the carbon chain molecule H2CCCC, detected in the dark cloud TMC-1 for the first time in the course of a molecular line survey using the Nobeyama 45-m telescope. From nine transitions observed in the frequency region of 17-45 GHz, the total column density of H2CCCC in TMC-1 is derived to be 7.5(+/-2.0) x 10 exp 12/sq cm, which is about half of the value reported in IRC + 10216. Five transitions of a related carbon chain molecule, H2CCC, were also detected in TMC-1. The column density of H2CCC obtained in TMC-1, 2.8(+/-0.9) x 10 exp 12/sq cm, is a factor of three smaller than that of H2CCCC. The ortho-to-para abundance ratios of H2CCCC and H2CCC were found to be 4.2 +/-1.5 and 5.9 +/-2.0, respectively. The chemical reactions of these carbon-chain molecules in dark clouds are discussed.

Kawaguchi, Kentarou↗

Detection of a new circumstellar carbon chain molecule, C4Si

A new interstellar carbon chain molecule, C4Si, has been detected in the envelope of the evolved star IRC + 10216. This molecule is the carrier of six unidentified lines which had been detected during the molecular line survey at Nobeyama Radio Observatory. The identification was made through astronomical detections followed by quantum chemical calculations and laboratory spectroscopic experiments. The rotational constant and the centrifugal distortion constant were B(0) = 1533.77206(146) MHz and D(0) = 0.00005827(35) MHz, respectively, where the numbers in parentheses represent one standard deviation in units of the last significant digits. The rotation temperature and the column density were 15 + or - 2 K and (7 + or - 1) x 10 to the 12th/sq cm, respectively, assuming a source size of 25 arcsec.

Ohishi, Masatoshi↗